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Isothermal Vapor–Liquid Equilibria of n-Tetradecane + Ethyl Hexanoate, Ethyl Decanoate, and Ethyl Tetradecanoate

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Ecole Militaire Polytechnique EMP, BP 17 Bordj-El-Bahri, Alger, Algérie
Laboratoire des Sciences Analytiques UMR 5280, Université de Lyon-UCB Lyon 1, 43 Bd du 11 Novembre 1918, 69622 Villeurbanne, France
§ Laboratoire de Thermodynamique et Modélisation Moléculaire, Faculté de Chimie, USTHB, BP. 32 El-Alia, 16111 Bab-Ezzouar, Alger, Algérie
Cite this: J. Chem. Eng. Data 2013, 58, 2, 492–498
Publication Date (Web):February 4, 2013
https://doi.org/10.1021/je301294a
Copyright © 2013 American Chemical Society

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    Abstract

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    The vapor pressures of three binary systems, (ethyl hexanoate (1) + n-tetradecane (2)), (ethyl decanoate (1) + n-tetradecane (2)), and (ethyl tetradecanoate (1) + n-tetradecane (2)), were measured by means of a static apparatus at temperatures between (373.15 and 453.15) K. We correlated the data with the Antoine equation. The molar excess Gibbs energies GE obtained from these data by using Barker’s method were fitted to the Redlich–Kister equation. A maximum azeotropic behavior is observed for the binary mixture {ethyl decanoate (1) + n-tetradecane (2)}. Positive values of the excess Gibbs energy are obtained for all of the investigated temperatures and compositions. The data were also correlated by using Wilson equation. The predicted GE obtained by using group contribution model, UNIFAC (Gmehling version), are different to the experimental values. These deviations are more important for systems {ethyl decanoate (1) + n-tetradecane (2)} and {ethyl tetradecanoate (1) + n-tetradecane (2)}.

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