ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Figure 1Loading Img

Solubilities of Phenylphosphinic Acid, Methylphenylphosphinic Acid, Hexachlorocyclotriphosphazene, and Hexaphenoxycyclotriphosphazene in Selected Solvents

View Author Information
School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, People’s Republic of China
*Fax: +86-10-68911040. E-mail: [email protected]
Cite this: J. Chem. Eng. Data 2011, 56, 3, 661–670
Publication Date (Web):January 24, 2011
https://doi.org/10.1021/je1009812
Copyright © 2011 American Chemical Society

    Article Views

    1490

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options
    Supporting Info (2)»

    Abstract

    Phenylphosphinic acid (PPA), methylphenylphosphinic acid (MPPA), hexachlorocyclotriphosphazene (HCCP), and hexaphenoxycyclotriphosphazene (HPCCP) were prepared and characterized by elemental analysis, nuclear magnetic resonance, differential scanning calorimetry, and thermogravimetric analysis. Using a static analytical method, the solubilities of PPA, MPPA, HCCP, and HPCCP were measured in ten solvents and correlated with an empirical equation. The calculated results showed good agreement with the experimental data. Furthermore, using the Scatchard−Hildebrand model, activity coefficients have also been calculated and compared with the experimental values. The partial molar excess enthalpies at infinite dilution were also predicted.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Supporting Information

    ARTICLE SECTIONS
    Jump To

    The information of 1H NMR and 31P NMR spectra and the DSC and TGA graphs of PPA, MPPA, HCCP, and HPCCP, an analysis report for the uncertainty of DSC measurement, and the parameters of eq 2. This material is available free of charge via the Internet at http://pubs.acs.org.

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 22 publications.

