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Phase Equilibria of H2S-Hydrocarbons (Propane, n-Butane, and n-Pentane) Binary Systems at Low Temperatures

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Laboratoire des Sciences des Procédés et des Matériaux, Université Paris 13, CNRS Institut Galilée 99 avenue Jean-Baptiste Clément, 93430 Villetaneuse, France
MINES ParisTech, CEP/TEP-Centre Energétique et Procédés, 35 Rue Saint Honoré, 77305 Fontainebleau, France
§ Thermodynamics Research Unit, School of Chemical Engineering, University of KwaZulu-Natal, Howard College Campus, Durban, South Africa
IFP Energies Nouvelles, 1 & 4 avenue de Bois-Préau, 92852 Rueil-Malmaison Cedex, France
*E-mail: [email protected]. Telephone: +33 1 64694962. Fax: +33 1 64694968.
Cite this: J. Chem. Eng. Data 2012, 57, 5, 1534–1543
Publication Date (Web):April 19, 2012
https://doi.org/10.1021/je300111m
Copyright © 2012 American Chemical Society

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    Abstract

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    Isothermal vapor–liquid equilibrium measurements of three binary systems, H2S + propane, H2S + n-butane, and H2S + n-pentane, have been performed with a static synthetic apparatus at low temperatures. The method of Barker has been implemented to determine the corresponding nonrandom two-liquid (NRTL) parameters and to calculate the liquid mole fractions. The results have been further used along with literature data to adjust binary interaction parameters of the Peng–Robinson equation of state. Good agreement with Dechema values has been found.

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