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Isobaric Vapor−Liquid Equilibria of Binary Mixtures Containing the Carbonate Group −OCOO−

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UNILAB Research Center of Chemical Reaction Engineering, East China University of Science and Technology, Shanghai 200237, PR China
Cite this: J. Chem. Eng. Data 2005, 50, 2, 340–343
Publication Date (Web):January 19, 2005
https://doi.org/10.1021/je049859c
Copyright © 2005 American Chemical Society
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    Abstract

    Isobaric vapor−liquid equilibria (VLE) data for the four systems of dimethyl carbonate + ethylene carbonate, methanol + ethylene carbonate, dimethyl carbonate + ethylene glycol, and ethylene glycol + ethylene carbonate containing the carbonate group −OCOO−, which exist in the process of synthesizing DMC by transesterification of ethylene carbonate with methanol, have been measured at atmospheric pressure or under vacuum in an Ellis equilibrium still. The experimental VLE data are thermodynamically consistent, and the activity coefficients have been evaluated with the Wilson and NRTL equations, showing that the systems of dimethyl carbonate + ethylene glycol and ethylene glycol + ethylene carbonate have stronger nonideality. The results of this work are useful to the research on DMC synthesis by transesterification.

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     To whom correspondence should be addressed. E-mail:  yj.fang@ 163.com.

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