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Experimental Study of Thermodynamic Properties of Mixtures Containing Ionic Liquid 1-Ethyl-3-methylimidazolium Ethyl Sulfate Using Gas−Liquid Chromatography and Transpiration Method

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Department of Physical Chemistry, University of Rostock, Hermannstrasse 14, D-18055 Rostock, Germany
Chemical Faculty, Research Institute for Physical Chemical Problems, Belorussian State University, Minsk, Belarus
Cite this: J. Chem. Eng. Data 2006, 51, 6, 2138–2144
Publication Date (Web):October 3, 2006
https://doi.org/10.1021/je0602723
Copyright © 2006 American Chemical Society

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    Abstract

    Activity coefficients at infinite dilution of 46 solutes such as alkanes, alkenes, alkylbenzenes, linear and branched C1−C6 alcohols, esters, aldehydes, cyclohexanone oxime, and ε-caprolactam in the ionic liquid (IL) 1-ethyl-3-methylimidazolium ethyl sulfate or [EMIM][EtSO4] have been determined by gas chromatography using the IL as the stationary phase. The measurements were carried out at different temperatures between (302 and 396) K. From the temperature dependence of the limiting activity coefficients, partial molar excess enthalpies at infinite dilution of the solutes in the ILs have been derived. Vapor−liquid equilibria (VLE) of binary mixtures containing water with [EMIM][EtSO4] were studied using the transpiration method. VLE measurements were carried out over the broad concentration range at temperatures between (302.9 and 322.9) K. Activity coefficients γi of water in the [EMIM][EtSO4] have been determined from the VLE data and are described formally by using the NRTL equation. Furthermore, activity coefficients in infinity dilution of water in the IL [EMIM][EtSO4] have been derived by extrapolation to the infinite dilution of water.

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     On the leave from the Samara State Technical University, Samara, Russia.

    *

     Corresponding author. Telephone:  +49-381-498-6500. Fax:  +49-381-498-6502. E-mail: [email protected].

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    Two tables showing the critical constants and acentric factors of solutes and carrier gas used in calculation of virial coefficients and the experimental activity coefficients at infinity dilution. This material is available free of charge via the Internet at http://pubs.acs.org.

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