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Liquid−Liquid Equilibria of Water + Acetic Acid + Dimethyl Glutarate Ternary System

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Istanbul University, Engineering Faculty, Chemical Engineering Department, 34320 Avcilar, Istanbul, Turkey
Cite this: J. Chem. Eng. Data 2005, 50, 5, 1539–1542
Publication Date (Web):August 17, 2005
https://doi.org/10.1021/je049571n
Copyright © 2005 American Chemical Society

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    Abstract

    Liquid−liquid equilibrium (LLE) data of water + acetic acid + dimethyl glutarate were measured at T = (298.2, 308.2, and 318.2) K. Complete phase diagrams were obtained by determining binodal curves and tie lines. The reliability of the experimental tie line data was confirmed by using the Othmer−Tobias correlation. UNIFAC and modified UNIFAC models were used to predict the phase equilibrium data in the ternary system. Distribution coefficients and separation factors were evaluated for the immiscibility region.

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    Cited By

    This article is cited by 13 publications.

    1. Thanaporn Wannachod, Milan Hronec, Tomáš Soták, Katarína Fulajtárová, Ura Pancharoen, and Kasidit Nootong . Influence of Salt on the Solubility and Tie-Line Data for Water + Formic Acid + Methyl Isobutyl Ketone at T = 298.15 K. Journal of Chemical & Engineering Data 2016, 61 (7) , 2433-2439. https://doi.org/10.1021/acs.jced.6b00109
    2. Alka Kumari, Kadakanchi Sandeepa, Thella Prathap Kumar, and Bankupalli Satyavathi . Solubility, Thermodynamic Properties, and Derived Excess Properties of Benzoic Acid in (Acetic Acid + Water) and (Acetic Acid + Toluene) Binary Mixtures. Journal of Chemical & Engineering Data 2016, 61 (1) , 67-77. https://doi.org/10.1021/acs.jced.5b00197
    3. Amparo Cháfer, Estela Lladosa, Juan B. Montón and MaCruz Burguet. Liquid−Liquid Equilibria for the System 1-Methyl Propyl Ethanoate (1) + Acetic Acid (2) + Water (3) at (283.15 and 323.15) K. Journal of Chemical & Engineering Data 2010, 55 (1) , 523-525. https://doi.org/10.1021/je900332x
    4. B. Mahida, H. Benyounes, S. Jin, W. Shen. Pressure-swing distillation process for separating ternary azeotropic mixture of acidic aqueous solution. Chemical Engineering Communications 2022, 209 (7) , 882-894. https://doi.org/10.1080/00986445.2021.1925653
    5. Honglin Chen, Lei Zhang, Yulan Huang, Jingjing Lu, Zhijian Zhao, Xunqiu Wang. Isobaric vapor–liquid equilibrium of three binary systems containing dimethyl succinate, dimethyl glutarate and dimethyl adipate at 2, 5.2 and 8.3 kPa. The Journal of Chemical Thermodynamics 2019, 133 , 100-110. https://doi.org/10.1016/j.jct.2019.02.006
    6. Laerti Reis Roque, Rafaela Rocha Pinto, Leonardo Hadlich de Oliveira, Sarita Cândida Rabelo. Liquid-liquid equilibrium data for ternary systems of water + acetic acid+ acetate esters at 293.2 K and 303.2 K and ≈ 95 kPa. Fluid Phase Equilibria 2018, 463 , 34-47. https://doi.org/10.1016/j.fluid.2018.02.003
    7. Erol İnce, Yavuz Selim Aşçı. (Liquid+liquid) equilibria of the (water+carboxylic acid+dibasic esters mixture (DBE-2)) ternary systems. Fluid Phase Equilibria 2014, 370 , 19-23. https://doi.org/10.1016/j.fluid.2014.03.002
    8. Tugba Gündogdu, Süheyla Çehreli. Ternary liquid–liquid phase equilibria of (water–carboxylic acid–1-undecanol) systems at 298.15K. Fluid Phase Equilibria 2012, 331 , 26-32. https://doi.org/10.1016/j.fluid.2012.06.020
    9. Yu-Ting Tsai, Ho-mu Lin, Ming-Jer Lee. Kinetics of heterogeneous esterification of glutaric acid with methanol over Amberlyst 35. Journal of the Taiwan Institute of Chemical Engineers 2011, 42 (2) , 271-277. https://doi.org/10.1016/j.jtice.2010.07.010
    10. Kai-Wen Chan, Yu-Ting Tsai, Ho-mu Lin, Ming-Jer Lee. Esterification of adipic acid with methanol over Amberlyst 35. Journal of the Taiwan Institute of Chemical Engineers 2010, 41 (4) , 414-420. https://doi.org/10.1016/j.jtice.2009.12.001
    11. Thella Prathap Kumar, Parichay K. Das. SOLUBILITY AND TIE-LINE DATA FOR WATER + FORMIC ACID + METHYL ISOBUTYL KETONE TERNARY SYSTEM AT DIFFERENT TEMPERATURES. Chemical Engineering Communications 2010, 197 (9) , 1163-1171. https://doi.org/10.1080/00986440903574784
    12. Erol İnce. (Liquid+liquid) equilibria of the (water+acetic acid+dibasic esters mixture) system. The Journal of Chemical Thermodynamics 2006, 38 (12) , 1669-1674. https://doi.org/10.1016/j.jct.2006.03.012
    13. Shih-Bo Hung, Ho-Mu Lin, Cheng-Ching Yu, Hsiao-Ping Huang, Ming-Jer Lee. Liquid–liquid equilibria of aqueous mixtures containing selected dibasic esters and/or methanol. Fluid Phase Equilibria 2006, 248 (2) , 174-180. https://doi.org/10.1016/j.fluid.2006.08.002

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