ACS Publications. Most Trusted. Most Cited. Most Read
Solubility of Veratric Acid in Eight Monosolvents and Ethanol + 1-Butanol at Various Temperatures
My Activity

Figure 1Loading Img
    Article

    Solubility of Veratric Acid in Eight Monosolvents and Ethanol + 1-Butanol at Various Temperatures
    Click to copy article linkArticle link copied!

    View Author Information
    State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Box 35, Beijing, 100029, China
    College of Chinese Pharmacology, Beijing University of Chinese Medicine and Pharmacology, Beijing, 100029, China
    *Tel.: +86-10-64446523. E-mail address: [email protected]
    Other Access Options

    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2013, 58, 4, 1020–1028
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je400029t
    Published March 7, 2013
    Copyright © 2013 American Chemical Society

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    The solubility of veratric acid (3,4-dimethoxybenzoic acid, with measured melting point of 453.12 K by differential scanning calorimetry, DSC) in eight monosolvents, including ethanol, 1-propanol, 2-propanol, 1-butanol, 2-methyl-1-propanol, methyl acetate, ethyl acetate, and 2-butanone, and binary mixtures of ethanol + 1-butanol was determined at (278 to 323) K and atmospheric pressure using a dynamic method. The modified Apelblat equation and two local composition models (NRTL and UNIQUAC) were used to correlate the solubility of veratric acid in pure solvents. The modified Apelblat and the Jouyban–Acree model were used to correlate the solute solubility in binary mixtures. A combination of the Jouyban–Acree model and van’t Hoff equation was used to predict solubility data in the mixed solvents at different temperatures and gives a reasonable prediction. Each of the correlation equations selected gives a good description of the relationship of solubility and the temperature, and correlated data of the modified Apelblat equation show the best agreement with the experimental data, with the overall relative average deviations values of 0.61 % and 0.62 % in pure solvents and binary mixtures, respectively.

    Copyright © 2013 American Chemical Society

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Cited By

    Click to copy section linkSection link copied!
    Citation Statements
    Explore this article's citation statements on scite.ai

    This article is cited by 43 publications.

