ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Figure 1Loading Img

Activity Coefficients at Infinite Dilution of Organic Solutes in 1-Butyl-3-methylimidazolium Nitrate Using Gas−Liquid Chromatography

View Author Information
School of Chemical Engineering & the Environment, Beijing Institute of Technology, Beijing 100081, People's Republic of China
*E-mail: [email protected]. Fax: +86-10-68911040. Tel.: +86-10-68912660.
Cite this: J. Chem. Eng. Data 2011, 56, 5, 2730–2736
Publication Date (Web):April 12, 2011
https://doi.org/10.1021/je200050q
Copyright © 2011 American Chemical Society

    Article Views

    394

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options
    Supporting Info (1)»

    Abstract

    Activity coefficients at infinite dilution of 21 organic solutes in the ionic liquid 1-butyl-3-methylimidazolium nitrate ([BMIM][NO3]) have been determined using gas−liquid chromatography over a temperature range of (303.15 to 363.15) K with the ionic liquid as the stationary phase. The partial molar excess enthalpies at infinite dilution and the solubility parameters of ionic liquid were determined for the solutes from the temperature dependence of the experimental activity coefficient at infinite dilution values.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Supporting Information

    ARTICLE SECTIONS
    Jump To

    Experimental retention time tr and the input pressure Pi obtained in the measurement of activity coefficient at infinite dilution of organic solutes in ionic liquid 1-butyl-3-methylimidazolium nitrate. This material is available free of charge via the Internet at http://pubs.acs.org.

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 21 publications.

