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Volumetric and Viscosity Properties of Monosaccharides in Aqueous Amino Acid Solutions at 298.15 K

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School of Chemistry and Environmental Science, Henan Normal University, Xinxiang, Henan 453007, People's Republic of China
Cite this: J. Chem. Eng. Data 2006, 51, 3, 919–927
Publication Date (Web):April 1, 2006
https://doi.org/10.1021/je050412t
Copyright © 2006 American Chemical Society
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    Abstract

    Apparent molar volumes VΦ,S and viscosity B-coefficients for d-(+)-glucose, d-(+)-galactose, d-(+)-xylose, and d-(−)-ribose in aqueous amino acid (glycine or l-alanine) solutions have been determined respectively from density and viscosity measurements at 298.15 K. Infinite-dilution apparent molar volumes for the saccharides in aqueous glycine or l-alanine solutions have been evaluated, together with the standard transfer volumes Δt of the saccharides from water to aqueous amino acid solutions. It is shown that values of transfer volumes and viscosity B-coefficients are positive and increase with increasing amino acid contents. Volumetric parameters indicating the interactions of saccharides with amino acids in water have been obtained from the transfer volumes of the saccharides. The interactions between saccharides and amino acids are discussed in terms of the structural interaction model and the stereo structure of monosaccharide molecules.

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     Corresponding author. E-mail:  [email protected].

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    97. Anil Kumar Nain, Monika Lather, Rakesh Kumar Sharma. Study of solute–solute and solute–solvent interactions of l-methionine in aqueous-sucrose solutions at different temperatures. The Journal of Chemical Thermodynamics 2013, 58 , 101-109. https://doi.org/10.1016/j.jct.2012.11.001
    98. Parampaul K. Banipal, Amanpreet K. Hundal. Viscometric studies on saccharides in aqueous magnesium chloride solutions at T=(288.15 to 318.15)K. The Journal of Chemical Thermodynamics 2012, 51 , 70-76. https://doi.org/10.1016/j.jct.2012.02.016
    99. Y.J. Chen, X.P. Xuan, H.H. Zhang, K.L. Zhuo. Conductivities of 1-alkyl-3-methylimidazolium chloride ionic liquids in monosaccharide+water solutions at 298.15K. Fluid Phase Equilibria 2012, 316 , 164-171. https://doi.org/10.1016/j.fluid.2011.11.028
    100. Anil Kumar Nain, Renu Pal, Rakesh Kumar Sharma. Physicochemical study of solute–solute and solute–solvent interactions of l-histidine in water+sucrose solutions at different temperatures. Journal of Molecular Liquids 2012, 165 , 154-160. https://doi.org/10.1016/j.molliq.2011.11.003
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