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Experiments and Correlations of the Vapor–Liquid Equilibria for Carbon Monoxide + Propionic Acid and Carbon Monoxide + Methyl Formate Systems

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Department of Chemistry, School of Science, Tianjin University, Tianjin, 300072, China
The Library of Civil Aviation University of China, Tianjin, 300300, China
§ Department of Materials Science and Engineering, Tianjin Institute of Urban Construction, Tianjin, 300384, China
*Tel.: +86 22 27406140; fax: +86 22 27403475; e-mail: [email protected]
Cite this: J. Chem. Eng. Data 2012, 57, 7, 1887–1893
Publication Date (Web):June 8, 2012
https://doi.org/10.1021/je3001969
Copyright © 2012 American Chemical Society

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    Abstract

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    Vapor–liquid equilibrium data p, T, x, ρ, and Vm at (293.2, 313.2, 333.2, and 353.2) K and pressures between (1.39 and 9.96) MPa for the binary systems of carbon monoxide (CO) + propionic acid (PA) and carbon monoxide + methyl formate (MF) were reported. The equilibria were measured using a variable-volume cylindrical autoclave. The experimental data were modeled using the Peng–Robinson (PR) equation of state (EOS) and Peng–Robinson–Stryjek–Vera (PRSV) equation of state with van der Waals I or Panagiotopoulos–Reid mixing rules. The compared results showed a satisfactory agreement between the correlated and the experimental data. The binary interaction parameters were also obtained. At the same time, the Henry's coefficient, molar solution enthalpy, and molar solution entropy of CO in propionic acid and methyl formate were calculated.

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    Cited By

    This article is cited by 2 publications.

    1. Fan Wu, Qinghu Zhao, Lefu Tao, David Danaci, Penny Xiao, Fatin Abbas Hasan, Paul A. Webley. Solubility of Carbon Monoxide and Hydrogen in Methanol and Methyl Formate: 298–373 K and 0.3–3.3 MPa. Journal of Chemical & Engineering Data 2019, 64 (12) , 5609-5621. https://doi.org/10.1021/acs.jced.9b00676
    2. Stephanie Peper, José M.S. Fonseca, Ralf Dohrn. High-pressure fluid-phase equilibria: Trends, recent developments, and systems investigated (2009–2012). Fluid Phase Equilibria 2019, 484 , 126-224. https://doi.org/10.1016/j.fluid.2018.10.007

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