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Thermodynamic Study of Binary Mixtures Containing Glycols or Polyethylene Glycols + Benzyl Alcohol at 308.15 K
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    Thermodynamic Study of Binary Mixtures Containing Glycols or Polyethylene Glycols + Benzyl Alcohol at 308.15 K
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    Dipartimento di Chimica “G. Ciamician”, Università degli Studi, via Selmi 2, I-40126 Bologna, Italy, and I.S.O.F., C.N.R., c/o Dipartimento di Chimica “G.Ciamician”, via Selmi 2, I-40126 Bologna, Italy
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2004, 49, 2, 363–367
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    https://doi.org/10.1021/je0342062
    Published January 22, 2004
    Copyright © 2004 American Chemical Society

    Abstract

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    Excess molar enthalpies and excess molar volumes of binary mixtures containing ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, or poly(ethylene glycol)s (PEG200, PEG300, PEG400, and PEG600) + benzyl alcohol were determined at 308.15 K and at atmospheric pressure using a flow microcalorimeter and a digital density meter. Results were fitted to the Redlich−Kister polynomial to estimate the binary interaction parameters. The results are interpreted in terms of molecular interactions between the components.

    Copyright © 2004 American Chemical Society

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     To whom correspondence should be addressed. Fax:  + 39-051-2094325. E-mail:  [email protected].

     Università degli Studi.

     I.S.O.F., C.N.R.

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    This article is cited by 25 publications.

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    3. Carlo Castellari. Excess Molar Enthalpies and Hydrogen Bonding in Binary Mixtures Containing Ethers and Benzyl Alcohol at 308.15 K and Atmospheric Pressure. Journal of Chemical & Engineering Data 2006, 51 (2) , 599-603. https://doi.org/10.1021/je0504212
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    7. Ping Liu,, Zimin Liu, Tianxiang Zhao, Fei Liu, Quanlan Liao. Density, Viscosity, and Spectroscopic Nature for the Binary System of Tetraethylene Glycol (1) + Water (2) T = (298.15 to 323.15) K. International Journal of Thermophysics 2021, 42 (6) https://doi.org/10.1007/s10765-021-02851-8
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    9. M. M. Alavianmehr, N. Hemmati, H. Ghodrati. Excess molar volumes, excess thermal expansion coefficients and isentropic compressibility deviations for binary mixtures of benzyl alcohol + (1-butanol, 2-butanol, 2-methyl-1-butanol and tert -butanol) at T  = (298.15-328.15) K and ambient pressure. Physics and Chemistry of Liquids 2016, 46 , 1-15. https://doi.org/10.1080/00319104.2016.1166361
    10. Krzysztof Klimaszewski, Ewa Stronka-Lewkowska, Katarzyna Soliwoda, Adam Bald. Acoustic and volumetric studies on water + diethylene glycol mixtures in a wide temperature range. Comparison with mixtures of water with tri- and tetraethylene glycol. Journal of Molecular Liquids 2016, 215 , 520-533. https://doi.org/10.1016/j.molliq.2016.01.037
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    14. Krzysztof Klimaszewski, Ewa Stronka-Lewkowska, Ilona Trzcińska, Adam Bald. Volumetric and acoustic studies on (tetraethylene glycol + water) mixtures in a wide temperature range. The Journal of Chemical Thermodynamics 2015, 85 , 191-201. https://doi.org/10.1016/j.jct.2015.02.007
    15. Syeda K. Begum, Ronald J. Clarke, M. Shamsuddin Ahmed, Shahanara Begum, Mohammad A. Saleh. Volumetric, viscosimetric and surface properties of aqueous solutions of triethylene glycol, tetraethylene glycol, and tetraethylene glycol dimethyl ether. Journal of Molecular Liquids 2013, 177 , 11-18. https://doi.org/10.1016/j.molliq.2012.09.015
    16. Zhenhua Guo, Jianbin Zhang, Tong Zhang, Chunping Li, Yongfeng Zhang, Jie Bai. Liquid viscosities, excess properties, and viscous flow thermodynamics of triethylene glycol+water mixtures at T=(298.15, 303.15, 308.15, 313.15, and 318.15) K. Journal of Molecular Liquids 2012, 165 , 27-31. https://doi.org/10.1016/j.molliq.2011.10.003
    17. D.I. Sagdeev, M.G. Fomina, G.Kh. Mukhamedzyanov, I.M. Abdulagatov. Experimental study of the density and viscosity of polyethylene glycols and their mixtures at temperatures from 293K to 473K and at atmospheric pressure. The Journal of Chemical Thermodynamics 2011, 43 (12) , 1824-1843. https://doi.org/10.1016/j.jct.2011.06.013
    18. Ch. Wohlfarth. pVT data of poly(ethylene glycol) in benzyl alcohol. 2010, 47-47. https://doi.org/10.1007/978-3-642-02890-8_46
    19. Ch. Wohlfarth. Enthalpy of dilution of poly(ethylene glycol) in benzyl alcohol. 2010, 1290-1290. https://doi.org/10.1007/978-3-642-02890-8_774
    20. Alain Durand, Emmanuelle Marie. Macromolecular surfactants for miniemulsion polymerization. Advances in Colloid and Interface Science 2009, 150 (2) , 90-105. https://doi.org/10.1016/j.cis.2009.07.002
    21. Nikos G. Tsierkezos, Maria M. Palaiologou. Ultrasonic studies of liquid mixtures of either water or dimethylsulfoxide with ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, 1,2-propylene glycol and 1,4-butylene glycol at 298.15 K. Physics and Chemistry of Liquids 2009, 47 (4) , 447-459. https://doi.org/10.1080/00319100802104855
    22. Romolo Francesconi, Stefano Ottani. Correlation of density and refraction index for liquid binary mixtures containing polyglycols. Use of the group contributions in the Lorentz–Lorenz, Gladstone–Dale and Vogel equations to evaluate the density of mixtures. Journal of Molecular Liquids 2007, 133 (1-3) , 125-133. https://doi.org/10.1016/j.molliq.2006.07.001
    23. Yanwei Zhong, Haijun Wang, Kaishen Diao. Densities and excess volumes of binary mixtures of the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate with aromatic compound at T=(298.15 to 313.15)K. The Journal of Chemical Thermodynamics 2007, 39 (2) , 291-296. https://doi.org/10.1016/j.jct.2006.07.001
    24. . Enthalpies of Mixing or Intermediary Enthalpies of Dilution. 2006, 15-194. https://doi.org/10.1201/9781420009293.ch2
    25. Carlo Castellari, Romolo Francesconi, Fabio Comelli. Excess molar enthalpies and hydrogen bonding in binary mixtures containing glycols or poly(ethylene glycols) and 3-phenylpropyl alcohol at 308.15 K and atmospheric pressure. Thermochimica Acta 2004, 424 (1-2) , 69-73. https://doi.org/10.1016/j.tca.2004.05.015

    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2004, 49, 2, 363–367
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je0342062
    Published January 22, 2004
    Copyright © 2004 American Chemical Society

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