ACS Publications. Most Trusted. Most Cited. Most Read
My Activity

Figure 1Loading Img

Hydrogen Solubilities in the IUPAC Ionic Liquid 1-Hexyl-3-methylimidazolium Bis(Trifluoromethylsulfonyl)Imide

View Author Information
School of Chemical and Petroleum Engineering, Shiraz University, Shiraz 71345, Iran
Department of Chemical Technology, Faculty of Science and Technology, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands
§ Laboratory of Process Equipment, Department of Process and Energy, Faculty of Mechanical, Maritime, and Materials Engineering, Delft University of Technology, Leeghwaterstraat 44, 2628 CA Delft, The Netherlands
Chemical Engineering Department, The Petroleum Institute, P.O. Box 2533, Abu Dhabi, United Arab Emirates
*Tel: +98-711-2303071. E-mail: [email protected]
Cite this: J. Chem. Eng. Data 2011, 56, 4, 1105–1107
Publication Date (Web):February 23, 2011
Copyright © 2011 American Chemical Society

    Article Views





    Other access options


    Because of some disagreements among published data on the solubilities of gases in ionic liquids, an IUPAC project to establish recommended values for some properties and suggest suitable measurement methods was initiated. As part of this large project, this study focused on the solubility of hydrogen gas in the ionic liquid 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. High-pressure gas solubilities were measured at various temperatures up to 370 K and pressures up to 12 MPa. The results showed very good agreement between the data measured in this laboratory and those of two other laboratories where the hydrogen solubilities in the same IUPAC sample were measured using differing experimental setups.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.


    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Cited By

    This article is cited by 36 publications.

