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Liquid–Liquid Equilibria for the Ternary Systems of Perfluorohexane + Methyl Nonafluorobutyl Ether + Toluene, + 1,4-Dioxane, or + Dimethylformamide at 298.15 K

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Department of Chemical & Biological Engineering, Korea University, Seoul 136-713, Korea
Green School, Korea University, Seoul 136-713, Korea
§ LG Chem Research Park, Daejeon 305-380, Korea
Department of Health & Environment, Kimpo College, Gyenggi-do 415-761, Korea
Cite this: J. Chem. Eng. Data 2013, 58, 4, 915–919
Publication Date (Web):February 21, 2013
https://doi.org/10.1021/je301149f
Copyright © 2013 American Chemical Society

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    Abstract

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    Equilibrium tie-line data were determined for a fluorous biphasic systems at 298.15 K. Two phase mixtures were used, consisting of a perfluorinated solvent phase using a mixture of two fluorinated solvents (methyl nonafluorobutyl ether and perfluorohexane) as well as an organic solvent phase in which the organic solvents studied were toluene, 1,4-dioxane, and dimethylformamide, respectively. Nonrandom two liquid models applied to the four ternary systems produced interaction parameters that were well-correlated with the equilibrium composition. These parameters enabled the prediction of liquid–liquid equilibrium systems containing methyl nonafluorobutyl ether and perfluorohexane. The ability to manipulate fluorous biphasic systems composed of perfluorohexane and an organic solvent with the addition of methyl nonafluorobutyl ether was examined.

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    Cited By

    This article is cited by 8 publications.

    1. Karel Řehák, Martin Klajmon, Martin Strejc, and Pavel Morávek . Isothermal Vapor–Liquid Equilibria for Binary Mixtures of Methyl Nonafluorobutyl Ether + Acetone, Cyclopentyl Methyl Ether, Ethyl Acetate, n-Heptane, Methanol, and Toluene. Journal of Chemical & Engineering Data 2017, 62 (11) , 3878-3888. https://doi.org/10.1021/acs.jced.7b00599
    2. Michael D. Wales, Chaoran Huang, Logan B. Joos, Kyle V. Probst, Praveen V. Vadlani, Jennifer L. Anthony, and Mary E. Rezac . Liquid–Liquid Equilibria for Ternary Systems of Water + Methoxycyclopentane + Alcohol (Methanol, Ethanol, 1-Propanol, or 2-Propanol). Journal of Chemical & Engineering Data 2016, 61 (4) , 1479-1484. https://doi.org/10.1021/acs.jced.5b00803
    3. Gregorius Rionugroho Harvianto, Seo Eun Kim, Il Bong Jin, Ki Joon Kang, and Moonyong Lee . Liquid–Liquid Equilibria Data for the Quaternary System of Acetic Acid, Water, p-Xylene, and Ethyl Acetate at 313.15 K and 101.325 kPa. Journal of Chemical & Engineering Data 2016, 61 (2) , 780-787. https://doi.org/10.1021/acs.jced.5b00550
    4. Sang Young Lim, Tae Gyu Lee, Kwang Ho Song, and Jaehoon Choe . Liquid–Liquid Equilibria for the Ternary Systems of FC3283 + HFE7300 + Hexane, FC3283 + HFE7500 + Octane, and FC72 + HFE7100 + (Acetonitrile or Ethyl Acetate) at 273.15 K, 298.15 K, and 313.15 K. Journal of Chemical & Engineering Data 2014, 59 (5) , 1656-1660. https://doi.org/10.1021/je500107y
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    6. Tae Gyu Lee, Kwang Ho Song, and Jaehoon Choe . Liquid–Liquid Equilibria for the Ternary Systems of Perfluamine + Hydrofluoroether + Benzene, Toluene, or Xylene at 298.15 K or 313.15 K. Journal of Chemical & Engineering Data 2013, 58 (11) , 3130-3136. https://doi.org/10.1021/je400592a
    7. Tae Gyu Lee, Seo Young Kim, Kwang Ho Song, Jaehoon Choe, and Ji Hyeon Kim . Liquid–Liquid Equilibria for the Ternary Systems of Perfluorohexane or Perfluamine + Hydrofluoroether + Tetrahydrofuran at 298.15 K or 273.15 K. Journal of Chemical & Engineering Data 2013, 58 (7) , 2035-2043. https://doi.org/10.1021/je400227m
    8. Brandon J. Reizman, Klavs F. Jensen. Simultaneous solvent screening and reaction optimization in microliter slugs. Chemical Communications 2015, 51 (68) , 13290-13293. https://doi.org/10.1039/C5CC03651H

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