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Corrected Values for Boiling Points and Enthalpies of Vaporization of Elements in Handbooks

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Ningbo Institute of Material Technology & Engineering, Chinese Academy of Sciences, No. 519 Zhuangshi Road, Zhenhai District, Ningbo, Zhejiang Province, P.R. China 315201, and Department of Materials, Queen Mary University of London, Mile End Road, London E1 4NS, United Kingdom
Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ, United Kingdom
School of Engineering Sciences, University of Southampton, Southampton, SO17 1BJ, United Kingdom
* Authors to whom correspondence should be addressed. E-mail: [email protected]. Tel.: 0044-23-8059-8697. Fax: 0044-23 8059 3016.
Cite this: J. Chem. Eng. Data 2011, 56, 2, 328–337
Publication Date (Web):January 11, 2011
https://doi.org/10.1021/je1011086
Copyright © 2011 American Chemical Society

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    Abstract

    The scientific community relies upon the veracity of the scientific data in handbooks and databases. In a previous work, the authors developed a systematic, intelligent, and potentially automatic method to detect errors in such resources based on artificial neural networks (ANNs). This method revealed variations from (10 to 900) % in tables of property data for elements in the periodic table and pointed out the ones that are most probably correct. In this paper, we focus on the details of employing this method for analyzing the data of boiling points and enthalpies of vaporization recorded in different handbooks. The method points out the values that are likely to be correct. To verify the method employed, a detailed discussion of the data with reference to the original literature sources is given as well as factors that may affect the accuracy of the prediction.

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