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Enthalpies of Dilution of (2S,3R,4R,5R)-Hexane-1,2,3,4,5,6-hexol in Water and Aqueous Sodium Halide Solutions at T = (293.15 to 318.15) K

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Department of Chemistry and Chemical Engineering, Binzhou College, Binzhou, Shandong, 256603, People’s Republic of China, College of Chemistry and Chemical Engineering, Petroleum University of China, Qingdao, Shandong, 266555, People’s Republic of China, and College of Chemistry, Liaocheng University, Liaocheng, Shandong, 252059, People’s Republic of China
* Corresponding author. Department of Chemistry, Binzhou College, 5 Huanghe Road, Binzhou, Shandong 256603, People’s Republic of China. Tel.: +86-543-3190097. E-mail: [email protected] (Mingzhi Song).
†Binzhou College.
‡Liaocheng University.
§Petroleum University of China.
Cite this: J. Chem. Eng. Data 2010, 55, 11, 5201–5206
Publication Date (Web):September 29, 2010
https://doi.org/10.1021/je1007394
Copyright © 2010 American Chemical Society

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    Abstract

    The enthalpies of dilution of (2S,3R,4R,5R)-hexane-1,2,3,4,5,6-hexol in water and aqueous sodium halide solutions have been determined by isothermal flow-mix microcalorimetry at T = (293.15 to 318.15) K. Experiential equations of apparent enthalpies of dilution varying with the concentration of the polylol have been obtained from the experimental data in terms of the improved McMillan−Mayer theory. Enthalpic interaction coefficients, h2, h3, and h4, pairwise entropic interaction coefficient s2, and Gibbs free energy pairwise coefficient g2 have been calculated. The values of pairwise enthalpic interaction coefficient, h2, have been discussed in the light of solute−solute and solute−solvent interactions. The results indicate that the values of h2 show quite well that the straight-line dependence on temperature and pairwise entropic interaction coefficient, s2, is a constant in the experimental range of temperature.

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    Cited By

    This article is cited by 1 publications.

    1. Jia-min Liu, Li-yuan Zhu, Hua-qin Wang, Nan Chen, and Xin-gen Hu . Temperature Dependences and Enthalpic Discrimination of Homochiral Pairwise Interactions of Six α-Amino Acid Enantiomers in Pure Water. Journal of Chemical & Engineering Data 2015, 60 (5) , 1242-1249. https://doi.org/10.1021/je500825a