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Hydrogen Solubilities in the IUPAC Ionic Liquid 1-Hexyl-3-methylimidazolium Bis(Trifluoromethylsulfonyl)Imide

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School of Chemical and Petroleum Engineering, Shiraz University, Shiraz 71345, Iran
Department of Chemical Technology, Faculty of Science and Technology, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands
§ Laboratory of Process Equipment, Department of Process and Energy, Faculty of Mechanical, Maritime, and Materials Engineering, Delft University of Technology, Leeghwaterstraat 44, 2628 CA Delft, The Netherlands
Chemical Engineering Department, The Petroleum Institute, P.O. Box 2533, Abu Dhabi, United Arab Emirates
*Tel: +98-711-2303071. E-mail: [email protected]
Cite this: J. Chem. Eng. Data 2011, 56, 4, 1105–1107
Publication Date (Web):February 23, 2011
https://doi.org/10.1021/je101060k
Copyright © 2011 American Chemical Society

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    Abstract

    Because of some disagreements among published data on the solubilities of gases in ionic liquids, an IUPAC project to establish recommended values for some properties and suggest suitable measurement methods was initiated. As part of this large project, this study focused on the solubility of hydrogen gas in the ionic liquid 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. High-pressure gas solubilities were measured at various temperatures up to 370 K and pressures up to 12 MPa. The results showed very good agreement between the data measured in this laboratory and those of two other laboratories where the hydrogen solubilities in the same IUPAC sample were measured using differing experimental setups.

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