    1. Han Yue, Yuxiang Liu, Yidong Gu, Xiwei Hu, Jiaming Zhu, Qunsheng Li. Solubility Measurement, Correlation, and Thermodynamic Study of trans-3-Hydroxycinnamic Acid in Nine Pure Solvents and (Ethanol + Ethyl Acetate) Cosolvent Mixtures at Temperatures from 293.15 to 333.15 K. Journal of Chemical & Engineering Data 2023, 68 (8) , 2107-2118. https://doi.org/10.1021/acs.jced.3c00198
    2. Dandan Liu, Weikun Tang, Yongjie Wang, Shujing Zhang, Jiaxin Wang, Junjie Li, Jun Wang, Minjie Zhi, Peng Wang, Zhenyu Li. Solubility and Hansen Solubility Parameters of N-Benzyloxycarbonyl-l-serine in 12 Monosolvents from 283.15 to 323.15 K. Journal of Chemical & Engineering Data 2023, 68 (7) , 1813-1825. https://doi.org/10.1021/acs.jced.3c00201
    3. Shaonan Zhang, Ningning Tian, Shengzhe Jia, Jing Yang, Yu Zhou, Shichao Du, Zhenguo Gao. Solubility Measurement and Data Correlation of Pentaerythritol in Four Binary Solvent Systems at Temperatures from 283.15 to 323.15 K. Journal of Chemical & Engineering Data 2021, 66 (5) , 2209-2217. https://doi.org/10.1021/acs.jced.1c00080
    4. Bruno Sepúlveda-Orellana, Nicolás F. Gajardo-Parra, Hoang T. Do, José R. Pérez-Correa, Christoph Held, Gabriele Sadowski, Roberto I. Canales. Measurement and PC-SAFT Modeling of the Solubility of Gallic Acid in Aqueous Mixtures of Deep Eutectic Solvents. Journal of Chemical & Engineering Data 2021, 66 (2) , 958-967. https://doi.org/10.1021/acs.jced.0c00784
    5. Xiao Juan Liu, Yang Zhang, Xue Zhong Wang. Solubility of Benzanilide Crystals in Organic Solvents. Journal of Chemical & Engineering Data 2020, 65 (8) , 3808-3819. https://doi.org/10.1021/acs.jced.0c00167
    6. Xiaofeng Chen, Xiaofang Gong, Juan Xu, Peng Li, Huiping Wang, Lifeng Ning. Measurement and Correlation of the Solubility of Etonogestrel in Ten Pure and Binary Mixed Solvent Systems at Temperatures from 273.15 to 323.15 K. Journal of Chemical & Engineering Data 2020, 65 (6) , 3190-3202. https://doi.org/10.1021/acs.jced.0c00201
    7. Jingping Sun, Long Wang, Shuaiwei Ding, Xiaobo Sun, Li Xu. Solubility Behavior and Thermodynamic Analysis of Bisphenol A in 14 Different Pure Solvents. Journal of Chemical & Engineering Data 2020, 65 (5) , 2846-2858. https://doi.org/10.1021/acs.jced.0c00166
    8. Liangcheng Song, Danyang Zhao, Shuguang Zhang, Xiao Zhang, Guan Wang, Chongqiang Zhu, Yu Tian, Chunhui Yang. Solubility of Diflufenican in Pure and Binary Solvent Systems. Journal of Chemical & Engineering Data 2018, 63 (11) , 4176-4184. https://doi.org/10.1021/acs.jced.8b00632
    9. Si Li, Lingyu Wang, Minghe Zhu, Dandan Han, Ya Liu, Mingyang Chen, Jie Hou, and Junbo Gong . Determination and Correlation of Solubility and Thermodynamic Properties of trans-Cinnamyl Alcohol in Pure and Binary Solvents from 253.15 K to 293.15 K. Journal of Chemical & Engineering Data 2018, 63 (1) , 77-88. https://doi.org/10.1021/acs.jced.7b00665
    10. Yuqiang Zhang, Fan Guo, Qiao Cui, Muyao Lu, Xiaolin Song, Hongjian Tang, and Qunsheng Li . Measurement and Correlation of the Solubility of Vanillic Acid in Eight Pure and Water + Ethanol Mixed Solvents at Temperatures from (293.15 to 323.15) K. Journal of Chemical & Engineering Data 2016, 61 (1) , 420-429. https://doi.org/10.1021/acs.jced.5b00619
    11. Fang Zhang, Yaocun Tang, Long Wang, Li Xu, and Guoji Liu . Solubility Measurement and Correlation for 2-Naphthaldehyde in Pure Organic Solvents and Methanol + Ethanol Mixtures. Journal of Chemical & Engineering Data 2015, 60 (8) , 2502-2509. https://doi.org/10.1021/acs.jced.5b00377
    12. Fang Zhang, Yaocun Tang, Long Wang, Li Xu, and Guoji Liu . Solubility Determination and Thermodynamic Models for 2-Methylnaphthalene in Different Solvents from T = (278.15 to 303.15) K. Journal of Chemical & Engineering Data 2015, 60 (6) , 1699-1705. https://doi.org/10.1021/je5010627
    13. Yuanming Tian, Jinhuan Li, Bin Wu, Yuqiang Zhang, Hongjian Tang, and Qunsheng Li . Determination and Modeling of the Solubility of 2,4-Dimethoxybenzoic Acid in Six Pure and Isopropanol + Ethyl Acetate Mixed Organic Solvents at Temperatures From (288.15 to 323.15) K. Journal of Chemical & Engineering Data 2015, 60 (4) , 1098-1105. https://doi.org/10.1021/je501045s
    14. Rongrong Li, Bin Zhang, Ling Wang, Ganbing Yao, Yingjie Zhang, and Hongkun Zhao . Experimental Measurement and Modeling of Solubility Data for 2,3-Dichloronitrobenzene in Methanol, Ethanol, and Liquid Mixtures (Methanol + Water, Ethanol + Water). Journal of Chemical & Engineering Data 2014, 59 (11) , 3586-3592. https://doi.org/10.1021/je500494d
