ACS Publications. Most Trusted. Most Cited. Most Read
Surface Tension of Liquid Fluorocompounds
My Activity

Figure 1Loading Img
    Article

    Surface Tension of Liquid Fluorocompounds
    Click to copy article linkArticle link copied!

    View Author Information
    CICECO, Departamento de Química, Universidade de Aveiro, 3810-193 Aveiro, Portugal
    Other Access Options

    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2006, 51, 5, 1820–1824
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je060199g
    Published July 29, 2006
    Copyright © 2006 American Chemical Society

    Abstract

    Click to copy section linkSection link copied!

    This work aims at studying the surface tension of some linear, cyclic, aromatic, and α-substituted perfluorocarbons. Despite its fundamental interest, information about this property for these compounds is scarce, and the available data are old and present strong discrepancies among each other. The measurements were carried out in the temperature range (283 to 327) K with the Du Noüy ring method. The analysis of the experimental data shows that the molecular structure is an important factor in the surface behavior of the studied compounds since the aromatic fluorocompounds present the highest surface tensions, followed by the cyclic and substituted fluorocompounds. The linear n-perfluoroalkanes exhibit the lowest surface tension values, slightly increasing with the carbon number. The surface thermodynamic functions such as surface entropy and enthalpy were derived from surface tension values and are also reported. The experimental data were compared against the Faizullin correlation, and it is shown that this correlation describes the measured surface tensions with deviations inferior to 4 %.

    Copyright © 2006 American Chemical Society

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    *

     Corresponding author. Fax:  +351 234 370 084. E-mail:  [email protected].

    Cited By

    Click to copy section linkSection link copied!
    Citation Statements
    Explore this article's citation statements on scite.ai

    This article is cited by 61 publications.