    1. Mei-Xin Lv, Feng-Ying Bai, Guang Zeng, Zi-Xin You, Yong-Heng Xing, Zhan Shi. Manganese Cyclotriphosphazene Multicarboxylate Frameworks and Composite Encapsulated 1,3,6,8-Tetrakis(p-benzoic acid) Pyrene as Visualization of Highly Selective Fluorescence Sensors for Aromatic Compounds with NH2/NO2 Group. Crystal Growth & Design 2021, 21 (12) , 6824-6839. https://doi.org/10.1021/acs.cgd.1c00764
    2. Karen R. Winters, Jean-Luc Montchamp. Evaluation and Development of Methodologies for the Synthesis of Thiophosphinic Acids. The Journal of Organic Chemistry 2020, 85 (22) , 14545-14558. https://doi.org/10.1021/acs.joc.0c01151
    3. Dongmei Jia, Yuejin Li, Yaping Li, and Changhai Li . Measurement and Correlation of Solubility of 2-Chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine in Different Organic Solvents. Journal of Chemical & Engineering Data 2013, 58 (11) , 3183-3189. https://doi.org/10.1021/je400639m
    4. Chao-Jun Du, Li-Sheng Wang, Guo-Min Yu, and Gui-Qin Sun . Solid–Liquid Phase Equilibrium of N,N′-(Methylenedi-4,1-phenylene)bis(phosphoramidic acid) Tetraphenyl Ester in Selected Solvents. Industrial & Engineering Chemistry Research 2013, 52 (32) , 10916-10923. https://doi.org/10.1021/ie401349f
    5. Xian-Zhao Shao, Li-Sheng Wang, Guo-Qing Yan, and Guo-Min Yu . Determination and Correlation of Solubility of Tris(3-hydroxypropyl)phosphine Oxide in Selected Solvents. Journal of Chemical & Engineering Data 2013, 58 (3) , 598-604. https://doi.org/10.1021/je301029j
    6. Xian-Zhao Shao, Li-Sheng Wang, and Mi-Yi Li . Measurement and Correlation of the Solubilities of 2-[(6-Oxido-6H-dibenz[c,e][1,2]oxaphosphorin-6-yl)methyl]butanedioic Acid in Selected Solvents. Industrial & Engineering Chemistry Research 2012, 51 (13) , 5082-5089. https://doi.org/10.1021/ie202640z
    7. Farzaneh Radmanesh, Ernst J. R. Sudhölter, Alberto Tena, Maria G. Elshof, Nieck E. Benes. Thin‐Film Composite Cyclomatrix Poly(Phenoxy)Phosphazenes Membranes for Hot Hydrogen Separation. Advanced Materials Interfaces 2023, 10 (4) https://doi.org/10.1002/admi.202202077
    8. Jin Li, Xiaoli Ma, Yangfan Peng, Xing He, Zonggang Du, Zhi Yang. Solubility of mono-alkyl magnesium complex in pure and binary solvents: Measurement, correlation, thermodynamics from 268.15 K to 318.15 K. Journal of Molecular Liquids 2021, 337 , 116423. https://doi.org/10.1016/j.molliq.2021.116423
    9. Haodong Duan, Xiaolei Xu, Kangwei Leng, Ge Guo, Qing Yu, Xinjin Li, Yuxi Han, Jun Gao, Zhongwei Wang. AlCl3-catalyzed C-H p hosphination of benzene: A mechanistic study. Applied Catalysis A: General 2021, 611 , 117943. https://doi.org/10.1016/j.apcata.2020.117943
    10. Xue‐zheng Huang, Qi Jing, Yu‐hui Lin, Yi‐xiao Wang, Yi‐Fei Ye. Synthesis of A Novel Cyclotriphosphazene and Its Enhancement of Anti‐aging and Flame Retardancy of Polyolefin. ChemistrySelect 2020, 5 (30) , 9486-9491. https://doi.org/10.1002/slct.202001910
    11. Rajesh K. Singh, Shallu Chaudhary, D.N. Prasad, Sahil Kumar. An Atom-economic Efficient Synthesis of 1-Amidoalkyl-2-naphthols Mediated By Hexachlorocyclotriphosphazene (HCCP) as a Novel Catalyst. Letters in Organic Chemistry 2019, 16 (10) , 846-850. https://doi.org/10.2174/1570178616666181210103350
    12. Xiangdong Li, Minqing Zhang, Jinli Zhang, Wenpeng Li, Wei Li. Measurement and correlation of solubility of trimethylolethane in different pure solvents and binary mixtures. Chinese Journal of Chemical Engineering 2017, 25 (10) , 1473-1480. https://doi.org/10.1016/j.cjche.2017.05.007
    13. William Acree, James S. Chickos. Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds and Ionic Liquids. Sublimation, Vaporization, and Fusion Enthalpies from 1880 to 2015. Part 2. C11–C192. Journal of Physical and Chemical Reference Data 2017, 46 (1) https://doi.org/10.1063/1.4970519
    14. Xianzhao Shao, Zhizhou Li, Wei Wang, Hongguang Ge. Determination and correlation of solubility of phenylphosphonic acid in selected solvents. Journal of Molecular Liquids 2016, 219 , 201-205. https://doi.org/10.1016/j.molliq.2016.03.021
    15. Igor A. Sedov, Mikhail A. Stolov, Erin Hart, Damini Grover, Heidi Zettl, Victoria Koshevarova, Acree William E., Michael H. Abraham. Abraham model correlations for solute transfer into 2-ethoxyethanol from water and from the gas phase. Journal of Molecular Liquids 2015, 208 , 63-70. https://doi.org/10.1016/j.molliq.2015.03.051
    16. Xianzhao Shao, Hongguang Ge, Zhizhou Li, Chuanqing Ren, Junhong Wang. Solubility of methylphosphonic acid in selected organic solvents. Fluid Phase Equilibria 2015, 390 , 7-13. https://doi.org/10.1016/j.fluid.2015.01.009
    17. Guo-Min Yu, Li-Sheng Wang, Chao-Jun Du, Jian Sun. Solubilities of phosphoric acid, P , P ′-1,4-phenylene P , P , P ′, P ′-tetraphenyl ester in the organic solvents. Fluid Phase Equilibria 2015, 388 , 6-15. https://doi.org/10.1016/j.fluid.2014.12.034
    18. Gui-Qin Sun, Li-Sheng Wang, Jun-Chao Du, Chun-Mei Qi. Solubility of 1,3,2-dioxaphosphorinane-5,5-dimethyl-2-(2,4,6-tribromophenoxy)-2-oxide in selected solvents. Fluid Phase Equilibria 2013, 360 , 97-105. https://doi.org/10.1016/j.fluid.2013.09.023
    19. Chun-Mei Qi, Li-Sheng Wang, Jun-Chao Du, Guo-Min Yu, Gui-Qin Sun. Determination and correlation of solubilities of 1,2-bis (2-oxo-5,5-dimethyl-1,3,2-dioxyphosphacyclohexyl-2-imino) ethane in selected solvents. Fluid Phase Equilibria 2013, 360 , 343-350. https://doi.org/10.1016/j.fluid.2013.09.058
    20. Ru-Yi Jiang, Li-Sheng Wang. Solubilities of Hexaphenoxycyclotriphosphazene and Tri(2-cyanoethyl)phosphine in Selected Solvents: Measurement and Correlation. Journal of Solution Chemistry 2012, 41 (12) , 2107-2122. https://doi.org/10.1007/s10953-012-9930-4
    21. Dongmei Jia, Lisheng Wang, Changhai Li, Xinxin Wang. Solid–liquid phase equilibrium of glyphosate in selected solvents. Fluid Phase Equilibria 2012, 327 , 1-8. https://doi.org/10.1016/j.fluid.2012.05.003
    22. Xin Wang, Qingshan Li, Youbo Di, Guangzhong Xing. Preparation and properties of flame-retardant viscose fiber containing phosphazene derivative. Fibers and Polymers 2012, 13 (6) , 718-723. https://doi.org/10.1007/s12221-012-0718-3

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect