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Vapor−Liquid Equilibrium for Benzaldehyde with 1-Methylethylbenzene and for 2-Methyl-propan-2-ol with 2,4,4-Trimethyl-1-pentene

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Instytut Chemii Fizycznej PAN, Kasprzaka 44, 01-224 Warszawa, Poland
Cite this: J. Chem. Eng. Data 2007, 52, 1, 239–243
Publication Date (Web):November 9, 2006
https://doi.org/10.1021/je060359o
Copyright © 2007 American Chemical Society

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    Abstract

    The saturation pressure of 2-methylpropan-2-ol and 2,4,4-trimethyl-1-pentene at (305 to 356) K was measured by the ebulliometric method. The vapor−liquid equilibrium (VLE) (P, T, x, y) was measured by the ebulliometric method for the system benzaldehyde + 1-methylethylbenzene at 373.15 K and for the system 2-methyl-propan-2-ol + 2,4,4-trimethyl-1-pentene at (313.16, 333.14, and 353.18) K. A positive azeotrope was found in the last system. The experimental vapor pressures were correlated with Antoine equation and for 2-methyl-propan-2-ol. VLE was correlated with Redlich−Kister four-parameter equation.

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    Cited By

    This article is cited by 4 publications.

    1. William Acree, James S. Chickos. Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From 1880 to 2015. Part 1. C 1 − C 10. Journal of Physical and Chemical Reference Data 2016, 45 (3) , 033101. https://doi.org/10.1063/1.4948363
    2. Eni Bogdani, Rim Daoussi, Séverine Vessot, Jacques Jose, Julien Andrieu. Implementation and validation of the thermogravimetric method for the determination of equilibrium vapour pressure values and sublimation enthalpies of frozen organic formulations used in drug freeze–drying processes. Chemical Engineering Research and Design 2011, 89 (12) , 2606-2612. https://doi.org/10.1016/j.cherd.2011.05.004
    3. I. Wichterle, J. Linek, Z. Wagner, J.-C. Fontaine, K. Sosnkowska-Kehiaian, H.V. Kehiaian. Vapor-Liquid Equilibrium of the Mixture C4H10O + C8H16 (LB4626, EVLM 1131). 2008, 5709-5711. https://doi.org/10.1007/978-3-540-70745-5_2166
    4. I. Wichterle, J. Linek, Z. Wagner, J.-C. Fontaine, K. Sosnkowska-Kehiaian, H.V. Kehiaian. Vapor-Liquid Equilibrium of the Mixture C7H6O + C9H12 (LB4625, EVLM 1131). 2008, 1492-1493. https://doi.org/10.1007/978-3-540-70745-5_472

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