    1. Manuella El Haber, Violaine Gérard, Judith Kleinheins, Corinne Ferronato, Barbara Nozière. Measuring the Surface Tension of Atmospheric Particles and Relevant Mixtures to Better Understand Key Atmospheric Processes. Chemical Reviews 2024, 124 (19) , 10924-10963. https://doi.org/10.1021/acs.chemrev.4c00173
    2. Marina Tsianou Dmitry Bedrov Paschalis Alexandridis . Surfactants in the Environment: Self-Assembly of PFAS Pollutants in Solution and at Interfaces. , 443-462. https://doi.org/10.1021/bk-2023-1457.ch016
    3. Johannes Jaegers, Sven Haferkamp, Oliver Arnolds, Daniel Moog, Anna Wrobeln, Fabian Nocke, Miriam Cantore, Stefanie Pütz, Anne Hartwig, Rico Franzkoch, Olympia Ekaterini Psathaki, Holger Jastrow, Carsten Schauerte, Raphael Stoll, Michael Kirsch, Katja Bettina Ferenz. Deciphering the Emulsification Process to Create an Albumin-Perfluorocarbon-(o/w) Nanoemulsion with High Shelf Life and Bioresistivity. Langmuir 2022, 38 (34) , 10351-10361. https://doi.org/10.1021/acs.langmuir.1c03388
    4. Susanne Dogan, Michael Paulus, Göran Surmeier, Kevin Foryt, Katharina Brägelmann, Metin Tolan. Nondestructive Compression and Fluidization of Phospholipid Monolayers by Gaseous and Aerolized Perfluorocarbons: Promising Substances for Lung Surfactant Treatment. Langmuir 2022, 38 (21) , 6690-6699. https://doi.org/10.1021/acs.langmuir.2c00617
    5. Atip Lawanprasert, Alda Chau, Janna N. Sloand, Sean Hannifin, Scott H. Medina. Tuning the Interfacial Properties of Fluorous Colloids Toward Ultrasound Programmable Bioactivity. ACS Applied Materials & Interfaces 2021, 13 (5) , 5989-5998. https://doi.org/10.1021/acsami.0c20352
    6. Chee Leng Lay, Charlynn Sher Lin Koh, Yih Hong Lee, Gia Chuong Phan-Quang, Howard Yi Fan Sim, Shi Xuan Leong, Xuemei Han, In Yee Phang, Xing Yi Ling. Two-Photon-Assisted Polymerization and Reduction: Emerging Formulations and Applications. ACS Applied Materials & Interfaces 2020, 12 (9) , 10061-10079. https://doi.org/10.1021/acsami.9b20911
    7. Ross Lundy, Conor Byrne, Justin Bogan, Kevin Nolan, Maurice N. Collins, Eric Dalton, and Ryan Enright . Exploring the Role of Adsorption and Surface State on the Hydrophobicity of Rare Earth Oxides. ACS Applied Materials & Interfaces 2017, 9 (15) , 13751-13760. https://doi.org/10.1021/acsami.7b01515
    8. M. B. Oliveira, F. Llovell, J. A. P. Coutinho, and L. F. Vega . New Procedure for Enhancing the Transferability of Statistical Associating Fluid Theory (SAFT) Molecular Parameters: The Role of Derivative Properties. Industrial & Engineering Chemistry Research 2016, 55 (37) , 10011-10024. https://doi.org/10.1021/acs.iecr.6b02205
    9. Andreia Luís, Karina Shimizu, João M. M. Araújo, Pedro J. Carvalho, José A. Lopes-da-Silva, José N. Canongia Lopes, Luís Paulo N. Rebelo, João A. P. Coutinho, Mara G. Freire, and Ana B. Pereiro . Influence of Nanosegregation on the Surface Tension of Fluorinated Ionic Liquids. Langmuir 2016, 32 (24) , 6130-6139. https://doi.org/10.1021/acs.langmuir.6b00209
    10. J. Y. Lee, S. Pechook, B. Pokroy, and J. S. Yeo . Multilevel Hierarchy of Fluorinated Wax on CuO Nanowires for Superoleophobic Surfaces. Langmuir 2014, 30 (51) , 15568-15573. https://doi.org/10.1021/la5040273
    11. Rolf E. Isele-Holder and Ahmed E. Ismail . Atomistic Potentials for Trisiloxane, Alkyl Ethoxylate, and Perfluoroalkane-Based Surfactants with TIP4P/2005 and Application to Simulations at the Air–Water Interface. The Journal of Physical Chemistry B 2014, 118 (31) , 9284-9297. https://doi.org/10.1021/jp502975p
    12. Samuel V. D. Freitas, Mariana B. Oliveira, António J. Queimada, Maria Jorge Pratas, Álvaro S. Lima, and João A. P. Coutinho . Measurement and Prediction of Biodiesel Surface Tensions. Energy & Fuels 2011, 25 (10) , 4811-4817. https://doi.org/10.1021/ef201217q
    13. Pedro J. Carvalho, Catarina M. S. S. Neves, and João A. P. Coutinho. Surface Tensions of Bis(trifluoromethylsulfonyl)imide Anion-Based Ionic Liquids. Journal of Chemical & Engineering Data 2010, 55 (9) , 3807-3812. https://doi.org/10.1021/je100253m
