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Density and Viscosity of Aqueous (Piperazine + Carbon Dioxide) Solutions

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Department of Chemical Engineering, The University of Texas at Austin, 1 University Station C0400, Austin Texas 78712, United States
*E-mail: [email protected], [email protected]. Tel.: +1 (512) 471-7230. Fax: +1 (512) 471-7060.
Cite this: J. Chem. Eng. Data 2011, 56, 3, 574–581
Publication Date (Web):February 14, 2011
https://doi.org/10.1021/je1012263
Copyright © 2011 American Chemical Society
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    Abstract

    The density (ρ) and viscosity (μ) of aqueous (piperazine (PZ) + carbon dioxide (CO2)) solutions were measured over a temperature range of (293.15 to 333.15) K and concentration ranges of (1.5 to 7.0) mol·kg−1 PZ ((2 to 20) molal (m) PZ) and (0 to 4.0) mol·kg−1 CO2. Data for density and viscosity are presented in tabular form and include units useful for CO2 capture applications (CO2 loading and PZ concentration in m). Density data are analyzed as the ratio of ρ to the density of water to eliminate the effect of temperature. On this basis, ρ for (5 to 12) m PZ ((3.2 to 5.0) mol·kg−1 PZ) was correlated with a linear regression as a function of CO2 and PZ concentrations to within 0.78 % for all data. A prediction of ρ up to 20 m PZ induces an error of only 1.5 %. Viscosity data are analyzed in a similar way, and a regression for 8 m PZ (4.1 mol·kg−1 PZ) viscosity fit all experimental data within 6.0 %. The applicability of these regressions to online monitoring of a PZ based CO2 capture application is discussed.

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