ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Figure 1Loading Img

Vapor−Liquid Equilibria for the 1,1-Difluoroethane (HFC-152a) + Propane (R-290) System

View Author Information
Division of Mechanical Engineering, Ajou University, Wonchun-dong, Yeongtong-gu, Suwon, 443-749, Korea, and Division of Mechanical Engineering, Graduate School, Ajou University, Wonchun-dong, Yeongtong-gu, Suwon, 443-749, Korea
Cite this: J. Chem. Eng. Data 2007, 52, 4, 1203–1208
Publication Date (Web):May 25, 2007
https://doi.org/10.1021/je060501l
Copyright © 2007 American Chemical Society

    Article Views

    253

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options

    Abstract

    Isothermal vapor−liquid equilibrium data of the binary system 1,1-difluoroethane (HFC-152a) + propane (R-290) were measured in the temperature range from 273.15 K to 313.15 K at 10 K intervals and in the composition range from 0.2 to 0.8 mole fraction of propane. The temperature, pressure, and compositions of the liquid and vapor phases were measured with a circulation-type apparatus. The experimental data were correlated with the Carnahan−Starling−De Santis, Peng−Robinson, and Redlich−Kwong−Soave equations of state. Azeotropic behavior was revealed near 0.73 mole fraction of propane. The vapor pressure of the azeotropic system was compared with those of chlorodifluoroethane (HCFC-22) and the zeotropic mixture of difluoroethane (HFC-32) + pentafluoroethane (HFC-125) (50−50) (alternative refrigerant blend R-410A), the zeotropic mixture of HFC-32 + HFC-125 + 1,1,1,2-tetrafluoroethane (HFC-134a) (23−25−52) (alternative refrigerant blend R-407C), dichlorodifluoromethane (HCFC-12), and HFC-134a. It was found that the vapor pressure of the azeotropic system was very close to that of HCFC-22. This azeotropic system has good potential to replace the use of HCFC-22 as a refrigerant.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    *

     To whom correspondence should be addressed. Fax:  82-31-213-7108. E-mail:  [email protected].

     Ajou University.

     Graduate School, Ajou University.

    Cited By

    This article is cited by 16 publications.

