ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Figure 1Loading Img

Vapor–Liquid Equilibrium Data for Binary Systems of 1-Methyl-4-(1-methylethenyl)-cyclohexene + {Ethanol, Propan-1-ol, Propan-2-ol, Butan-1-ol, Pentan-1-ol, or Hexan-1-ol} at 40 kPa

View Author Information
Thermodynamics Research Unit, School of Engineering, University of KwaZulu-Natal, Howard College Campus, Durban, 4041, South Africa
Physical Chemistry Division, Faculty of Chemistry, Warsaw University of Technology, 00-664 Warsaw, Poland
*E-mail: [email protected]. Tel.: +27 31 260 3128. Fax: +27 31 260 1118.
Cite this: J. Chem. Eng. Data 2012, 57, 7, 2053–2058
Publication Date (Web):June 19, 2012
https://doi.org/10.1021/je300347z
Copyright © 2012 American Chemical Society

    Article Views

    371

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options

    Abstract

    Abstract Image

    Isobaric binary vapor–liquid equilibrium (VLE) data were measured for the 1-methyl-4-(1-methylethenyl)-cyclohexene (d-limonene) + {ethanol, propan-1-ol, propan-2-ol, butan-1-ol, pentan-1-ol, or hexan-1-ol} systems at 40 kPa. A low pressure dynamic still was used for the measurements. The experimental data were regressed using the nonrandom two-liquid (NRTL) and Wilson activity coefficient models. Both models correlated the data well. The 1-methyl-4-(1-methylethenyl)-cyclohexene + {butan-1-ol or pentan-1-ol or hexan-1-ol} systems exhibit a minimum temperature azeotrope. The 1-methyl-4-(1-methylethenyl)-cyclohexene + {ethanol or propan-1-ol or propan-2-ol} systems show the largest positive deviation from Raoult's law, and these systems exhibit no azeotropic behavior.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Cited By

    This article is cited by 13 publications.

    1. Banzi Patrick Mbatha, Peterson Thokozani Ngema, Nkululeko Nkosi, Suresh Ramsuroop. Infinite Dilution Activity Coefficient Measurements for 1-Methyl-4-(1-methylethenyl)-cyclohexene as a Green Solvent for Separation. Journal of Chemical & Engineering Data 2022, 67 (4) , 966-974. https://doi.org/10.1021/acs.jced.1c00801
    2. Jay H. Tailor, Nitin V. Bhate. Isobaric Vapor Liquid Equilibrium Data for the 1,2-Dichloroethane–1-Butanol System. Journal of Chemical & Engineering Data 2019, 64 (12) , 5256-5262. https://doi.org/10.1021/acs.jced.9b00484
    3. Ruslan N. Nagrimanov, Aizat A. Samatov, Marat A. Ziganshin, Boris N. Solomonov, Sergey P. Verevkin. Re-evaluation of solution enthalpies of aliphatic hydrocarbons functional derivatives and terpenes in n-heptane and their validation by thermochemical consistency. Journal of Molecular Liquids 2024, 394 , 123697. https://doi.org/10.1016/j.molliq.2023.123697
    4. Singh Upasana, Vasava Krupali, Tailor Jay, Nitin V. Bhate. Ebulliometric determination of vapour liquid equilibria for 1-propanol – n-propyl acetate system. Chemical Data Collections 2023, 44 , 101011. https://doi.org/10.1016/j.cdc.2023.101011
    5. V. Zhelezny, I. Motovoy, K. Khanchych, V. Sechenyh, Ya. Hlek. Temperature and concentration dependencies of the saturated vapor pressure for the solutions of nanoparticles AL2O3 in isopropanol and fullerenes C60 in o-xylene. Journal of Molecular Liquids 2020, 319 , 114362. https://doi.org/10.1016/j.molliq.2020.114362
    6. Julcelly Dayara de Oliveira Henriques, Filipe Hobi Bordón Sosa, Rafael Macedo Dias, Patricia Fazzio Martins Martinez, Mariana Conceição da Costa. Flash point and excess molar volumes of binary mixtures containing d-limonene and alcohol compounds from propanol to dodecanol. The Journal of Chemical Thermodynamics 2020, 150 , 106224. https://doi.org/10.1016/j.jct.2020.106224
    7. Nikolai G. Polikhronidi, Rabiyat G. Batyrova, Jiangtao Wu, Ilmutdin M. Abdulagatov. PVT and Thermal-Pressure Coefficient Measurements and Derived Thermodynamic Properties of 2-Propanol in the Critical and Supercritical Regions. International Journal of Thermophysics 2020, 41 (7) https://doi.org/10.1007/s10765-020-02672-1
    8. Nikolai G. Polikhronidi, Rabiyat G. Batyrova, Joseph W. Magee, Ilmutdin M. Abdulagatov. Influence of nanofluid instability on thermodynamic properties near the critical point. The Journal of Chemical Thermodynamics 2019, 133 , 46-59. https://doi.org/10.1016/j.jct.2018.12.009
    9. Ilmutdin M. Abdulagatov, Akhmed R. Bazaev, Emil A. Bazaev, Tamerlan A. Dzhapparov. PVT properties of 1-propanol in the critical and supercritical regions. The Journal of Supercritical Fluids 2016, 117 , 172-193. https://doi.org/10.1016/j.supflu.2016.06.017
    10. Vojtěch Štejfa, Michal Fulem, Květoslav Růžička, Pavel Matějka. Vapor pressures and thermophysical properties of selected hexenols and recommended vapor pressure for hexan-1-ol. Fluid Phase Equilibria 2015, 402 , 18-29. https://doi.org/10.1016/j.fluid.2015.05.026
    11. Manel Zaoui-Djelloul-Daouadji, Amina Negadi, Ilham Mokbel, Latifa Negadi. (Vapor-liquid) equilibria and excess Gibbs free energy functions of (ethanol+glycerol), or (water+glycerol) binary mixtures at several temperatures. The Journal of Chemical Thermodynamics 2014, 69 , 165-171. https://doi.org/10.1016/j.jct.2013.09.046
    12. Prashant Reddy, J. David Raal, Deresh Ramjugernath. A novel dynamic recirculating apparatus for vapour–liquid equilibrium measurements at moderate pressures and temperatures. Fluid Phase Equilibria 2013, 358 , 121-130. https://doi.org/10.1016/j.fluid.2013.07.044
    13. Sandra M. García-Abarrio, Luisa Haya, Juan I. Pardo, José S. Urieta, Ana M. Mainar. Isobaric VLE of the mixture {(±)-linalool+ethanol}: A case study for the distillation of absolute and volatile oils. The Journal of Chemical Thermodynamics 2013, 64 , 182-186. https://doi.org/10.1016/j.jct.2013.05.022

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect