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Densities, Speeds of Sound, and Viscosities of (l-Proline + Aqueous Glucose) and (l-Proline + Aqueous Sucrose) Solutions in the Temperature Range (298.15 to 323.15) K

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Department of Chemistry, Aligarh Muslim University, Aligarh 202002, U.P., India
E-mail: [email protected]. Phone: +91 571 2703515.
Cite this: J. Chem. Eng. Data 2011, 56, 9, 3504–3509
Publication Date (Web):July 28, 2011
https://doi.org/10.1021/je2000205
Copyright © 2011 American Chemical Society
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    Abstract

    Densities (ρ), speeds of sound (u), and viscosities (η) of l-proline in 1 mol·L–1 aqueous glucose/1 mol·L–1 aqueous sucrose solutions have been measured as a function of molal concentration of l-proline at temperatures of (298.15, 303.15, 308.15, 313.15, 318.15, and 323.15) K. Using the ρ and u data, the partial molar volumes (ϕvo), transfer partial molar volumes (Δtrϕvo), isentropic compressibilities (κs), partial molar isentropic compressibilities (ϕko), and transfer partial molar isentropic compressibilities (Δtrϕko) have been computed. The viscosity B-coefficients of the Jones–Dole equation also have been computed. The κs values decrease with increase in molal concentration of l-proline and also with increase in temperature. The ϕvo increase and ϕko decrease with an increase in temperature. The Δtrϕvo values increase and Δtrϕko values decrease with an increase in temperature. The trends of variations of experimental and computed parameters have been discussed in terms of hydrophilic–ionic group and hydrophilic–hydrophobic interactions operative in the systems.

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    Partial molar volumes and compressibilities of l-proline (Table S1), transfer partial molar volumes and compressibilities as a function of temperature (Table S2), and viscosity B-coefficients at different temperatures (Table S3). This material is available free of charge via the Internet at http://pubs.acs.org.

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    Get article recommendations from ACS based on references in your Mendeley library.

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    STEP 1:
    Click to create an ACS ID

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    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

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