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Volumetric Study for the Binary Nitromethane with Chloroalkane Mixtures at Temperatures in the Range (298.15 to 318.15) K

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“Ilie Murgulescu” Institute of Physical Chemistry, Romanian Academy, Splaiul Independentei 202, 060021 Bucharest, Romania
*E-mail: [email protected]. Tel.: +40 213167912. Fax: +40 213121147.
Cite this: J. Chem. Eng. Data 2013, 58, 5, 1161–1167
Publication Date (Web):April 25, 2013
https://doi.org/10.1021/je3013342
Copyright © 2013 American Chemical Society
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Abstract

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The results of the density measurements for the pair systems containing nitromethane with 1,1,2,2-tetrachloroethane, 1,1,1-trichloroethane, chloroform, 1,2-dichloroethane, 1,3-dichloropropane, 1,4-dichlorobutane, 1-chlorobutane, and 1-chloropentane at T = (298.15, 308.15, and 318.15) K and atmospheric pressure on entire compositional range are reported. The derived excess molar volumes, VE, are positive for the nitromethane + 1,1,1-trichloroethane, + 1,2-dichloroethane, + 1,3-dichloropropane, + 1,4-dichlorobutane, + 1-chlorobutane, and + 1-chloropentane binary mixtures, and they are negative for the other two systems: nitromethane + 1,1,2,2-tetrachloroethane, and + chloroform, on the entire compositional range and at all three studied temperatures. The excess molar volumes have been correlated with the three-parameter Redlich–Kister equation.

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This article is cited by 9 publications.

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  3. S. Mallick, M. Malathi. Study of the H-bond interaction on binary mixtures of nitromethane with primary alcohols at different temperatures using dielectric parameters. Indian Journal of Physics 2018, 92 (10) , 1245-1258. https://doi.org/10.1007/s12648-018-1225-1
  4. Dana Dragoescu, Magdalena Bendová, Zdeněk Wagner, Daniela Gheorghe. Volumetric, acoustic and optical properties for binary mixtures of nitroethane with chloroalkane at temperatures between 298.15 K and 318.15 K. Comparison with theories. Journal of Molecular Liquids 2016, 223 , 790-804. https://doi.org/10.1016/j.molliq.2016.08.076
  5. Dana Dragoescu, Daniela Gheorghe, Magdalena Bendová, Zdeněk Wagner. Speeds of sound, isentropic compressibilities and refractive indices for some binary mixtures of nitromethane with chloroalkane at temperatures from 298.15 to 318.15K. Comparison with theories. Fluid Phase Equilibria 2015, 385 , 105-119. https://doi.org/10.1016/j.fluid.2014.10.004
  6. Dana Dragoescu. Volumetric and optical properties for some (2-butanone+chloroalkane) binary mixtures at T=298.15K. The Journal of Chemical Thermodynamics 2014, 75 , 13-19. https://doi.org/10.1016/j.jct.2014.04.004
  7. Mariana Teodorescu, B. Marongiu, Sara Maxia, Alessandra Piras, Marianna Usula, Silvia Porcedda. Calorimetric study of the selected nitroalkane+chloroalkane binary systems. Journal of Thermal Analysis and Calorimetry 2014, 116 (1) , 119-127. https://doi.org/10.1007/s10973-013-3408-5
  8. M. Chorążewski, A. Grzybowski, M. Paluch. The complex, non-monotonic thermal response of the volumetric space of simple liquids. Phys. Chem. Chem. Phys. 2014, 16 (37) , 19900-19908. https://doi.org/10.1039/C4CP02350A
  9. Laura Lomba, Beatriz Giner, Estefanía Zuriaga, Ignacio Gascón, Carlos Lafuente. Thermophysical properties of lactates. Thermochimica Acta 2014, 575 , 305-312. https://doi.org/10.1016/j.tca.2013.11.010

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