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Experimental and Modeling of Vapor–Liquid Equilibria for Electrolyte Solution Systems
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    Experimental and Modeling of Vapor–Liquid Equilibria for Electrolyte Solution Systems
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    College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong 266100, China
    *Tel.: +8613791914873. E-mail: [email protected]
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2014, 59, 11, 3741–3748
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    https://doi.org/10.1021/je500623w
    Published September 22, 2014
    Copyright © 2014 American Chemical Society

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    Vapor–liquid equilibrium (VLE) data are reported for binary and mixed electrolyte solutions containing CaCl2, MgCl2, K2SO4, MgSO4, and KCl at total molality of salt between (0.0 and 12.0) mol·kg–1. The measurements were carried out with a pressure between (6.3 and 101.3) kPa in a computer-controlled glass apparatus. An activity coefficient model based on the hypothesis of hydration was deduced in this paper. Experimental data and literature data for 20 salts, with temperature spanning from (273.15 to 415.85) K, were successfully correlated using the developed model. Meanwhile, the model was also successfully applied to predict the VLE data in mixed electrolyte solution systems with the binary parameters.

    Copyright © 2014 American Chemical Society

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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2014, 59, 11, 3741–3748
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je500623w
    Published September 22, 2014
    Copyright © 2014 American Chemical Society

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