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Surface Properties of Dilute Solutions of Alkanes in Benzyl Alcohol

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Department of Chemistry, Faculty of Science, Bu-Ali Sina University, Hamadan, Iran
Cite this: J. Chem. Eng. Data 2006, 51, 1, 56–59
Publication Date (Web):December 13, 2005
https://doi.org/10.1021/je050159x
Copyright © 2006 American Chemical Society

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    Abstract

    Surface tensions of dilute solutions of cyclohexane, hexane, heptane, and nonane in benzyl alcohol were measured at various temperatures. Surface mole fractions were obtained from an extended Langmuir model. The results show that all of alkanes are surface active in benzyl alcohol and that their surface mole fractions are higher than their bulk mole fractions. The lyophobicity of solutes decreases with increasing temperature.

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    Cited By

    This article is cited by 16 publications.

    1. Kadakanchi Sandeepa, Tulasi S.V.R. Neeharika, Ravi Kumar K, Bankupalli Satyavathi, Prathap Kumar Thella. Determination of Solid–Liquid Phase Equilibrium of Benzoic Acid in Mono, Binary, and Ternary Systems and Their Correlation. Journal of Chemical & Engineering Data 2021, 66 (1) , 793-804. https://doi.org/10.1021/acs.jced.0c00873
    2. Tobias Klein, Shaomin Yan, Junwei Cui, Joseph W. Magee, Kenneth Kroenlein, Michael H. Rausch, Thomas M. Koller, Andreas P. Fröba. Liquid Viscosity and Surface Tension of n-Hexane, n-Octane, n-Decane, and n-Hexadecane up to 573 K by Surface Light Scattering. Journal of Chemical & Engineering Data 2019, 64 (9) , 4116-4131. https://doi.org/10.1021/acs.jced.9b00525
    3. Kai-Di Chen, Yi-Feng Lin, and Chein-Hsiun Tu . Densities, Viscosities, Refractive Indexes, and Surface Tensions for Mixtures of Ethanol, Benzyl Acetate, and Benzyl Alcohol. Journal of Chemical & Engineering Data 2012, 57 (4) , 1118-1127. https://doi.org/10.1021/je201009c
    4. Carolina Bermúdez-Salguero and Jesús Gracia-Fadrique , Encina Calvo and Alfredo Amigo . Densities, Refractive Indices, Speeds of Sound, and Surface Tensions for Dilute Aqueous Solutions of 2-Methyl-1-propanol, Cyclopentanone, Cyclohexanone, Cyclohexanol, and Ethyl Acetoacetate at 298.15 K. Journal of Chemical & Engineering Data 2011, 56 (10) , 3823-3829. https://doi.org/10.1021/je200468r
    5. Saeid Azizian and Nowrouz Bashavard. Surface Tension of Dilute Solutions of Alkanes in Cyclohexanol at Different Temperatures. Journal of Chemical & Engineering Data 2008, 53 (10) , 2422-2425. https://doi.org/10.1021/je8004112
    6. Karla Granados and, Jesús Gracia-Fadrique, , Alfredo Amigo and, Ramón Bravo. Refractive Index, Surface Tension, and Density of Aqueous Mixtures of Carboxylic Acids at 298.15 K. Journal of Chemical & Engineering Data 2006, 51 (4) , 1356-1360. https://doi.org/10.1021/je060084c
    7. G. Reza Vakili-Nezhaad, Majid Al-Wadhahi, Shamsa Al-Haddabi, Ali Vakilinejad, William E. Acree. Surface tension of binary organic mixtures based on a new dimensionless number. The Journal of Chemical Thermodynamics 2021, 152 , 106292. https://doi.org/10.1016/j.jct.2020.106292
    8. Simon Stephan, Stefan Becker, Kai Langenbach, Hans Hasse. Vapor-liquid interfacial properties of the system cyclohexane + CO2: Experiments, molecular simulation and density gradient theory. Fluid Phase Equilibria 2020, 518 , 112583. https://doi.org/10.1016/j.fluid.2020.112583
    9. Mostafa Lashkarbolooki, Mahdi Bayat. Prediction of surface tension of liquid normal alkanes, 1-alkenes and cycloalkane using neural network. Chemical Engineering Research and Design 2018, 137 , 154-163. https://doi.org/10.1016/j.cherd.2018.07.021
    10. D. I. Sagdeev, M. G. Fomina, G. Kh. Mukhamedzyanov, I. M. Abdulagatov. Experimental Study of the Density and Viscosity of $$n$$ -Heptane at Temperatures from 298 K to 470 K and Pressure upto 245 MPa. International Journal of Thermophysics 2013, 34 (1) , 1-33. https://doi.org/10.1007/s10765-012-1373-z
    11. Saeid Azizian, Tahere Fereidooni Moghadam. Derivation of a new equation for prediction of the thin layer depth of the extended-Langmuir model for dilute binary mixtures. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2011, 378 (1-3) , 67-71. https://doi.org/10.1016/j.colsurfa.2011.01.055
    12. Ch. Wohlfarth. Surface tension of cyclohexane. 2008, 172-173. https://doi.org/10.1007/978-3-540-75508-1_122
    13. Ch. Wohlfarth. Surface tension of hexane. 2008, 181-182. https://doi.org/10.1007/978-3-540-75508-1_130
    14. Ch. Wohlfarth. Surface tension of benzyl alcohol. 2008, 192-192. https://doi.org/10.1007/978-3-540-75508-1_138
    15. Ch. Wohlfarth. Surface tension of heptane. 2008, 202-204. https://doi.org/10.1007/978-3-540-75508-1_148
    16. Ch. Wohlfarth. Surface tension of nonane. 2008, 232-232. https://doi.org/10.1007/978-3-540-75508-1_171

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