P–ρ–T Data for 1-Butanol and Isobutyl Alcohol from (283.15 to 363.15) K at Pressures up to 66 MPa
- Gustavo A. Iglesias-Silva
- ,
- Micael Bravo-Sánchez
- ,
- Alejandro Estrada-Baltazar
- ,
- Christian Bouchot
- , and
- Kenneth R. Hall
Abstract

We present densities of pure 1-butanol and isobutyl alcohol from (283.15 to 363.15) K at pressures up to 66 MPa. We have measured densities using a vibrating tube densimeter. We use a forced path calibration method since this method depends mainly upon the mechanical properties of the cell. Experimental measurements of n-heptane have been measured to test the reliability of the apparatus. These measurements agree with a reference equation of state within 0.1 %. The new experimental densities of 1-butanol and isobutyl alcohol agree within 0.2 % with densities from the literature.
Cited By
This article is cited by 16 publications.
- Abel G. M. Ferreira, Jaime Batista Santos, Johnny Baptista, Saman Khalighi, Rui M. M. Brito, Pedro F. Cruz. Effect of Isobutanol Addition on the Biodiesel Density. Journal of Chemical & Engineering Data 2021, 66
(12)
, 4542-4562. https://doi.org/10.1021/acs.jced.1c00588
- Mishqah Hussain, Kuveneshan Moodley. P–ρ–T Data and Modeling for Butan-1-ol + n-Octane or n-Decane between 313.15–353.15 K and 0.1–20 MPa. Journal of Chemical & Engineering Data 2020, 65
(4)
, 1636-1654. https://doi.org/10.1021/acs.jced.9b01042
- Kuveneshan Moodley. Density, Speed of Sound, and Refractive Index Measurements for Mixtures of n-Heptane with Pentan-2-one or 4-Methylpentan-2-one for T = 298.15–338.15 K and 0.101 MPa. Journal of Chemical & Engineering Data 2020, 65
(4)
, 1761-1772. https://doi.org/10.1021/acs.jced.9b01070
- David Guerrero-Zárate, Gustavo A. Iglesias-Silva, Alejandro Estrada-Baltazar. P–ρ–T Data and Derivative Properties of 3-Methylpentane, 2,4-Dimethylpentane, and 2,3,4-Trimethylpentane from 283.15 to 363.15 K at Pressures up to 65 MPa. Journal of Chemical & Engineering Data 2019, 64
(12)
, 6020-6030. https://doi.org/10.1021/acs.jced.9b00846
- Kuveneshan Moodley, Carey-Lee Dorsamy, Caleb Narasigadu, Youlita Vemblanathan. Excess Properties and Phase Equilibria for the Potential Biofuel System of Propan-2-ol and 2-Methyl-propan-1-ol at 333.15, 343.15, and 353.15 K. Journal of Chemical & Engineering Data 2018, 63
(6)
, 2106-2113. https://doi.org/10.1021/acs.jced.8b00103
- Dan Fang, Xianyang Meng, and Jiangtao Wu . Compressed Liquid Densities of Binary Mixtures of 1-Butanol and Diethylene Glycol Dimethyl Ether from (283 to 363) K at Pressures up to 100 MPa. Journal of Chemical & Engineering Data 2017, 62
(9)
, 2937-2943. https://doi.org/10.1021/acs.jced.7b00176
- Martin A. Gomez-Osorio, Robert A. Browne, Mauricio Carvajal Diaz, Kenneth R. Hall, and James C. Holste . Density Measurements for Ethane, Carbon Dioxide, and Methane + Nitrogen Mixtures from 300 to 470 K up to 137 MPa Using a Vibrating Tube Densimeter. Journal of Chemical & Engineering Data 2016, 61
(8)
, 2791-2798. https://doi.org/10.1021/acs.jced.6b00138
- Micael G. Bravo-Sánchez, David Guerrero-Zárate, Gustavo A. Iglesias-Silva, and Alejandro Estrada-Baltazar , Christian Bouchot . P–ρ–T Data for 2-Butanol and tert-Butanol from 283.15 to 363.15 K and 303.15 to 363.15 K at Pressures up to 66 MPa. Journal of Chemical & Engineering Data 2016, 61
(4)
, 1555-1565. https://doi.org/10.1021/acs.jced.5b00934
- R. Villablanca-Ahues, R. Nagl, T. Zeiner, P. Jaeger. Interfacial tension and phase equilibria for binary systems containing (CH4-CO2)+(n-dodecane; n-butanol; water). Fluid Phase Equilibria 2023, 570 , 113783. https://doi.org/10.1016/j.fluid.2023.113783
- Daniel Benestante Hauk, Ricardo Belchior Torres, José Vicente Hallak Dangelo. Binary mixtures of {1-Ethyl-3-methylimidazolium trifluoromethanesulfonate ([EMIM][triflate]) + alcohols} at high-pressure: A thermodynamic, spectroscopic and correlation approach. The Journal of Chemical Thermodynamics 2022, 169 , 106742. https://doi.org/10.1016/j.jct.2022.106742
- Beatriz Lorenzo, José Aythami Yánez, Juan Ortega, Adriel Sosa, Luis Fernández. Liquid-State Volumetric Properties of a Set of Alcohols with Up to Five Carbon Atoms. Liquids 2022, 2
(1)
, 1-13. https://doi.org/10.3390/liquids2010001
- Vincenzo P. Cotroneo-Figueroa, Nicolás F. Gajardo-Parra, Pablo López-Porfiri, Ángel Leiva, Maria Gonzalez-Miquel, José Matías Garrido, Roberto I. Canales. Hydrogen bond donor and alcohol chain length effect on the physicochemical properties of choline chloride based deep eutectic solvents mixed with alcohols. Journal of Molecular Liquids 2022, 345 , 116986. https://doi.org/10.1016/j.molliq.2021.116986
- Daniel B. Hauk, Ricardo Belchior Torres, José Vicente Hallak d'Angelo. Thermodynamic and spectroscopic properties of binary {1-Ethyl-3-methylimidazolium thiocyanate ([EMIM][SCN]) + alcohols} mixtures at T = (298.15 to 308.15) K and p = (0.1 to 40) MPa: Experimental study and modelling. The Journal of Chemical Thermodynamics 2021, 160 , 106489. https://doi.org/10.1016/j.jct.2021.106489
- Mishqah Hussain, Kuveneshan Moodley. P-ρ-T data and modelling for (2-methylpropan-1-ol + n-octane or n-decane) between 313.15 K–353.15 K and 0.1–20 MPa. The Journal of Chemical Thermodynamics 2021, 152 , 106279. https://doi.org/10.1016/j.jct.2020.106279
- Divna M. Majstorović, Ivona R. Radović, Mirjana Lj. Kijevčanin, Emila M. Živković. Thermodynamic study of ester diethyl tartrate and its binary systems with iso-alcohols. Fluid Phase Equilibria 2020, 509 , 112461. https://doi.org/10.1016/j.fluid.2020.112461
- Zuber S. Vaid, Utkarsh U. More, Shantilal B. Oswal, Naved I. Malek. Experimental and theoretical excess molar properties of imidazolium based ionic liquids with isomers of butanol. Thermochimica Acta 2016, 634 , 38-47. https://doi.org/10.1016/j.tca.2016.03.026