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Henry's Law Constants and Infinite Dilution Activity Coefficients of Propane, Propene, Butane, Isobutane, 1-Butene, Isobutene, trans-2-Butene, and 1,3-Butadiene in 2-Methyl-1-butanol, 3-Methyl-1-butanol, and 2-Methyl-2-butanol
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    Henry's Law Constants and Infinite Dilution Activity Coefficients of Propane, Propene, Butane, Isobutane, 1-Butene, Isobutene, trans-2-Butene, and 1,3-Butadiene in 2-Methyl-1-butanol, 3-Methyl-1-butanol, and 2-Methyl-2-butanol
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    Department of Chemistry and Bioscience, Kurashiki University of Science and the Arts, 2640 Nishinoura, Tsurajimacho, Kurashiki 712-8505, Japan
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2005, 50, 1, 211–215
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    https://doi.org/10.1021/je049723e
    Published October 30, 2004
    Copyright © 2005 American Chemical Society

    Abstract

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    Henry's law constants and infinite dilution activity coefficients of propane, propene, butane, isobutane, 1-butene, isobutene, trans-2-butene, and 1,3-butadiene in 2-methyl-1-butanol and 3-methyl-1-butanol in the temperature range of (250 to 330) K and 2-methyl-2-butanol in the temperature range of (270 to 330) K were measured by a gas stripping method. A rigorous formula for evaluating the Henry's law constants from the gas stripping measurements was used for the data reduction of these highly volatile mixtures. The estimated uncertainties are about 2% for the Henry's law constants and 3% for the estimated infinite dilution activity coefficients. In the evaluation of the infinite dilution activity coefficients, the nonideality of the solute cannot be neglected, especially at higher temperatures. The estimated uncertainty of the infinite dilution activity coefficients includes 1% for nonideality.

    Copyright © 2005 American Chemical Society

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    Cited By

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    This article is cited by 10 publications.

    1. Yoshimori Miyano, Shunsuke Ashimori, Takumi Otuka, Takeshi Dairaku, Towaki Kitamoto, Yuki Kume, Yoko Tateishi, Yumi Nishiguchi, Risa Miura, and Takashi Mitani . Henry’s Law Constants and Infinite Dilution Activity Coefficients of Propane, Propene, Butane, 2-Methylpropane, 1-Butene, 2-Methylpropene, trans-2-Butene, cis-2-Butene, 1,3-Butadiene, Dimethyl Ether, Chloroethane, and 1,1-Difluoroethane in 2-Methylphenol, 3-Methylphenol, and 4-Methylphenol. Journal of Chemical & Engineering Data 2010, 55 (11) , 4956-4960. https://doi.org/10.1021/je100529s
    2. Ellen Qian, Avi Gupta, Reese Neal, Grace Lee, Melanie Che, Lainey Wang, David Yue, Rachel Fischer, Megan Jodray, Erin Connolly, Shang Wang, Kelly Liu, Alex Zhang, Jingyi Dai, Siqi Zhu, William E. Acree, Michael H. Abraham. Development of Abraham model correlations for describing solute transfer into 2-methyl-1-butanol from both water and the gas phase from experimental solubility data of crystalline organic compounds. Physics and Chemistry of Liquids 2020, 58 (5) , 623-635. https://doi.org/10.1080/00319104.2019.1625050
    3. Igor A. Sedov, Timur M. Salikov, Ellen Qian, Anisha Wadawadigi, Olivia Zha, William E. Acree, Michael H. Abraham. Abraham model correlations for solute transfer into 2-methyl-2-butanol based on measured activity coefficient and solubility data at 298.15 K. Journal of Molecular Liquids 2019, 293 , 111454. https://doi.org/10.1016/j.molliq.2019.111454
    4. Christoph Hille, Stefan Ringe, Martin Deimel, Christian Kunkel, William E. Acree, Karsten Reuter, Harald Oberhofer. Generalized molecular solvation in non-aqueous solutions by a single parameter implicit solvation scheme. The Journal of Chemical Physics 2019, 150 (4) https://doi.org/10.1063/1.5050938
    5. Robert Franke, Bernd Hannebauer, Sebastian Jung. Accurate pre-calculation of limiting activity coefficients by COSMO-RS with molecular-class based parameterization. Fluid Phase Equilibria 2013, 340 , 11-14. https://doi.org/10.1016/j.fluid.2012.11.016
    6. Robert Franke, Bernd Hannebauer. On the influence of basis sets and quantum chemical methods on the prediction accuracy of COSMO-RS. Physical Chemistry Chemical Physics 2011, 13 (48) , 21344. https://doi.org/10.1039/c1cp22317h
    7. R. Franke, S. Jung, B. Hannebauer. Fallstudie zur Vorausberechnung Henryscher Koeffizienten. Chemie Ingenieur Technik 2010, 82 (3) , 265-272. https://doi.org/10.1002/cite.200900118
    8. R. Franke, B. Hannebauer, S. Jung. A Case Study in the Pre‐Calculation of Henry Coefficients. Chemical Engineering & Technology 2010, 33 (2) , 251-257. https://doi.org/10.1002/ceat.200900505
    9. Laura M. Sprunger, Sai S. Achi, Racheal Pointer, William E. Acree, Michael H. Abraham. Development of Abraham model correlations for solvation characteristics of secondary and branched alcohols. Fluid Phase Equilibria 2010, 288 (1-2) , 121-127. https://doi.org/10.1016/j.fluid.2009.10.024
    10. Yoshimori Miyano, Takahiro Kobashi, Hiroshi Shinjo, Shinya Kumada, Yusuke Watanabe, Wataru Niya, Yoko Tateishi. Henry’s law constants and infinite dilution activity coefficients of cis-2-butene, dimethylether, chloroethane, and 1,1-difluoroethane in methanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, isobutanol, tert-butanol, 1-pentanol, 2-pentanol, 3-pentanol, 2-methyl-1-butanol, 3-methyl-1-butanol, and 2-methyl-2-butanol. The Journal of Chemical Thermodynamics 2006, 38 (6) , 724-731. https://doi.org/10.1016/j.jct.2005.08.004

    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2005, 50, 1, 211–215
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je049723e
    Published October 30, 2004
    Copyright © 2005 American Chemical Society

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