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Thermodynamic Properties of Binary Mixtures of Tetrahydropyran with Anilines at 308.15 K

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Department of Chemistry, Maharshi Dayanand University, Rohtak 124001, India, P.D.M. College of Engineering for Women, Bhadurgarh, Haryana, India, and Department of Chemistry, A.I.J.H.M. College, Rohtak 124001, Haryana, India
†Part of the “Sir John S. Rowlinson Festschrift”.
* Corresponding author. Tel.: +91 9729071881. E-mail: [email protected]
‡Maharshi Dayanand University.
§A.I.J.H.M. College.
∥P.D.M. College of Engineering for Women.
Cite this: J. Chem. Eng. Data 2010, 55, 10, 4525–4531
Publication Date (Web):August 26, 2010
https://doi.org/10.1021/je1005196
Copyright © 2010 American Chemical Society

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    Abstract

    Excess molar volumes, VE, excess molar enthalpies, HE, speeds of sound, u, and vapor−liquid equilibrium data of tetrahydropyran (1) + aniline or N-methylaniline or 2-methylaniline (2) binary mixtures have been measured over the entire mole fraction range at 308.15 K. Speeds of sound and vapor−liquid equilibrium data have been utilized to predict isentropic compressibility changes of mixing, κSE, and excess Gibb’s free energy, GE. The observed VE, HE, κSE, and GE data have been analyzed in terms of Graph theory. It has been observed that VE, HE, κSE, and GE predicted by Graph theory compare well with their corresponding experimental values.

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