    14. Madhuvanthi A. Kandadai, Praveena Mohan, Genyao Lin, Anthony Butterfield, Mikhail Skliar and Jules J. Magda . Comparison of Surfactants Used to Prepare Aqueous Perfluoropentane Emulsions for Pharmaceutical Applications. Langmuir 2010, 26 (7) , 4655-4660. https://doi.org/10.1021/la100307r
    15. Pedro J. Carvalho, Mara G. Freire, Isabel M. Marrucho, António J. Queimada and João A. P. Coutinho . Surface Tensions for the 1-Alkyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide Ionic Liquids. Journal of Chemical & Engineering Data 2008, 53 (6) , 1346-1350. https://doi.org/10.1021/je800069z
    16. Mara G. Freire, Abel G. M. Ferreira, Isabel M. A. Fonseca, Isabel M. Marrucho and João A. P. Coutinho . Viscosities of Liquid Fluorocompounds. Journal of Chemical & Engineering Data 2008, 53 (2) , 538-542. https://doi.org/10.1021/je700632z
    17. Mara G. Freire,, Lígia Gomes,, Luís M. N. B. F. Santos,, Isabel M. Marrucho, and, João A. P. Coutinho. Water Solubility in Linear Fluoroalkanes Used in Blood Substitute Formulations. The Journal of Physical Chemistry B 2006, 110 (45) , 22923-22929. https://doi.org/10.1021/jp0622942
    18. Bruno Linclau. Physical Properties of Fluorinated Compounds. 2024, 1-56. https://doi.org/10.1002/9780470682531.pat1033
    19. Egor V. Lupachev, Andrey A. Voshkin, Alexey V. Kisel’, Nikolai N. Kulov, Yulia A. Zakhodyaeva, Andrei V. Polkovnichenko. Separation of an Industrial Mixture of Decalin or Naphthalene Fluorination Products: Cis-Perfluorodecalin, Trans-Perfluorodecalin and Perfluoro(butylcyclohexane): Physicochemical, Thermophysical, and Spectral Data. Processes 2023, 11 (11) , 3208. https://doi.org/10.3390/pr11113208
    20. Mitra Aliabouzar, Oliver D. Kripfgans, J. Brian Fowlkes, Mario L. Fabiilli. Bubble nucleation and dynamics in acoustic droplet vaporization: a review of concepts, applications, and new directions. Zeitschrift für Medizinische Physik 2023, 33 (3) , 387-406. https://doi.org/10.1016/j.zemedi.2023.01.004
    21. Katja Steck, Jonathan Dijoux, Natalie Preisig, Victor Bouylout, Cosima Stubenrauch, Wiebke Drenckhan. Fluorocarbon vapors slow down coalescence in foams: influence of surfactant concentration. Colloid and Polymer Science 2023, 301 (7) , 685-695. https://doi.org/10.1007/s00396-023-05129-7
    22. Xilei Wu, Jiongliang Huang, Yuan Zhuang, Ying Liu, Jialiang Yang, Hongsheng Ouyang, Xiaohong Han. Prediction Models of Saturated Vapor Pressure, Saturated Density, Surface Tension, Viscosity and Thermal Conductivity of Electronic Fluoride Liquids in Two-Phase Liquid Immersion Cooling Systems: A Comprehensive Review. Applied Sciences 2023, 13 (7) , 4200. https://doi.org/10.3390/app13074200
    23. Mitra Aliabouzar, Oliver D. Kripfgans, Jonathan B. Estrada, J. Brian Fowlkes, Mario L. Fabiilli. Multi-time scale characterization of acoustic droplet vaporization and payload release of phase-shift emulsions using high-speed microscopy. Ultrasonics Sonochemistry 2022, 88 , 106090. https://doi.org/10.1016/j.ultsonch.2022.106090
    24. Samhitha Kancharla, Paschalis Alexandridis, Marina Tsianou. Sequestration of per- and polyfluoroalkyl substances (PFAS) by adsorption: Surfactant and surface aspects. Current Opinion in Colloid & Interface Science 2022, 58 , 101571. https://doi.org/10.1016/j.cocis.2022.101571
    25. Mitra Aliabouzar, Oliver Kripfgans, Jonathan Estrada, Jeffry Fowlkes, Mario Fabiilli. Multi-Time Scale Characterization of Acoustic Droplet Vaporization and Payload Release of Phase-Shift Emulsions. SSRN Electronic Journal 2022, 26 https://doi.org/10.2139/ssrn.4120358
    26. Hari O. S. Yadav, Shogo Harada, An-Tsung Kuo, Shingo Urata, Wataru Shinoda. Hemimicelle formation of semi-fluorocarbon chains at air–water interface: coarse-grained molecular dynamics study with an extension of the SPICA force field. Molecular Physics 2021, 119 (19-20) https://doi.org/10.1080/00268976.2021.1910355
    27. Katja Steck, Martin Hamann, Sébastien Andrieux, Pierre Muller, Patrick Kékicheff, Cosima Stubenrauch, Wiebke Drenckhan. Fluorocarbon Vapors Slow Down Coalescence in Foams. Advanced Materials Interfaces 2021, 8 (20) https://doi.org/10.1002/admi.202100723