    15. Kejian Cui, Yumei Yang, Zihui Meng, Guangrui Xu, Zhibin Xu, and Min Xue . Solubility of Tetranitrodimerglycoluril (TNDGU) in Different Solvents at Temperatures between 293.15 K and 313.15 K. Journal of Chemical & Engineering Data 2014, 59 (8) , 2620-2622. https://doi.org/10.1021/je500392g
    16. Hui Xu, Bin Zhang, Zhipeng Yang, Ganbing Yao, and Hongkun Zhao . Solubility of Dichloronitrobenzene in Eight Organic Solvents from T = (278.15 to 303.15) K: Measurement and Thermodynamic Modeling. Journal of Chemical & Engineering Data 2014, 59 (4) , 1281-1287. https://doi.org/10.1021/je401044h
    17. Yanan Qin, Xuemei Wang, Songgu Wu, and Junbo Gong . Solubility of 2-Hydroxypropane-1,2,3-tricarboxylic Acid Monohydrate in Different Binary Solvents from (278.15 to 303.15) K. Journal of Chemical & Engineering Data 2014, 59 (2) , 376-381. https://doi.org/10.1021/je400838e
    18. Haili Wu, Leping Dang, and Hongyuan Wei . Solid–Liquid Phase Equilibrium of Nicotinamide in Different Pure Solvents: Measurements and Thermodynamic Modeling. Industrial & Engineering Chemistry Research 2014, 53 (4) , 1707-1711. https://doi.org/10.1021/ie403628d
    19. Hongkun Zhao, Hui Xu, Zhipeng Yang, and Rongrong Li . Solubility of 3,4-Dichloronitrobenzene in Methanol, Ethanol, and Liquid Mixtures (Methanol + Water, Ethanol + Water): Experimental Measurement and Thermodynamic Modeling. Journal of Chemical & Engineering Data 2013, 58 (11) , 3061-3068. https://doi.org/10.1021/je400507u
    20. Qi Hao, Weiyi Su, Honghai Wang, Yatao Wang, Min Su, Yuqi Hu. Methanol-water manipulated polymorphic nucleation of L-Ornithine-L-Aspartate. Chemical Engineering Science 2024, 299 , 120541. https://doi.org/10.1016/j.ces.2024.120541
    21. Kadir AKSU. Potansiyel Biyolojik Aktif Metil-4,5-dimetoksi-2-(2-(4-metoksifenil)-2-oksoetil)benzoat’ın Sentezi. Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi 2021, 11 (3) , 2152-2159. https://doi.org/10.21597/jist.875097
    22. Xiaocong Li, Li Xu, Guoji Liu. Binary Solid–Liquid Solubility Determination and Model Correlation of Furaneol in Different Pure Solvents. Russian Journal of Physical Chemistry A 2020, 94 (13) , 2742-2751. https://doi.org/10.1134/S0036024420130130
    23. Mingyan Li, Zidan Gao, Zhili Li, Zhirong Wang, Rui Zhou, Baohua Wang. Determination and correlation of solubility of 4,4′-difluorobenzophenone in pure and binary mixed solvents and thermodynamic properties of solution. Journal of Molecular Liquids 2020, 317 , 113903. https://doi.org/10.1016/j.molliq.2020.113903
    24. Jonathan Z. Lu, William E. Acree, Michael H. Abraham. Abraham model correlations for enthalpies of solvation of organic solutes dissolved in methyl acetate and octane. Physics and Chemistry of Liquids 2020, 58 (1) , 18-30. https://doi.org/10.1080/00319104.2018.1534234
    25. Zongpeng Zou, Xiaobo Sun, Yi Yu, Xin Fang, Li Xu. Determination and correlation of solubility and solution thermodynamics of musk ketone in twelve pure solvents. Journal of Molecular Liquids 2019, 293 , 111437. https://doi.org/10.1016/j.molliq.2019.111437
    26. Sérgio M. Vilas-Boas, Vanessa Vieira, Paula Brandão, Rebeca S. Alves, João A.P. Coutinho, Simão P. Pinho, Olga Ferreira. Solvent and temperature effects on the solubility of syringic, vanillic or veratric acids: Experimental, modeling and solid phase studies. Journal of Molecular Liquids 2019, 289 , 111089. https://doi.org/10.1016/j.molliq.2019.111089
    27. Zongpeng Zou, Yi Yu, Xin Fang, Guoji Liu, Li Xu. Determination and correlation of solubility and solution thermodynamics of musk xylene in different pure solvents. The Journal of Chemical Thermodynamics 2019, 135 , 205-214. https://doi.org/10.1016/j.jct.2019.03.029
    28. Adel Noubigh, Mourad Cherif, Manef Abderrabba. Experimental data and thermodynamic modelling of gallic acid solubility in a variety of pure solvents. Physics and Chemistry of Liquids 2019, 57 (3) , 311-324. https://doi.org/10.1080/00319104.2018.1443454
    29. Yan Chen, Yanyang Wu, Xiangyang Zhang, Kui Chen, Bin Wu, Lijun Ji, Jiawen Zhu. Measurement and correlation of solubility and thermodynamic properties of N -acetyl- l -glutamine in some pure solvents and binary solvents at various temperatures. Chemical Engineering Communications 2019, 206 (3) , 355-364. https://doi.org/10.1080/00986445.2018.1493580
