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Evaluation of the Vaporization, Fusion, and Sublimation Enthalpies of the 1-Alkanols:  The Vaporization Enthalpy of 1-, 6-, 7-, and 9-Heptadecanol, 1-Octadecanol, 1-Eicosanol, 1-Docosanol, 1-Hexacosanol, and Cholesterol at T = 298.15 K by Correlation Gas Chromatography

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    Evaluation of the Vaporization, Fusion, and Sublimation Enthalpies of the 1-Alkanols:  The Vaporization Enthalpy of 1-, 6-, 7-, and 9-Heptadecanol, 1-Octadecanol, 1-Eicosanol, 1-Docosanol, 1-Hexacosanol, and Cholesterol at T = 298.15 K by Correlation Gas Chromatography
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    Department of Chemistry and Biochemistry, University of MissouriSt. Louis, St. Louis, Missouri 63121
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2006, 51, 2, 475–482
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    https://doi.org/10.1021/je0503857
    Published January 17, 2006
    Copyright © 2006 American Chemical Society
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    Abstract

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    The vaporization enthalpies and vapor pressures of 1-, 6-, 7-, and 9-heptadecanol, 1-octadecanol, 1-eicosanol, 1-docosanol, 1-hexacosanol and cholesterol at T = 298.15 K have been measured by correlation gas chromatography using as standards, the even carbon n-alkanols from 1-decanol to 1-octadecanol and 1-pentadecanol. Fusion enthalpies for the all of these compounds were either measured by DSC or obtained from the literature. Adjusted to T = 298.15 K, the fusion and vaporization enthalpies were combined to provide sublimation enthalpies. The sublimation enthalpies were compared to existing literature values. Agreement between the two sets of values when available was generally very good.

    Copyright © 2006 American Chemical Society

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    †

     Visiting summer student, 2000, Brown University.

    ‡

     1999 NSF STARS high school participant.

    §

     2000 NSF STARS high school participant.

    ‖

     2005 STARS high school participant.

    *

     Corresponding author. E-mail:  [email protected]. Phone:  (314)516-5377.

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    Tables including retention times and a summary of each correlation. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cite this: J. Chem. Eng. Data 2006, 51, 2, 475–482
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je0503857
    Published January 17, 2006
    Copyright © 2006 American Chemical Society
    Request reuse permissions

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