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Compressed Liquid Densities and Excess Volumes of CO2 + Decane Mixtures from (313 to 363) K and Pressures up to 25 MPa

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Instituto Politécnico Nacional, ESIQIE, Laboratorio de Termodinámica, Edif. Z, Secc. 6, 1er piso, UPALM Zacatenco, 07738 Lindavista, México, D.F., México
Cite this: J. Chem. Eng. Data 2005, 50, 3, 1030–1037
Publication Date (Web):April 26, 2005
https://doi.org/10.1021/je050020m
Copyright © 2005 American Chemical Society
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    Abstract

    Experimental liquid densities of decane and of CO2 (1) + decane (2) binary mixtures (at five different compositions, x1 = 0.0551, 0.2369, 0.4536, 0.8114, and 0.9663) were measured from (313 to 363) K and at pressures up to 25 MPa. The densities of decane were fitted to the Benedict−Webb−Rubin−Starling equation of state (BWRS EoS). Excess molar volumes are calculated by using decane densities calculated from the BWRS EoS and CO2 densities calculated from the Span−Wagner EoS.

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