    1. Patrice Paricaud. Multipolar SAFT-VR Mie Equation of State: Predictions of Phase Equilibria in Refrigerant Systems with No Binary Interaction Parameter. The Journal of Physical Chemistry B 2023, 127 (13) , 3052-3070. https://doi.org/10.1021/acs.jpcb.3c01058
    2. Tao Yang, Xiaozhen Hu, Xianyang Meng, Jiangtao Wu. Vapor–Liquid Equilibria for the Binary and Ternary Systems of Difluoromethane (R32), 1,1-Difluoroethane (R152a), and 2,3,3,3-Tetrafluoroprop-1-ene (R1234yf). Journal of Chemical & Engineering Data 2018, 63 (3) , 771-780. https://doi.org/10.1021/acs.jced.7b00950
    3. Yanni Liu, Kaihua Guo, and Laiyun Lu . Vapor–Liquid Equilibrium Measurements for a Tetrafluoromethane + Propane System over a Temperature Range from (142.96 to 293.23) K. Journal of Chemical & Engineering Data 2012, 57 (12) , 3611-3616. https://doi.org/10.1021/je300806e
    4. Xueqiang Dong, Maoqiong Gong, Yu Zhang, Junsheng Liu and Jianfeng Wu . Isothermal Vapor−Liquid Equilibria for 1,1-Difluoroethane (R152a) + Propane (R290) at Temperatures between (254.31 and 287.94) K. Journal of Chemical & Engineering Data 2010, 55 (6) , 2145-2148. https://doi.org/10.1021/je900744x
    5. Eric W. Lemmon and Mark O. McLinden, Wolfgang Wagner. Thermodynamic Properties of Propane. III. A Reference Equation of State for Temperatures from the Melting Line to 650 K and Pressures up to 1000 MPa. Journal of Chemical & Engineering Data 2009, 54 (12) , 3141-3180. https://doi.org/10.1021/je900217v
    6. Shu-Xin Hou,, Yuan-Yuan Duan, and, Xiao-Dong Wang. Vapor−Liquid Equilibria Predictions for New Refrigerant Mixtures Based on Group Contribution Theory. Industrial & Engineering Chemistry Research 2007, 46 (26) , 9274-9284. https://doi.org/10.1021/ie070911i
    7. Seyed Hossein Mazloumi, Ali Haghtalab, Ali Karimi. Extension of a square-well equation of state for chain-like molecules using perturbed hard chain theory. Fluid Phase Equilibria 2023, 565 , 113659. https://doi.org/10.1016/j.fluid.2022.113659
    8. Kai Kang, Yaxiu Gu, Xiaopo Wang. Assessment and development of the viscosity prediction capabilities of entropy scaling method coupled with a modified binary interaction parameter estimation model for refrigerant blends. Journal of Molecular Liquids 2022, 358 , 119184. https://doi.org/10.1016/j.molliq.2022.119184
    9. Quan Zhong, Huan Zhao, Minting Wu, Yujie Huang, Youlin Zhang, Jun Shen. Isothermal vapor–liquid equilibrium of ternary system (difluoromethane + propane + trifluoroiodomethane) at temperatures ranging from 263.15 K to 303.15 K. The Journal of Chemical Thermodynamics 2021, 163 , 106587. https://doi.org/10.1016/j.jct.2021.106587
    10. Liu Zhang, Jin-xiu Zhao, Li-fang Yue, Hong-xing Zhou, Chun-li Ren. Cycle performance evaluation of various R134a/hydrocarbon blend refrigerants applied in vapor-compression heat pumps. Advances in Mechanical Engineering 2019, 11 (1) , 168781401881956. https://doi.org/10.1177/1687814018819561
    11. Qazi Nasir, Khalik M. Sabil, K.K. Lau. Measurement of isothermal (vapor + liquid) equilibria, (VLE) for binary (CH 4 + CO 2 ) from T = (240.35 to 293.15) K and CO 2 rich synthetic natural gas systems from T = (248.15 to 279.15) K. Journal of Natural Gas Science and Engineering 2015, 27 , 158-167. https://doi.org/10.1016/j.jngse.2015.08.045
    12. Yanjun Sun, Zhigang Liu. The study of binary interaction parameters on VLE for alternative refrigerant mixtures. Asia-Pacific Journal of Chemical Engineering 2015, 10 (3) , 476-482. https://doi.org/10.1002/apj.1884
    13. Peng Hu, Long-Xiang Chen, Ze-Shao Chen. A modified differential-model for interaction parameters in PR EoS with vdW mixing rules for mixtures containing HFCs and HCs. Fluid Phase Equilibria 2012, 324 , 64-69. https://doi.org/10.1016/j.fluid.2012.03.027
    14. José M.S. Fonseca, Ralf Dohrn, Stephanie Peper. High-pressure fluid-phase equilibria: Experimental methods and systems investigated (2005–2008). Fluid Phase Equilibria 2011, 300 (1-2) , 1-69. https://doi.org/10.1016/j.fluid.2010.09.017
    15. Xin Zou, Maoqiong Gong, Gaofei Chen, Zhaohu Sun, Jianfeng Wu. Experimental study on saturated flow boiling heat transfer of R290/R152a binary mixtures in a horizontal tube. Frontiers of Energy and Power Engineering in China 2010, 4 (4) , 527-534. https://doi.org/10.1007/s11708-010-0109-7
    16. I. Wichterle, J. Linek, Z. Wagner, J.-C. Fontaine, K. Sosnkowska-Kehiaian, H.V. Kehiaian. Vapor-Liquid Equilibrium of the Mixture C2H4F2 + C3H8 (LB4795, EVLM 1131). 2008, 3235-3237. https://doi.org/10.1007/978-3-540-70745-5_1174

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect