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Critical Temperatures and Pressures of Straight-Chain Saturated Dicarboxylic Acids (C4 to C14)†

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Institute of Thermal Physics, Ural Branch of Russian Academy of Sciences, Amundsena Street, 106, 620016 Ekaterinburg, Russia
Institute of Organic Synthesis, Ural Branch of Russian Academy of Sciences, Sof'i Kovalevskoi Street, 20, 620219 Ekaterinburg, Russia
Cite this: J. Chem. Eng. Data 2004, 49, 6, 1515–1520
Publication Date (Web):September 15, 2004
https://doi.org/10.1021/je0498356
Copyright © 2004 American Chemical Society
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    Abstract

    The critical temperatures and pressures of nine saturated straight-chain dicarboxylic acids HOOC(CH2)nCOOH with n = 2, 3, 4, 5, 6, 7, 8, 10, and 12 have been measured. All of the acids investigated are thermally unstable at their critical points. The method of pulse heating of a wire probe immersed in the liquid under study has been used. Residence times are from (0.01 to 1) ms. The experimental critical properties of dicarboxylic acids have been compared with the values calculated by the group-contribution methods of Ambrose, Joback, and Reid, Constantinou and Gani, and Marrero and Gani.

    †

     This will be part of a special print edition containing papers reporting experimental results from the various projects of the Design Institute for Physical Properties of the American Institute of Chemical Engineers.

    *

     Corresponding author. E-mail:  [email protected].

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