    30. Yi Yu, Fang Zhang, Xiaoqiang Gao, Li Xu, Guoji Liu. Experiment, correlation and molecular simulation for solubility of 4-methylphthalic anhydride in different organic solvents from T = (278.15 to 318.15) K. Journal of Molecular Liquids 2019, 275 , 768-777. https://doi.org/10.1016/j.molliq.2018.10.158
    31. Sérgio M. Vilas-Boas, Paula Brandão, Mónia A.R. Martins, Liliana P. Silva, Tatiana B. Schreiner, Luciano Fernandes, Olga Ferreira, Simão P. Pinho. Solubility and solid phase studies of isomeric phenolic acids in pure solvents. Journal of Molecular Liquids 2018, 272 , 1048-1057. https://doi.org/10.1016/j.molliq.2018.10.108
    32. Long Wang, Chengzong Xing, Li Xu, Guoji Liu. Solubility of 2-Chloro-3-(trifluoromethyl)pyridine and Correlation with the Polarity in Organic Solvents at 273–303 K. Russian Journal of Physical Chemistry A 2018, 92 (11) , 2204-2209. https://doi.org/10.1134/S0036024418110237
    33. Xin Tong, Delani Woods, William E. Acree, Michael H Abraham. Updated Abraham model correlations for correlating solute transfer into dry butanone and dry cyclohexanone solvents. Physics and Chemistry of Liquids 2018, 56 (5) , 571-583. https://doi.org/10.1080/00319104.2017.1354377
    34. Muyao Lu, Fan Guo, Bingjie Fan, Zhongqi Ren, Qunsheng Li. Solubility and solution thermodynamics of Raspberry Ketone in pure organic solvents and binary solvent mixtures from T = (293.15 to 333.15) K. Journal of Molecular Liquids 2017, 246 , 332-341. https://doi.org/10.1016/j.molliq.2017.09.084
    35. Long Wang, Chengzong Xing, Liqing Zhao, Li Xu, Guoji Liu. Measurement and correlation of solubility of 2-chloro-3-(trifluoromethyl)pyridine in pure solvents and ethanol + n -propanol mixtures. Journal of Molecular Liquids 2017, 238 , 470-477. https://doi.org/10.1016/j.molliq.2017.04.083
    36. William Acree, James S. Chickos. Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds and Ionic Liquids. Sublimation, Vaporization, and Fusion Enthalpies from 1880 to 2015. Part 2. C11–C192. Journal of Physical and Chemical Reference Data 2017, 46 (1) https://doi.org/10.1063/1.4970519
    37. Adel Noubigh, Manef Abderrabba. Solid–liquid phase equilibrium and thermodynamic properties of vanillic acid in different pure solvents. Journal of Molecular Liquids 2016, 223 , 261-266. https://doi.org/10.1016/j.molliq.2016.07.004
    38. William Acree, James S. Chickos. Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From 1880 to 2015. Part 1. C 1 − C 10. Journal of Physical and Chemical Reference Data 2016, 45 (3) , 033101. https://doi.org/10.1063/1.4948363
    39. Bingxue Li, Yanyang Wu, Jiawen Zhu, Kui Chen, Bin Wu, Lijun Ji. Determination and correlation of solubility and mixing properties of isonicotinamide (form II) in some pure solvents. Thermochimica Acta 2016, 627-629 , 55-60. https://doi.org/10.1016/j.tca.2016.01.012
    40. Aleksandr N. Shestakov, Mikhail A. Kuznetsov. Synthesis of di-, tri- and tetracyclopropylhydrazines. Chemical Communications 2016, 52 (11) , 2398-2400. https://doi.org/10.1039/C5CC07477K
    41. Jiangang Chen, Guanjun Nan, Rong Yang, Sanqi Zhang, Xiaoli Bian, Guangde Yang. Solubility of three types of benzamide derivatives in toluene, ethyl acetate, acetone, chloroform, methanol, and water at temperatures ranging from 288.15 to 328.15K at atmospheric pressure. Journal of Molecular Liquids 2015, 204 , 137-146. https://doi.org/10.1016/j.molliq.2015.01.045
    42. Jie Zhang, Yongli Wang, Guan Wang, Hongxun Hao, Huihui Wang, Qinghua Luan, Chen Jiang. Determination and correlation of solubility of spironolactone form II in pure solvents and binary solvent mixtures. The Journal of Chemical Thermodynamics 2014, 79 , 61-68. https://doi.org/10.1016/j.jct.2014.07.011
    43. William E. Acree. IUPAC-NIST Solubility Data Series. 99. Solubility of Benzoic Acid and Substituted Benzoic Acids in Both Neat Organic Solvents and Organic Solvent Mixtures. Journal of Physical and Chemical Reference Data 2013, 42 (3) https://doi.org/10.1063/1.4816161

    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2013, 58, 4, 1020–1028
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je400029t
    Published March 7, 2013
    Copyright © 2013 American Chemical Society

    Article Views

    585

    Altmetric

    -

    Citations

    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.