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Surface Tensions and Densities of Oxalic, Malonic, Succinic, Maleic, Malic, and cis-Pinonic Acids

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    Surface Tensions and Densities of Oxalic, Malonic, Succinic, Maleic, Malic, and cis-Pinonic Acids
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    Finnish Meteorological Institute, Erik Palménin Aukio 1, P.O. Box 503, FI-00101 Helsinki, Finland, and Department of Physical Sciences, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2006, 51, 1, 255–260
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    https://doi.org/10.1021/je050366x
    Published December 6, 2005
    Copyright © 2006 American Chemical Society
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    Abstract

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    The surface tensions and densities of aqueous solutions of oxalic, malonic, succinic, maleic, malic, and cis-pinonic acids were measured as a function of the acid mole fraction at 25 °C. These organic acids are typically found in atmospheric aerosols. The surface tensions were measured using the Wilhelmy plate method and were measured also as a function of temperature. The measurable mole fractions were limited by the solubilities of the acids at room temperature. All the acids lower the surface tension of pure water. cis-Pinonic acid lowers the surface tension most effectively. The measured surface tensions were fitted with equations covering the acid mole fraction range from zero to one and assuming a theoretical surface tension of pure, supercooled acids at room temperature. The measured densities were also fitted in a similar way. These equations can be used in model calculations of formation and growth of atmospheric particles.

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     Corresponding author. E-mail:  [email protected].

    †

     Finnish Meteorological Institute.

    ‡

     University of Helsinki.

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    Cite this: J. Chem. Eng. Data 2006, 51, 1, 255–260
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je050366x
    Published December 6, 2005
    Copyright © 2006 American Chemical Society
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