    1. Alejandro Rivera-Pousa, Raúl Lois-Cuns, Martín Otero-Lema, Hadrián Montes-Campos, Trinidad Méndez-Morales, Luis Miguel Varela. Size Matters: A Computational Study of Hydrogen Absorption in Ionic Liquids. Journal of Chemical Information and Modeling 2024, 64 (1) , 164-177.
    2. Philip Eor, Nicholas Tryon-Tasson, Seongyoung Kong, Emily A. Smith, Jared L. Anderson. Deconvoluting the Combined Effects of Gas Composition and Temperature on Olefin Selectivity for Separations Using Silver(I) Ions in Ionic Liquids. ACS Measurement Science Au 2023, 3 (1) , 53-61.
    3. Tobias Klein, Maximilian Piszko, Maren Lang, Julian Mehler, Peter S. Schulz, Michael H. Rausch, Cédric Giraudet, Thomas M. Koller, Andreas P. Fröba. Diffusivities in Binary Mixtures of [AMIM][NTf2] Ionic Liquids with the Dissolved Gases H2, He, N2, CO, CO2, or Kr Close to Infinite Dilution. Journal of Chemical & Engineering Data 2020, 65 (8) , 4116-4129.
    4. Haibo Zhai, Edward S. Rubin. Systems Analysis of Physical Absorption of CO2 in Ionic Liquids for Pre-Combustion Carbon Capture. Environmental Science & Technology 2018, 52 (8) , 4996-5004.
    5. Lan-yun Wang, Yong-liang Xu, Zhen-dong Li, Ya-nan Wei, and Jian-ping Wei . CO2/CH4 and H2S/CO2 Selectivity by Ionic Liquids in Natural Gas Sweetening. Energy & Fuels 2018, 32 (1) , 10-23.
    6. Lanyun Wang, Yanan Wei, Shaokun Wang, and Yongliang Xu . CO2 and CH4 Sorption by [N4 4 4 4][NTf2] Ionic Liquid Using Quartz Crystal Microbalance Experiments under Different Pressures. Journal of Chemical & Engineering Data 2017, 62 (4) , 1318-1325.
    7. Michael F. Friedrich, Simon Kokolakis, Martin Lucas, and Peter Claus . Measuring Diffusion and Solubility of Slightly Soluble Gases in [CnMIM][NTf2] Ionic Liquids. Journal of Chemical & Engineering Data 2016, 61 (4) , 1616-1624.
    8. Ramesh Singh, Eliseo Marin-Rimoldi, and Edward J. Maginn . A Monte Carlo Simulation Study To Predict the Solubility of Carbon Dioxide, Hydrogen, and Their Mixture in the Ionic Liquids 1-Alkyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide ([Cnmim+][Tf2N–], n = 4, 6). Industrial & Engineering Chemistry Research 2015, 54 (16) , 4385-4395.
    9. Indra Bahadur, Khalid Osman, Christophe Coquelet, Paramespri Naidoo, and Deresh Ramjugernath . Solubilities of Carbon Dioxide and Oxygen in the Ionic Liquids Methyl Trioctyl Ammonium Bis(trifluoromethylsulfonyl)imide, 1-Butyl-3-Methyl Imidazolium Bis(trifluoromethylsulfonyl)imide, and 1-Butyl-3-Methyl Imidazolium Methyl Sulfate. The Journal of Physical Chemistry B 2015, 119 (4) , 1503-1514.
    10. Zhigang Lei, Chengna Dai, and Biaohua Chen . Gas Solubility in Ionic Liquids. Chemical Reviews 2014, 114 (2) , 1289-1326.
    11. Omar M. Basha, Murphy J. Keller, David R. Luebke, Kevin P. Resnik, and Badie I. Morsi . Development of a Conceptual Process for Selective CO2 Capture from Fuel Gas Streams Using [hmim][Tf2N] Ionic Liquid as a Physical Solvent. Energy & Fuels 2013, 27 (7) , 3905-3917.
    12. L. J. Florusse, S. Raeissi, and C. J. Peters . An IUPAC Task Group Study: The Solubility of Carbon Monoxide in [hmim][Tf2N] at High Pressures. Journal of Chemical & Engineering Data 2011, 56 (12) , 4797-4799.
    13. Claudio A. Faúndez, Luis A. Forero, José O. Valderrama. Use of Thermodynamically Consistent Phase Equilibrium Data to Obtain a Generalized Padé-Type Model for the Henry’s Constants of Gases in Ionic Liquids. Processes 2024, 12 (2) , 343.
    14. Reza Nakhaei-Kohani, Saeid Atashrouz, Maryam Pourmahdi, Fahimeh Hadavimoghaddam, Karam Jabbour, Abdolhossein Hemmati-Sarapardeh, Ahmad Mohaddespour. Hydrogen solubility in ionic liquids: Application of a structure-based deep learning approach and equations of state. International Journal of Hydrogen Energy 2023, 48 (80) , 31234-31253.
    15. Aliyu Adebayo Sulaimon, Luqman Adam Azman, Syed Ali Qasim Zohair, Bamikole Joshua Adeyemi, Azmi B Shariff, Wan Zaireen Nisa Yahya. Predicting the Hydrogen Storage Potential of Ionic Liquids Using the Data Analytics Techniques. 2023
    16. Hossein Sakhaeinia, Elaheh Zare-Neyestanak, Mohammad Shokouhi. Evaluation of Anion Effect on the Solubility of Hydrogen Sulfide in Ionic Liquids Using Molecular Dynamics Simulation. Theoretical Foundations of Chemical Engineering 2020, 54 (5) , 949-960.
    17. Dmitry N. Lapshin, Miguel Jorge, Eleanor E. B. Campbell, Lev Sarkisov. On competitive gas adsorption and absorption phenomena in thin films of ionic liquids. Journal of Materials Chemistry A 2020, 8 (23) , 11781-11799.
