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Henry's Law Constants and Infinite Dilution Activity Coefficients of Propane, Propene, Butane, 2-Methylpropane, 1-Butene, 2-Methylpropene, trans-2-Butene, cis-2-Butene, 1,3-Butadiene, Dimethyl Ether, Chloroethane, and 1,1-Difluoroethane in Benzene, Toluene, o-Xylene, m-Xylene, p-Xylene, and Styrene
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    Henry's Law Constants and Infinite Dilution Activity Coefficients of Propane, Propene, Butane, 2-Methylpropane, 1-Butene, 2-Methylpropene, trans-2-Butene, cis-2-Butene, 1,3-Butadiene, Dimethyl Ether, Chloroethane, and 1,1-Difluoroethane in Benzene, Toluene, o-Xylene, m-Xylene, p-Xylene, and Styrene
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    Department of Chemistry and Bioscience, Kurashiki University of Science and the Arts, 2640 Nishinoura, Tsurajimacho, Kurashiki 712-8505, Japan
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2007, 52, 1, 291–297
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    https://doi.org/10.1021/je060395n
    Published December 5, 2006
    Copyright © 2007 American Chemical Society

    Abstract

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    Henry's law constants and infinite dilution activity coefficients of propane, propene, butane, 2-methylpropane, 1-butene, 2-methylpropene, trans-2-butene, cis-2-butene, 1,3-butadiene, dimethyl ether, chloroethane, and 1,1-difluoroethane in benzene, toluene, o-xylene, m-xylene, p-xylene, and styrene in the temperature range of (250 to 330) K were measured by a gas stripping method, and partial molar excess enthalpies and entropies were evaluated from the activity coefficients. A rigorous formula for evaluating the Henry's law constants from the gas stripping measurements was used for the data reduction of these highly volatile mixtures. The estimated uncertainties are about 2 % for the Henry's law constants and 3 % for the infinite dilution activity coefficients. The Henry's law constants followed the order of increasing Henry's law constant with decreases in the normal boiling point temperature of the liquefied gas except polar gases. In general, the partial molar excess enthalpies and entropies of gases in the aromatics increase with decreases of the polarities of the gases and increasing molecular size of the gases.

    Copyright © 2007 American Chemical Society

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     Corresponding author. E-mail:  [email protected]. Fax:  +81-86-440-1062.

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    This article is cited by 5 publications.

    1. Guilherme Duarte Ramos Matos, Gaetano Calabrò, David L. Mobley. Infinite Dilution Activity Coefficients as Constraints for Force Field Parametrization and Method Development. Journal of Chemical Theory and Computation 2019, 15 (5) , 3066-3074. https://doi.org/10.1021/acs.jctc.8b01029
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    3. Thomas Brouwer, Sascha R.A. Kersten, Gerrald Bargeman, Boelo Schuur. trends in solvent impact on infinite dilution activity coefficients of solutes reviewed and visualized using an algorithm to support selection of solvents for greener fluid separations. Separation and Purification Technology 2021, 272 , 118727. https://doi.org/10.1016/j.seppur.2021.118727
    4. Mikhail A. Varfolomeev, Ilnaz T. Rakipov, William E. Acree, Michela Brumfield, Michael H. Abraham. Examination of hydrogen-bonding interactions between dissolved solutes and alkylbenzene solvents based on Abraham model correlations derived from measured enthalpies of solvation. Thermochimica Acta 2014, 594 , 68-79. https://doi.org/10.1016/j.tca.2014.08.024
    5. Timothy W. Stephens, Nohelli E. De La Rosa, Mariam Saifullah, Shulin Ye, Vicky Chou, Amanda N. Quay, William E. Acree, Michael H. Abraham. Abraham model correlations for solute partitioning into o-xylene, m-xylene and p-xylene from both water and the gas phase. Fluid Phase Equilibria 2011, 308 (1-2) , 64-71. https://doi.org/10.1016/j.fluid.2011.06.010

    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2007, 52, 1, 291–297
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je060395n
    Published December 5, 2006
    Copyright © 2007 American Chemical Society

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