    1. Sérgio M. Vilas-Boas, Mónia A. R. Martins, Fábio R. Tentor, Gabriel Teixeira, Juliana G. Sgorlon, João A. P. Coutinho, Olga Ferreira, Simão P. Pinho. Imidazolium Chloride Ionic Liquid Mixtures as Separating Agents: Fuel Processing and Azeotrope Breaking. Energy & Fuels 2022, 36 (15) , 8552-8561. https://doi.org/10.1021/acs.energyfuels.2c01724
    2. Nanthinie Thangarajoo, Pranesh Matheswaran, Khairiraihanna Johari, Kiki A. Kurnia. Overview of Activity Coefficient of Methanol at Infinite Dilution in Ionic Liquids and their Modeling using Group Contribution Model. Journal of Chemical & Engineering Data 2019, 64 (4) , 1760-1769. https://doi.org/10.1021/acs.jced.8b01246
    3. Jiang Kan, Li-Sheng Wang, Xin-Xin Wang, and Jia-Dong Duan . Activity Coefficients of Organic Solutes at Infinite Dilution in the Ionic Liquids. 2. Organic Solutes in 1-Hexyl-3-methylimidazolium Nitrate and Gas–Liquid Partitioning and Interfacial Adsorption Using Gas–Liquid Chromatography. Industrial & Engineering Chemistry Research 2012, 51 (38) , 12479-12487. https://doi.org/10.1021/ie301591j
    4. Zhigang Lei, Chengna Dai, Xing Liu, Li Xiao, and Biaohua Chen . Extension of the UNIFAC Model for Ionic Liquids. Industrial & Engineering Chemistry Research 2012, 51 (37) , 12135-12144. https://doi.org/10.1021/ie301159v
    5. Brian Yoo, Waheed Afzal, and John M. Prausnitz . Solubility Parameters for Nine Ionic Liquids. Industrial & Engineering Chemistry Research 2012, 51 (29) , 9913-9917. https://doi.org/10.1021/ie300588s
    6. Kaikai Li, Fei Chang, Sensen Shi, Chongyang Jiang, Yinge Bai, Haifeng Dong, Xianghai Meng, Jeffery C.S. Wu, Xiangping Zhang. A new method of Ionic Fragment Contribution-Gradient Boosting Regressor for predicting the infinite dilution activity coefficient of dichloromethane in ionic liquids. Fluid Phase Equilibria 2023, 564 , 113622. https://doi.org/10.1016/j.fluid.2022.113622
    7. Igor A. Sedov, Timur I. Magsumov. Solvation properties of protic ionic liquids 2-methoxyethylammonium nitrate, propylammonium hydrogen sulfate, and butylammonium hydrogen sulfate. The Journal of Chemical Thermodynamics 2022, 170 , 106779. https://doi.org/10.1016/j.jct.2022.106779
    8. Amel Ayad, Fabrice Mutelet, Amina Negadi. Temperature-Dependent Linear Solvation Energy Relationship for the Determination of Gas-Liquid Partition Coefficients of Organic Compounds in Ionic Liquids. 2022https://doi.org/10.5772/intechopen.102733
    9. Zhixing Wu, Sensen Shi, Guoxiong Zhan, Fei Chang, Yinge Bai, Xiangping Zhang, Jeffery C. S. Wu, Shaojuan Zeng. Ionic liquid screening for dichloromethane absorption by multi-scale simulations. Separation and Purification Technology 2021, 275 , 119187. https://doi.org/10.1016/j.seppur.2021.119187
    10. Thomas Brouwer, Sascha R.A. Kersten, Gerrald Bargeman, Boelo Schuur. trends in solvent impact on infinite dilution activity coefficients of solutes reviewed and visualized using an algorithm to support selection of solvents for greener fluid separations. Separation and Purification Technology 2021, 272 , 118727. https://doi.org/10.1016/j.seppur.2021.118727
    11. Sergey P. Verevkin. Imidazolium Based Ionic Liquids: Unbiased Recovering of Vaporization Enthalpies from Infinite-Dilution Activity Coefficients. Molecules 2021, 26 (19) , 5873. https://doi.org/10.3390/molecules26195873
    12. Colin F. Poole, Sanka N. Atapattu. Determination of physicochemical properties of ionic liquids by gas chromatography. Journal of Chromatography A 2021, 1644 , 461964. https://doi.org/10.1016/j.chroma.2021.461964
    13. Pratik Dhakal, Jonathan A. Ouimet, Sydnee N. Roese, Andrew S. Paluch. MOSCED parameters for 1-n-alkyl-3-methylimidazolium-based ionic liquids: Application to limiting activity coefficients and intuitive entrainer selection for extractive distillation processes. Journal of Molecular Liquids 2019, 293 , 111552. https://doi.org/10.1016/j.molliq.2019.111552
    14. Jingli Han, Chengna Dai, Gangqiang Yu, Zhigang Lei. Parameterization of COSMO-RS model for ionic liquids. Green Energy & Environment 2018, 3 (3) , 247-265. https://doi.org/10.1016/j.gee.2018.01.001
    15. Yizhak Marcus. Are solubility parameters relevant for the solubility of liquid organic solutes in room temperature ionic liquids?. Journal of Molecular Liquids 2016, 214 , 32-36. https://doi.org/10.1016/j.molliq.2015.11.019
    16. Timothy W. Stephens, Vicky Chou, Amanda N. Quay, Connie Shen, Nishu Dabadge, Amy Tian, Matthew Loera, Bria Willis, Anastasia Wilson, William E. Acree, Pamela Twu, Jared L. Anderson, Michael H. Abraham. Thermochemical investigations of solute transfer into ionic liquid solvents: updated Abraham model equation coefficients for solute activity coefficient and partition coefficient predictions. Physics and Chemistry of Liquids 2014, 52 (4) , 488-518. https://doi.org/10.1080/00319104.2014.880114
    17. Li-Sheng Wang, Xue-Yuan Wang. Selectivities at infinite dilution of xylene isomers in ionic liquids. Fluid Phase Equilibria 2014, 374 , 37-47. https://doi.org/10.1016/j.fluid.2014.04.016
    18. Lin-Kun Jiang, Li-Sheng Wang, Chao-Jun Du, Xue-Yuan Wang. Activity coefficients at infinite dilution of organic solutes in 1-hexyl-3-methylimidazolium trifluoroacetate and influence of interfacial adsorption using gas–liquid chromatography. The Journal of Chemical Thermodynamics 2014, 70 , 138-146. https://doi.org/10.1016/j.jct.2013.10.038
    19. Maciej Zawadzki, Leszek Niedzicki, Władysław Wieczorek, Urszula Domańska. Estimation of extraction properties of new imidazolide anion based ionic liquids on the basis of activity coefficient at infinite dilution measurements. Separation and Purification Technology 2013, 118 , 242-254. https://doi.org/10.1016/j.seppur.2013.07.006
    20. Jia-Dong Duan, Li-Sheng Wang, Kan Jiang, Xin-Xin Wang. Activity coefficients at infinite dilution of organic solutes in 1-octyl-3-methylimidazolium nitrate using gas–liquid chromatography. Fluid Phase Equilibria 2012, 328 , 1-8. https://doi.org/10.1016/j.fluid.2012.05.006
    21. Zhigang Lei, Li Xiao, Chengna Dai, Biaohua Chen. Group contribution lattice fluid equation of state (GCLF EOS) for ionic liquids. Chemical Engineering Science 2012, 75 , 1-13. https://doi.org/10.1016/j.ces.2012.03.002

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect