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Evaluation of the Vaporization, Fusion, and Sublimation Enthalpies of the 1-Alkanols:  The Vaporization Enthalpy of 1-, 6-, 7-, and 9-Heptadecanol, 1-Octadecanol, 1-Eicosanol, 1-Docosanol, 1-Hexacosanol, and Cholesterol at T = 298.15 K by Correlation Gas Chromatography

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Department of Chemistry and Biochemistry, University of MissouriSt. Louis, St. Louis, Missouri 63121
Cite this: J. Chem. Eng. Data 2006, 51, 2, 475–482
Publication Date (Web):January 17, 2006
https://doi.org/10.1021/je0503857
Copyright © 2006 American Chemical Society
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    Abstract

    The vaporization enthalpies and vapor pressures of 1-, 6-, 7-, and 9-heptadecanol, 1-octadecanol, 1-eicosanol, 1-docosanol, 1-hexacosanol and cholesterol at T = 298.15 K have been measured by correlation gas chromatography using as standards, the even carbon n-alkanols from 1-decanol to 1-octadecanol and 1-pentadecanol. Fusion enthalpies for the all of these compounds were either measured by DSC or obtained from the literature. Adjusted to T = 298.15 K, the fusion and vaporization enthalpies were combined to provide sublimation enthalpies. The sublimation enthalpies were compared to existing literature values. Agreement between the two sets of values when available was generally very good.

    †

     Visiting summer student, 2000, Brown University.

    ‡

     1999 NSF STARS high school participant.

    §

     2000 NSF STARS high school participant.

    ‖

     2005 STARS high school participant.

    *

     Corresponding author. E-mail:  [email protected]. Phone:  (314)516-5377.

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