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Vapor–Liquid Equilibrium Data for Binary Systems of 1-Methyl-4-(1-methylethenyl)-cyclohexene + {Ethanol, Propan-1-ol, Propan-2-ol, Butan-1-ol, Pentan-1-ol, or Hexan-1-ol} at 40 kPa

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Thermodynamics Research Unit, School of Engineering, University of KwaZulu-Natal, Howard College Campus, Durban, 4041, South Africa
Physical Chemistry Division, Faculty of Chemistry, Warsaw University of Technology, 00-664 Warsaw, Poland
*E-mail: [email protected]. Tel.: +27 31 260 3128. Fax: +27 31 260 1118.
Cite this: J. Chem. Eng. Data 2012, 57, 7, 2053–2058
Publication Date (Web):June 19, 2012
Copyright © 2012 American Chemical Society

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    Abstract Image

    Isobaric binary vapor–liquid equilibrium (VLE) data were measured for the 1-methyl-4-(1-methylethenyl)-cyclohexene (d-limonene) + {ethanol, propan-1-ol, propan-2-ol, butan-1-ol, pentan-1-ol, or hexan-1-ol} systems at 40 kPa. A low pressure dynamic still was used for the measurements. The experimental data were regressed using the nonrandom two-liquid (NRTL) and Wilson activity coefficient models. Both models correlated the data well. The 1-methyl-4-(1-methylethenyl)-cyclohexene + {butan-1-ol or pentan-1-ol or hexan-1-ol} systems exhibit a minimum temperature azeotrope. The 1-methyl-4-(1-methylethenyl)-cyclohexene + {ethanol or propan-1-ol or propan-2-ol} systems show the largest positive deviation from Raoult's law, and these systems exhibit no azeotropic behavior.

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    Cited By

    This article is cited by 13 publications.

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    9. Ilmutdin M. Abdulagatov, Akhmed R. Bazaev, Emil A. Bazaev, Tamerlan A. Dzhapparov. PVT properties of 1-propanol in the critical and supercritical regions. The Journal of Supercritical Fluids 2016, 117 , 172-193.
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    11. Manel Zaoui-Djelloul-Daouadji, Amina Negadi, Ilham Mokbel, Latifa Negadi. (Vapor-liquid) equilibria and excess Gibbs free energy functions of (ethanol+glycerol), or (water+glycerol) binary mixtures at several temperatures. The Journal of Chemical Thermodynamics 2014, 69 , 165-171.
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    13. Sandra M. García-Abarrio, Luisa Haya, Juan I. Pardo, José S. Urieta, Ana M. Mainar. Isobaric VLE of the mixture {(±)-linalool+ethanol}: A case study for the distillation of absolute and volatile oils. The Journal of Chemical Thermodynamics 2013, 64 , 182-186.

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