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    Surface Tensions and Densities of Sulfuric Acid + Dimethylamine + Water Solutions
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    Finnish Meteorological Institute, Sahaajankatu 20 E, 00880 Helsinki, Finland, and Department Of Applied Physics, University of Kuopio, P.O. Box 1627, 70211 Kuopio, Finland
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2004, 49, 4, 917–922
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    https://doi.org/10.1021/je034225b
    Published May 29, 2004
    Copyright © 2004 American Chemical Society
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    Abstract

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    The surface tensions and densities of aqueous solutions of dimethylamine, (CH3)2NH, and sulfuric acid, H2SO4, were measured at 24.2 °C. Mol fractions of dimethylamine were varied between 0 and 0.21 and of sulfuric acid between 0 and 0.48. The surface tension of the binary dimethylamine + water solution decreased exponentially as dimethylamine was added, from the surface tension of water (72 mN·m-1 at 25 °C) to the value of 34 mN·m-1 at the maximum dimethylamine mol fraction of 0.21. The surface tension of the ternary system did not change from that of water + sulfuric acid until a sufficient amount of dimethylamine was added to turn the solution alkaline. When the mol fraction of dimethylamine was more than double the mol fraction of sulfuric acid, the surface tension of the solution started to approach that of water + dimethylamine. Polynomial fits were applied to measured data sets of both surface tension and density. Results and fitting parameters are presented.

    Copyright © 2004 American Chemical Society

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    *

     To whom correspondence may be addressed. E-mail: [email protected].

    †

     Finnish Meteorological Institute.

    ‡

     University of Kuopio.

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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2004, 49, 4, 917–922
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je034225b
    Published May 29, 2004
    Copyright © 2004 American Chemical Society
    Request reuse permissions

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