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Determination of CO2 Solubility in Saturated Liquid CH4 + N2 and CH4 + C2H6 Mixtures above Atmospheric Pressure

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Institute of Refrigeration and Cryogenics, Shanghai Jiao Tong University, Shanghai 200240, China
*Tel.: +86-21-34206533; fax: +86-21-34206814; e-mail address: [email protected]
Cite this: J. Chem. Eng. Data 2012, 57, 8, 2296–2303
Publication Date (Web):July 18, 2012
https://doi.org/10.1021/je3002859
Copyright © 2012 American Chemical Society
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    Abstract

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    Accurate CO2 solubility data are crucial for putting a proposal of pressurized liquefied natural gas (PLNG) project into practice. A solid–liquid equilibrium (SLE) apparatus, which is based on the static–analytic method, has been set up to measure the solubility of carbon dioxide in saturated liquid CH4/CH4 + N2/CH4 + C2H6 in the pressure region from atmospheric up to 3 MPa, corresponding to the temperature region from (112 to 170) K. In addition, Peng–Robinson (PR) and Suave–Redlich–Kwong (SRK) equations-of-state (EOS) are selected to calculate the solubility of carbon dioxide in CH4 + N2 and CH4 + C2H6 mixtures, and the results are consistent with the experimental data in the whole region. Two temperature-dependent correlations for the interaction coefficients kij on CH4 + CO2 system are derived by the experimental data for PR and SRK EOS, which can improve the calculation accuracy of the binary and ternary solid–liquid phase equilibrium.

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