    18. Jibril Abdulsalam, Jean Mulopo, Mutiu K. Amosa, Samson Bada, Rosemary Falcon, Bilainu O. Oboirien. Towards a cleaner natural gas production: recent developments on purification technologies. Separation Science and Technology 2019, 54 (15) , 2461-2497.
    19. Stephanie Peper, José M.S. Fonseca, Ralf Dohrn. High-pressure fluid-phase equilibria: Trends, recent developments, and systems investigated (2009–2012). Fluid Phase Equilibria 2019, 484 , 126-224.
    20. Andreia S.L. Gouveia, Lucas Ventaja, Liliana C. Tomé, Isabel M. Marrucho. Towards Biohydrogen Separation Using Poly(Ionic Liquid)/Ionic Liquid Composite Membranes. Membranes 2018, 8 (4) , 124.
    21. Azadeh Kordi, Fatemeh Sabzi. Thermodynamic modeling of hydrogen solubility in a series of ionic liquids. International Journal of Hydrogen Energy 2018, 43 (39) , 18296-18305.
    22. Yuya Hiraga, Alif Duereh, Richard L. Smith. Aspects of solvent polarity and solvent properties in developing efficient systems for processing biomass with ionic liquid mixtures and supercritical CO2. The Journal of Supercritical Fluids 2018, 134 , 12-20.
    23. Haibo Zhai, Edward S. Rubin. Technical and Economic Assessments of Ionic Liquids for Pre-Combustion CO2 Capture at IGCC Power Plants. Energy Procedia 2017, 114 , 2166-2172.
    24. Daniela Kerlé, Majid Namayandeh Jorabchi, Ralf Ludwig, Sebastian Wohlrab, Dietmar Paschek. A simple guiding principle for the temperature dependence of the solubility of light gases in imidazolium-based ionic liquids derived from molecular simulations. Physical Chemistry Chemical Physics 2017, 19 (3) , 1770-1780.
    25. Xiangyang Liu, Maogang He, Nan Lv, Houda Xu, Lihang Bai. Selective absorption of CO 2 from H 2 , O 2 and N 2 by 1-hexyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate. The Journal of Chemical Thermodynamics 2016, 97 , 48-54.
    26. Selva Pereda, Sona Raeissi, Alfonsina E. Andreatta, Susana B. Bottini, Maaike Kroon, Cor J. Peters. Modeling gas solubilities in imidazolium based ionic liquids with the [Tf 2 N] anion using the GC-EoS. Fluid Phase Equilibria 2016, 409 , 408-416.
    27. Reza Haghbakhsh, Sona Raeissi. Two simple correlations to predict viscosities of pure and aqueous solutions of ionic liquids. Journal of Molecular Liquids 2015, 211 , 948-956.
    28. Yuya Hiraga, Yoshiyuki Sato, Richard L. Smith. Development of a simple method for predicting CO2 enhancement of H2 gas solubility in ionic liquids. The Journal of Supercritical Fluids 2015, 96 , 162-170.
    29. Zhigang Lei, Chengna Dai, Qian Yang, Jiqin Zhu, Biaohua Chen. UNIFAC model for ionic liquid‐CO (H 2 ) systems: An experimental and modeling study on gas solubility. AIChE Journal 2014, 60 (12) , 4222-4231.
    30. Roberto Rinaldi. Solvents and Solvent Effects in Biomass Conversion. 2014, 74-98.
    31. Xiaoyan Ji, Christoph Held, Gabriele Sadowski. Modeling imidazolium-based ionic liquids with ePC-SAFT. Part II. Application to H2S and synthesis-gas components. Fluid Phase Equilibria 2014, 363 , 59-65.
    32. V.A. Toussaint, E. Kühne, A. Shariati, C.J. Peters. Solubility measurements of hydrogen in 1-butyl-3-methylimidazolium tetrafluoroborate and the effect of carbon dioxide and a selected catalyst on the hydrogen solubility in the ionic liquid. The Journal of Chemical Thermodynamics 2013, 59 , 239-242.
    33. S. Raeissi, A.M. Schilderman, C.J. Peters. High pressure phase behaviour of mixtures of hydrogen and the ionic liquid family [cnmim][Tf2N]. The Journal of Supercritical Fluids 2013, 73 , 126-129.
    34. Sona Raeissi, Cor J. Peters. Understanding temperature dependency of hydrogen solubility in ionic liquids, including experimental data in [bmim][Tf 2 N]. AIChE Journal 2012, 58 (11) , 3553-3559.
    35. Mostafa Lashkarblooki, Ali Zeinolabedini Hezave, Adel M. Al-Ajmi, Shahab Ayatollahi. Viscosity prediction of ternary mixtures containing ILs using multi-layer perceptron artificial neural network. Fluid Phase Equilibria 2012, 326 , 15-20.
    36. Ali Zeinolabedini Hezave, Mostafa Lashkarbolooki, Sona Raeissi. Using artificial neural network to predict the ternary electrical conductivity of ionic liquid systems. Fluid Phase Equilibria 2012, 314 , 128-133.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Your Mendeley pairing has expired. Please reconnect