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Experimental Isobaric Vapor−Liquid Equilibrium for Binary Systems of Ethyl Methyl Carbonate + Methanol, + Ethanol, + Dimethyl Carbonate, or + Diethyl Carbonate at 101.3 kPa

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    Experimental Isobaric Vapor−Liquid Equilibrium for Binary Systems of Ethyl Methyl Carbonate + Methanol, + Ethanol, + Dimethyl Carbonate, or + Diethyl Carbonate at 101.3 kPa
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    School of Chemical Engineering and Technology, Tianjin University, Tianjin, People’s Republic of China, and Tianjin Univtech Co. Ltd., Tianjin, People’s Republic of China
    * To whom correspondence should be addressed. Tel.: +86 02227409476. E-mail: [email protected]
    †Tianjin University.
    ‡Tianjin Univtech Co. Ltd.
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2010, 55, 11, 4896–4902
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je100494z
    Published September 9, 2010
    Copyright © 2010 American Chemical Society
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    Abstract

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    Isobaric vapor−liquid equilibrium (VLE) data were measured for the binary systems ethyl methyl carbonate (EMC) + methanol, + ethanol, + dimethyl carbonate (DMC), and + diethyl carbonate (DEC) at 101.3 kPa using a vapor−liquid equilibrium still. The thermodynamic consistency of the experimental data was verified by Herington (1) method. The experimental VLE data were correlated with the Wilson, NRTL, and UNIQUAC activity coefficient models. The results show that the calculated values of vapor phase mole fraction and boiling temperature by the Wilson, NRTL, and UNIQUAC models agree well with the experimental data. Futhermore, azeotropic behavior was observed for the binary system of ethanol + EMC.

    Copyright © 2010 American Chemical Society

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    Cited By

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    This article is cited by 30 publications.

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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2010, 55, 11, 4896–4902
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je100494z
    Published September 9, 2010
    Copyright © 2010 American Chemical Society
    Request reuse permissions

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