    28. Mitra Aliabouzar, Oliver D. Kripfgans, William Y. Wang, Brendon M. Baker, J. Brian Fowlkes, Mario L. Fabiilli. Stable and transient bubble formation in acoustically-responsive scaffolds by acoustic droplet vaporization: theory and application in sequential release. Ultrasonics Sonochemistry 2021, 72 , 105430. https://doi.org/10.1016/j.ultsonch.2020.105430
    29. Johannes Jägers, Anna Wrobeln, Katja B. Ferenz. Perfluorocarbon-based oxygen carriers: from physics to physiology. Pflügers Archiv - European Journal of Physiology 2021, 473 (2) , 139-150. https://doi.org/10.1007/s00424-020-02482-2
    30. S. H. Baete, Y. De Deene. Gel Phantoms for Dynamic Contrast Enhanced MRI and Fluor-19 MRI Oximetry. 2020, 401-431. https://doi.org/10.1039/9781788013178-00401
    31. Jan Zawala, Kazimierz Malysa, Przemyslaw B. Kowalczuk. On importance of external conditions and properties of the interacting phases in formation and stability of symmetrical and unsymmetrical liquid films. Advances in Colloid and Interface Science 2020, 276 , 102085. https://doi.org/10.1016/j.cis.2019.102085
    32. Yue Wu, Joshua S. Heyne, Zhili Zhang. Simultaneous measurements of refractive index, surface tension, and evaporation rate of Jet A fuel. Applied Optics 2019, 58 (16) , 4326. https://doi.org/10.1364/AO.58.004326
    33. Romain Lhermerout, Kristina Davitt. Contact angle dynamics on pseudo-brushes: Effects of polymer chain length and wetting liquid. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2019, 566 , 148-155. https://doi.org/10.1016/j.colsurfa.2019.01.006
    34. Sara Zullino, Monica Argenziano, Ilaria Stura, Caterina Guiot, Roberta Cavalli. From Micro- to Nano-Multifunctional Theranostic Platform: Effective Ultrasound Imaging Is Not Just a Matter of Scale. Molecular Imaging 2018, 17 https://doi.org/10.1177/1536012118778216
    35. A. B. Pereiro, J. M. M. Araújo, J. M. S. S. Esperança, L. P. N. Rebelo. Surfactant Fluorinated Ionic Liquids. 2017, 79-102. https://doi.org/10.1039/9781788011839-00079
    36. Majid Moosavi, Fatemeh Khashei, Ali Sharifi, Mojtaba Mirzaei. The effects of temperature and alkyl chain length on the density and surface tension of the imidazolium-based geminal dicationic ionic liquids. The Journal of Chemical Thermodynamics 2017, 107 , 1-7. https://doi.org/10.1016/j.jct.2016.12.009
    37. Pedro Morgado, Olga Lobanova, Erich A. Müller, George Jackson, Miguel Almeida, Eduardo J. M. Filipe. SAFT-γ force field for the simulation of molecular fluids: 8. Hetero-segmented coarse-grained models of perfluoroalkylalkanes assessed with new vapour–liquid interfacial tension data. Molecular Physics 2016, 114 (18) , 2597-2614. https://doi.org/10.1080/00268976.2016.1218077
    38. Nityanshu Kumar, Gaurav Manik. Molecular dynamics simulations of polyvinyl acetate-perfluorooctane based anti-stain coatings. Polymer 2016, 100 , 194-205. https://doi.org/10.1016/j.polymer.2016.08.019
    39. P. Verdia, H. Q. N. Gunaratne, T. Y. Goh, J. Jacquemin, M. Blesic. A class of efficient short-chain fluorinated catanionic surfactants. Green Chemistry 2016, 18 (5) , 1234-1239. https://doi.org/10.1039/C5GC02790J
    40. N.M. Kovalchuk, A. Trybala, V. Starov, O. Matar, N. Ivanova. Fluoro- vs hydrocarbon surfactants: Why do they differ in wetting performance?. Advances in Colloid and Interface Science 2014, 210 , 65-71. https://doi.org/10.1016/j.cis.2014.04.003
    41. A. Mulero, I. Cachadiña. Recommended Correlations for the Surface Tension of Several Fluids Included in the REFPROP Program. Journal of Physical and Chemical Reference Data 2014, 43 (2) https://doi.org/10.1063/1.4878755
    42. A. Mulero, M.I. Parra, E.L. Sanjuán, I. Cachadiña. Analysis of specific correlations and general models for the surface tension of six liquid oxides. Fluid Phase Equilibria 2013, 358 , 60-67. https://doi.org/10.1016/j.fluid.2013.07.049
    43. A. Mulero, M.I. Parra, I. Cachadiña. The Somayajulu correlation for the surface tension revisited. Fluid Phase Equilibria 2013, 339 , 81-88. https://doi.org/10.1016/j.fluid.2012.11.038
