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Excess Enthalpies of {CH3(CH2)nCN, n = 5 to 12} + Methyl Methylthiomethyl Sulfoxide or + Dimethyl Sulfoxide at 298.15 K

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Department of Chemistry, Faculty of Science and Technology, Kinki University, Kowakae, Higashi-Osaka 577-8502, Japan
Cite this: J. Chem. Eng. Data 2004, 49, 4, 1046–1051
Publication Date (Web):June 5, 2004
https://doi.org/10.1021/je0499317
Copyright © 2004 American Chemical Society

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    Abstract

    Excess enthalpies of binary mixtures between each of {CH3(CH2)nCN (n = 5−12)} and methyl methylthiomethyl sulfoxide or dimethyl sulfoxide have been determined at 298.15 K. All mixtures show positive enthalpy changes over the whole range of mole fractions. Excess enthalpies of the mixtures of nitriles increased with increasing size of the aliphatic groups. The increments of dipole interaction terms of μ12μ22(r1 + r2)-6 on excess partial molar enthalpies at infinite dilution showed different behavior on the border of pentanenitrile.

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    Cited By

    This article is cited by 7 publications.

    1. Takayoshi Kimura,, Mohammed Abdullah Khan,, Tadashi Kamiyama, and, Masao Fujisawa. Thermodynamic Properties of d- and l-Tartaric Acid in Aqueous and Ethanol Solution at 298.15 K. Journal of Chemical & Engineering Data 2006, 51 (3) , 909-913. https://doi.org/10.1021/je050388j
    2. Takayoshi Kimura, Satoko Kido. Enthalpies of mixing of ethanol solution of chiral limonenes at 298.15 K. Journal of Thermal Analysis and Calorimetry 2010, 99 (1) , 87-93. https://doi.org/10.1007/s10973-009-0482-9
    3. Takayoshi Kimura, Sekai Iwama, Satoko Kido, Mohammad Abdullah Khan. Thermodynamic properties of ethanol solution of chiral camphors and its derivatives. The Journal of Chemical Thermodynamics 2009, 41 (10) , 1170-1177. https://doi.org/10.1016/j.jct.2009.05.005
    4. T. Kimura, T. Sato, M. Hirota, S. Takagi. Excess enthalpies of ketone+methyl methylthiomethyl sulfoxide or +dimethyl sulfoxide at 298.15 k. Journal of Thermal Analysis and Calorimetry 2008, 92 (2) , 381-389. https://doi.org/10.1007/s10973-007-8956-0
    5. T. Kimura, M. A. Khan, T. Kamiyama. Enthalpic changes on mixing two couples of S- and R-enantiomers which contained amino groups at 298.15 K. Journal of Thermal Analysis and Calorimetry 2006, 85 (3) , 575-580. https://doi.org/10.1007/s10973-006-7657-4
    6. T. Kimura, M. A. Khan, T. Kamiyama. Enthalpies of mixing and apparent molar volumes of ethanol solution of chiral dicarboxylic acids. Journal of Thermal Analysis and Calorimetry 2006, 85 (3) , 559-565. https://doi.org/10.1007/s10973-006-7662-7
    7. Takayoshi Kimura, Mohammed Abdullah Khan, Masakazu Ishii, Tadashi Kamiyama. Enthalpy change on mixing a couple of S ‐ and R ‐enantiomers of some chiral compounds at 298.15 K. Chirality 2006, 18 (8) , 581-586. https://doi.org/10.1002/chir.20285

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