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Densities, Viscosities, and Refractive Properties of the Binary Mixtures of the Amino Acid Ionic Liquid [bmim][Ala] with Methanol or Benzylalcohol at T = (298.15 to 313.15) K

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School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China
*Tel./fax: +86 51089880685. E-mail address: [email protected] (H. Wang).
Cite this: J. Chem. Eng. Data 2011, 56, 6, 2877–2883
Publication Date (Web):May 24, 2011
https://doi.org/10.1021/je2000606
Copyright © 2011 American Chemical Society

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    Abstract

    Densities, viscosities, and refractive indices were determined for two ionic liquid (IL) mixtures formed by 1-butyl-3-methylimidazolium alanine acid salt ([bmim][Ala]) with methanol or benzylalcohol, respectively, over the mole fraction range from (0.1 to 0.9) and at temperatures from (298.15 to 313.15) K at intervals of 5 K and atmospheric pressure. Excess molar volumes, viscosity deviations, and refractive index deviations have been calculated from the experimental data and fitted to a Redlich–Kister polynomial function. The results have been interpreted in terms of ion–dipole interactions and structural factors of the IL and alcohol molecular liquids.

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