Isobaric Low-Pressure Vapor–Liquid Equilibrium Data for Ethylbenzene + Styrene + Sulfolane and the Three Constituent Binary SystemsClick to copy article linkArticle link copied!
Abstract
Isobaric vapor–liquid equilibrium (VLE) data have been measured for the ternary system (ethylbenzene + styrene + sulfolane) and the three constituent binary systems under vacuum [(5, 10, and 20) kPa]. The VLE data of the binary system (ethylbenzene + styrene) measured in this work are thermodynamically consistent according to the Herington area test and the point test method contrary to the low pressure VLE data about this system available in the literature. The binary VLE data were described well by the nonrandom two-liquid (NRTL) model. The relative volatility of the system (ethylbenzene + styrene) increases in the presence of sulfolane from 1.4 up to values of 2.2. The ternary system could only be well-correlated when using the ternary VLE data in combination with the binary VLE data as input for the regression of the NRTL binary interaction parameters.
Cited By
Smart citations by scite.ai include citation statements extracted from the full text of the citing article. The number of the statements may be higher than the number of citations provided by ACS Publications if one paper cites another multiple times or lower if scite has not yet processed some of the citing articles.
This article is cited by 17 publications.
- Roshi Dahal, Petri Uusi-Kyyny, Juha-Pekka Pokki, Ville Alopaeus. Isobaric Vapor–Liquid Equilibrium of the Binary Mixtures Toluene + Styrene and Styrene + α-Methylstyrene. Journal of Chemical & Engineering Data 2023, 68
(3)
, 654-663. https://doi.org/10.1021/acs.jced.2c00662
- Mark T. G. Jongmans, Mark Raijmakers, Boelo Schuur, and André B. de Haan . Binary and Ternary Vapor–Liquid Equilibrium Data of the System (Ethylbenzene + Styrene + 4-Methyl-N-butylpyridinium Tetrafluoroborate) at Vacuum Conditions and Liquid–Liquid Equilibrium Data of Their Binary Systems. Journal of Chemical & Engineering Data 2012, 57
(2)
, 626-633. https://doi.org/10.1021/je201205t
- Mark T.G. Jongmans, Boelo Schuur, and André B. de Haan . Ionic Liquid Screening for Ethylbenzene/Styrene Separation by Extractive Distillation. Industrial & Engineering Chemistry Research 2011, 50
(18)
, 10800-10810. https://doi.org/10.1021/ie2011627
- Sahil Sethi, Xiang Zhang, Kai Sundmacher. Process-driven solvent screening for efficient extractive distillation using interpolative rational functions. Chemical Engineering Science 2025, 301 , 120675. https://doi.org/10.1016/j.ces.2024.120675
- Dmitrii N. Bolmatenkov, Mikhail I. Yagofarov, Airat A. Notfullin, Boris N. Solomonov. Calculation of the vaporization enthalpies of alkylaromatic hydrocarbons as a function of temperature from their molecular structure. Fluid Phase Equilibria 2022, 554 , 113303. https://doi.org/10.1016/j.fluid.2021.113303
- Sarwono Mulyono, Hanee F. Hizaddin, Irfan Wazeer, Omar Alqusair, Emad Ali, Mohd. Ali Hashim, Mohamed K. Hadj-Kali. Liquid-liquid equilibria data for the separation of ethylbenzene/styrene mixtures using ammonium-based deep eutectic solvents. The Journal of Chemical Thermodynamics 2019, 135 , 296-304. https://doi.org/10.1016/j.jct.2019.04.003
- . Simple Concept Design of a New Process. 2018, 173-201. https://doi.org/10.1002/9781119311478.ch8
- Marek Blahušiak, Anton A. Kiss, Katarina Babic, Sascha R.A. Kersten, Gerrald Bargeman, Boelo Schuur. Insights into the selection and design of fluid separation processes. Separation and Purification Technology 2018, 194 , 301-318. https://doi.org/10.1016/j.seppur.2017.10.026
- Zhongpeng Xing, Yujie Gao, Hui Ding, Xianqin Wang, Lujun Li, Hang Zhou. Isobaric vapor–liquid equilibrium for ternary system of ethanol, ethyl propionate and para-xylene at 101.3 kPa. Chinese Journal of Chemical Engineering 2018, 26
(3)
, 560-565. https://doi.org/10.1016/j.cjche.2017.10.020
- Chengtian Cui, Xingang Li, Dongrong Guo, Jinsheng Sun. Towards energy efficient styrene distillation scheme: From grassroots design to retrofit. Energy 2017, 134 , 193-205. https://doi.org/10.1016/j.energy.2017.06.031
- William Acree, James S. Chickos. Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From 1880 to 2015. Part 1. C
1
− C
10. Journal of Physical and Chemical Reference Data 2016, 45
(3)
, 033101. https://doi.org/10.1063/1.4948363
- Yukwon Jeon, Sung Wook Row, Gichun Lee, Sang Sun Park, Young-Jong Seo, Young Hwan Chu, Yong-Gun Shul. Solvent screening for the separation of ethylbenzene and p-xylene by extractive distillation. Korean Journal of Chemical Engineering 2014, 31
(10)
, 1824-1830. https://doi.org/10.1007/s11814-014-0115-2
- Mark T.G. Jongmans, Jorg Trampé, Boelo Schuur, André B. de Haan. Solute recovery from ionic liquids: A conceptual design study for recovery of styrene monomer from [4-mebupy][BF4]. Chemical Engineering and Processing: Process Intensification 2013, 70 , 148-161. https://doi.org/10.1016/j.cep.2013.04.007
- Mark T.G. Jongmans, Eline Hermens, Mark Raijmakers, Jenny I.W. Maassen, Boelo Schuur, André B. de Haan. Conceptual process design of extractive distillation processes for ethylbenzene/styrene separation. Chemical Engineering Research and Design 2012, 90
(12)
, 2086-2100. https://doi.org/10.1016/j.cherd.2012.05.019
- Mark T.G. Jongmans, Alex Londoño, Boelo Schuur, André B. de Haan. Isobaric low-pressure vapor–liquid equilibrium data of the system monochloroacetic acid+dichloroacetic acid+diethylene glycol dipentyl ether and the constituent binary systems. Fluid Phase Equilibria 2012, 334 , 15-21. https://doi.org/10.1016/j.fluid.2012.07.027
- Mark T.G. Jongmans, Boelo Schuur, André B. de Haan. Binary and ternary LLE data of the system (ethylbenzene+styrene+1-ethyl-3-methylimidazolium thiocyanate) and binary VLE data of the system (styrene+1-ethyl-3-methylimidazolium thiocyanate). The Journal of Chemical Thermodynamics 2012, 47 , 234-240. https://doi.org/10.1016/j.jct.2011.10.021
- Mark T.G. Jongmans, Eline Hermens, Boelo Schuur, André B. de Haan. Binary and ternary vapor–liquid equilibrium data of the system ethylbenzene+styrene+3-methyl-N-butylpyridinium tetracyanoborate at vacuum conditions and liquid–liquid equilibrium data of their binary systems. Fluid Phase Equilibria 2012, 315 , 99-106. https://doi.org/10.1016/j.fluid.2011.11.027
Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.
Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.
The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.