    44. Steven H(ubert) Baete, Jan Vandecasteele, Luc Colman, Wilfried De Neve, Yves De Deene. An oxygen-consuming phantom simulating perfused tissue to explore oxygen dynamics and 19F MRI oximetry. Magnetic Resonance Materials in Physics, Biology and Medicine 2010, 23 (4) , 217-226. https://doi.org/10.1007/s10334-010-0219-6
    45. Behnam Zamanian, Mahdokht Masaeli, Jason W. Nichol, Masoud Khabiry, Matthew J. Hancock, Hojae Bae, Ali Khademhosseini. Interface‐Directed Self‐Assembly of Cell‐Laden Microgels. Small 2010, 6 (8) , 937-944. https://doi.org/10.1002/smll.200902326
    46. Mara G. Freire, Pedro J. Carvalho, Luís M.N.B.F. Santos, Lígia R. Gomes, Isabel M. Marrucho, João A.P. Coutinho. Solubility of water in fluorocarbons: Experimental and COSMO-RS prediction results. The Journal of Chemical Thermodynamics 2010, 42 (2) , 213-219. https://doi.org/10.1016/j.jct.2009.08.005
    47. A.M.A. Dias, F. Llovell, J.A.P. Coutinho, I.M. Marrucho, L.F. Vega. Thermodynamic characterization of pure perfluoroalkanes, including interfacial and second order derivative properties, using the crossover soft-SAFT EoS. Fluid Phase Equilibria 2009, 286 (2) , 134-143. https://doi.org/10.1016/j.fluid.2009.08.018
    48. Wen-Tien Tsai. Environmental hazards and health risk of common liquid perfluoro-n-alkanes, potent greenhouse gases. Environment International 2009, 35 (2) , 418-424. https://doi.org/10.1016/j.envint.2008.08.009
    49. Fatima R. Varanda, Lourdes F. Vega, João A.P. Coutinho, Isabel M. Marrucho. Liquid–liquid equilibrium of substituted perfluoro-n-octane+n-octane systems. Fluid Phase Equilibria 2008, 268 (1-2) , 85-89. https://doi.org/10.1016/j.fluid.2008.04.011
    50. Priscilla F.F. Amaral, Mara G. Freire, Maria Helena M. Rocha‐Leão, Isabel M. Marrucho, João A.P. Coutinho, Maria Alice Z. Coelho. Optimization of oxygen mass transfer in a multiphase bioreactor with perfluorodecalin as a second liquid phase. Biotechnology and Bioengineering 2008, 99 (3) , 588-598. https://doi.org/10.1002/bit.21640
    51. Ch. Wohlfarth. Surface tension of hexafluorobenzene. 2008, 161-161. https://doi.org/10.1007/978-3-540-75508-1_111
    52. Ch. Wohlfarth. Surface tension of tetradecafluorohexane. 2008, 162-162. https://doi.org/10.1007/978-3-540-75508-1_112
    53. Ch. Wohlfarth. Surface tension of octafluorotoluene. 2008, 187-187. https://doi.org/10.1007/978-3-540-75508-1_134
    54. Ch. Wohlfarth. Surface tension of tetradecafluoromethylcyclohexane. 2008, 188-188. https://doi.org/10.1007/978-3-540-75508-1_135
    55. Ch. Wohlfarth. Surface tension of hexadecafluoroheptane. 2008, 189-189. https://doi.org/10.1007/978-3-540-75508-1_136
    56. Ch. Wohlfarth. Surface tension of 1-bromoheptadecafluorooctane. 2008, 207-207. https://doi.org/10.1007/978-3-540-75508-1_151
    57. Ch. Wohlfarth. Surface tension of octadecafluorooctane. 2008, 208-208. https://doi.org/10.1007/978-3-540-75508-1_152
    58. Ch. Wohlfarth. Surface tension of eicosafluorononane. 2008, 223-223. https://doi.org/10.1007/978-3-540-75508-1_163
    59. Ch. Wohlfarth. Surface tension of 1,1,2,2,3,3,4,4,4a,5,5,6,6,7,7,8,8,8a-octadecafluorodecalin. 2008, 234-234. https://doi.org/10.1007/978-3-540-75508-1_173
    60. Mara G. Freire, Pedro J. Carvalho, Ana M. Fernandes, Isabel M. Marrucho, António J. Queimada, João A.P. Coutinho. Surface tensions of imidazolium based ionic liquids: Anion, cation, temperature and water effect. Journal of Colloid and Interface Science 2007, 314 (2) , 621-630. https://doi.org/10.1016/j.jcis.2007.06.003
    61. H. Schmitt, L. Frey, H. Ryssel, M. Rommel, C. Lehrer. UV nanoimprint materials: Surface energies, residual layers, and imprint quality. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena 2007, 25 (3) , 785-790. https://doi.org/10.1116/1.2732742

    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2006, 51, 5, 1820–1824
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je060199g
    Published July 29, 2006
    Copyright © 2006 American Chemical Society

    Article Views

    1529

    Altmetric

    -

    Citations

    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.