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Solubilities of Tris(o-phenylenedioxy)cyclotriphosphazene in Selected Solvents

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School of Chemical Engineering and the Environment, Beijing Institute of Technology, Beijing 100081, People's Republic of China
Fax: +86-10-68911040. E-mail: [email protected]
Cite this: J. Chem. Eng. Data 2011, 56, 7, 3208–3213
Publication Date (Web):June 21, 2011
https://doi.org/10.1021/je200252c
Copyright © 2011 American Chemical Society

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    Abstract

    Tris-(o-phenylenedioxy)-cyclotriphosphazene (TPP) was synthesized and characterized by elemental analysis (EA) and nuclear magnetic resonance (NMR). The melting point and the enthalpy of fusion of TPP were measured by da ifferential scanning calorimeter (DSC), and the thermal stability of TPP was measured by thermogravimetric analysis (TGA). Using a static analytical method, the solubility data of TPP in nine solvents were measured and correlated with an empirical equation. Moreover, using the Scatchard–Hildebrand model, activity coefficients have also been calculated and compared with the experimental values. The partial molar excess enthalpies at infinite dilution were also predicted.

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    1H NMR, 31P NMR spectra of TPP, and uncertainty analysis for the melting point and enthalpy of fusion of TPP. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cited By

    This article is cited by 7 publications.

    1. Gangfeng Chen, Guangpu Zhang, Bixin Jin, Mingyan Luo, Yunjun Luo, Satoshi Aya, Xiaoyu Li. Supramolecular Hexagonal Platelet Assemblies with Uniform and Precisely-Controlled Dimensions. Journal of the American Chemical Society 2019, 141 (39) , 15498-15503. https://doi.org/10.1021/jacs.9b08316
    2. Jozef Drabowicz, Rafal Karpowicz, Dorota Krasowska, Luca Sancineto, Christian V. Stevens. Compounds Containing a Spiro Phosphorus Atom. 2022, 633-740. https://doi.org/10.1016/B978-0-12-818655-8.00016-0
    3. William Acree, James S. Chickos. Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds and Ionic Liquids. Sublimation, Vaporization, and Fusion Enthalpies from 1880 to 2015. Part 2. C11–C192. Journal of Physical and Chemical Reference Data 2017, 46 (1) https://doi.org/10.1063/1.4970519
    4. Lin-Kun Jiang, Li-Sheng Wang, Guo-Min Yu. Thermostabilities and solubilities of flame retardant bisphenol S-bis (5,5-dimethyl-1,3-dioxaphosphorinanyl-2-oxy phosphate ester) as a function of temperature. Fluid Phase Equilibria 2014, 373 , 55-62. https://doi.org/10.1016/j.fluid.2014.04.006
    5. Lin-Kun Jiang, Li-Sheng Wang, Chao-Jun Du, Gui-Qin Sun, Chun-Mei Qi. Measurement and correlation of the solubilities of tetra(5,5-dimethyl-1,3-dioxaphosphorinanyl-2-oxy) neopentane in different pure solvents. Fluid Phase Equilibria 2014, 367 , 117-124. https://doi.org/10.1016/j.fluid.2014.01.043
    6. Frederick F. Stewart. Phosphazenes. 2013, 216-262. https://doi.org/10.1039/9781849737708-00216
    7. Ru-Yi Jiang, Li-Sheng Wang. Solubilities of Hexaphenoxycyclotriphosphazene and Tri(2-cyanoethyl)phosphine in Selected Solvents: Measurement and Correlation. Journal of Solution Chemistry 2012, 41 (12) , 2107-2122. https://doi.org/10.1007/s10953-012-9930-4

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