Bubble-Point Measurements of Eight Binary Mixtures for Organic Rankine Cycle Applications
View Author Information
Material Measurement Laboratory, Applied Chemicals and Materials Division, National Institute of Standards and Technology, 325 Broadway, Boulder, Colorado 80305-3337, United States
*E-mail: [email protected]
Abstract
The bubble-point pressures of two compositions of each of eight binary mixtures have been measured over a temperature range of 270 K to 380 K. Six of the mixtures included pentane, which was mixed with 1,1,1,3,3-pentafluoropropane (R-245fa); methyl perfluoropropyl ether (R-E347mcc); 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone; 1,1-dichloro-1-fluoroethane (R-141b); trans-1,3,3,3-tetrafluoropropene (R-1234ze(E)); and dimethyl ether. The two remaining binary mixtures were 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone + methyl perfluoropropyl ether (R-E347mcc) and butane + R-245fa. Interaction parameters for a Helmholtz energy mixture model were fitted for each mixture. Bubble-point data are reported as well as mixture model parameters, along with deviations of the data from their respective equations. These mixtures are of interest as working fluids in organic Rankine power cycles.
Cited By
This article is cited by 17 publications.
- Stephanie L. Outcalt, Aaron J. Rowane. Bubble Point Measurements of Mixtures of HFO and HFC Refrigerants. Journal of Chemical & Engineering Data 2021, 66 (12) , 4670-4683. https://doi.org/10.1021/acs.jced.1c00654
- Ian H. Bell, Demian Riccardi, Ala Bazyleva, Mark O. McLinden. Survey of Data and Models for Refrigerant Mixtures Containing Halogenated Olefins. Journal of Chemical & Engineering Data 2021, 66 (6) , 2335-2354. https://doi.org/10.1021/acs.jced.1c00192
- Megan E. Harries, Marcia L. Huber, Thomas J. Bruno. A Distillation Approach to Phase Equilibrium Measurements of Multicomponent Fluid Mixtures. Energy & Fuels 2019, 33 (8) , 7908-7915. https://doi.org/10.1021/acs.energyfuels.9b01366
- Fernando F. Czubinski, Carlos J. Noriega Sanchez, Alexandre K. da Silva, Moisés A. Marcelino Neto, Jader R. Barbosa, Jr.. Phase Equilibrium and Liquid Viscosity of CO2 + n-Dodecane Mixtures between 283 and 353 K. Journal of Chemical & Engineering Data 2019, 64 (8) , 3375-3384. https://doi.org/10.1021/acs.jced.9b00187
- Luuc Keulen, Elisabeth Mansfield, Ian H. Bell, Andrea Spinelli, Alberto Guardone. Bubble-Point Measurements and Modeling of Binary Mixtures of Linear Siloxanes. Journal of Chemical & Engineering Data 2018, 63 (9) , 3315-3330. https://doi.org/10.1021/acs.jced.8b00200
- Stephanie L. Outcalt, Tara J. Fortin. High-Accuracy, Temperature Dependent Density and Viscosity Measurements of a 50/50 JP-10 + Terpene Mixture. Energy & Fuels 2018, 32 (4) , 5103-5108. https://doi.org/10.1021/acs.energyfuels.7b03467
- Stephanie L. Outcalt. Compressed-Liquid Density Measurements of Four Polyol Ester-Based Lubricants. Energy & Fuels 2018, 32 (3) , 3775-3782. https://doi.org/10.1021/acs.energyfuels.8b00050
- Stephanie L. Outcalt . Compressed-Liquid Densities of Three “Reference” Turbine Fuels. Energy & Fuels 2016, 30 (12) , 10783-10788. https://doi.org/10.1021/acs.energyfuels.6b01820
- Elisabeth Mansfield, Ian H. Bell, and Stephanie L. Outcalt . Bubble-Point Measurements of n-Propane + n-Decane Binary Mixtures with Comparisons of Binary Mixture Interaction Parameters for Linear Alkanes. Journal of Chemical & Engineering Data 2016, 61 (7) , 2573-2579. https://doi.org/10.1021/acs.jced.6b00258
- Qiang Liu, Xiaojuan Feng, Baolin An, and Yuanyuan Duan . Speed of Sound Measurements Using a Cylindrical Resonator for Gaseous Carbon Dioxide and Propene. Journal of Chemical & Engineering Data 2014, 59 (9) , 2788-2798. https://doi.org/10.1021/je500424b
- Carlos J. Noriega Sanchez, Fernando F. Czubinski, Jader R. Barbosa Jr., Alexandre K. da Silva. Experimental data and Cubic-Equation-Of-State calculations of CO2/R-161 Vapor-Liquid equilibrium. The Journal of Chemical Thermodynamics 2022, 165 , 106635. https://doi.org/10.1016/j.jct.2021.106635
- Fernando F. Czubinski, Carlos J. Noriega Sanchez, Alexandre K. da Silva, Moisés A. Marcelino Neto, Jader R. Barbosa. Phase equilibrium and liquid viscosity data for R-290/POE ISO 22 mixtures between 283 and 353 K. International Journal of Refrigeration 2020, 114 , 79-87. https://doi.org/10.1016/j.ijrefrig.2020.02.029
- Matías Menossi, Juan M. Milanesio, Andrés Ciolino, Séverine Camy, Marcelo S. Zabaloy. Experimental pressure versus temperature isochoric – isoplethic curves for n-pentane – dimethyl ether, n-pentane – dimethyl ether – polybutadiene and n-pentane – dimethyl ether – polybutadiene– hydrogen at high pressures. The Journal of Supercritical Fluids 2020, 159 , 104660. https://doi.org/10.1016/j.supflu.2019.104660
- Quentin Blondel, Nicolas Tauveron, Nadia Caney, Nicolas Voeltzel. Experimental Study and Optimization of the Organic Rankine Cycle with Pure NovecTM649 and Zeotropic Mixture NovecTM649/HFE7000 as Working Fluid. Applied Sciences 2019, 9 (9) , 1865. https://doi.org/10.3390/app9091865
- Ram R. Ratnakar, Birol Dindoruk, Loren C. Wilson. Phase behavior experiments and PVT modeling of DME-brine-crude oil mixtures based on Huron-Vidal mixing rules for EOR applications. Fluid Phase Equilibria 2017, 434 , 49-62. https://doi.org/10.1016/j.fluid.2016.11.021
- Ram R. Ratnakar, Birol Dindoruk, Loren Wilson. Experimental investigation of DME–water–crude oil phase behavior and PVT modeling for the application of DME-enhanced waterflooding. Fuel 2016, 182 , 188-197. https://doi.org/10.1016/j.fuel.2016.05.096
- Elisabeth Mansfield, Stephanie L. Outcalt. Bubble-Point Measurements of n -Butane + n -Octane and n -Butane + n- Nonane Binary Mixtures. Journal of Chemical & Engineering Data 2015, 60 (8) , 2447-2453. https://doi.org/10.1021/acs.jced.5b00308