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Solubilities of 4-Formylbenzoic Acid in Ethanoic Acid, Water, and Ethanoic Acid/Water Mixtures with Different Compositions from (303.2 to 473.2) K

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State-Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
†Part of the “Sir John S. Rowlinson Festschrift”.
* To whom correspondence should be addressed. E-mail: [email protected]. Fax: +86-21-64253528.
Cite this: J. Chem. Eng. Data 2010, 55, 10, 4476–4478
Publication Date (Web):August 17, 2010
https://doi.org/10.1021/je100632c
Copyright © 2010 American Chemical Society

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    Abstract

    The solid−liquid equilibrium data of 4-formylbenzoic acid in four solvents was measured by the steady-state method at temperatures ranging from (303.2 to 473.2) K, including ethanoic acid, water, and aqueous ethanoic acid with 0.8 and 0.9 mass fractions of ethanoic acid, respectively. The solubility model modified from the Apelblat equation was used to correlate the experimental data. The average relative deviations of these correlations are 0.06 and 0.04 for solubilities in ethanoic acid and water at temperatures above 403.2 K, respectively, and no more than 0.03 for those in aqueous ethanoic acid.

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