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Measurement and Correlation of Diffusion Coefficients of Aromatic Compounds at Infinite Dilution in Alkane and Cycloalkane Solvents

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Laboratoire MSNM-GP, UMR 6181, Faculté des Sciences de Luminy, Université de la Méditerranée, 13288 Marseille, Cedex 9, France
Cite this: J. Chem. Eng. Data 2007, 52, 3, 977–981
Publication Date (Web):March 31, 2007
https://doi.org/10.1021/je6005604
Copyright © 2007 American Chemical Society

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    Abstract

    The Taylor dispersion technique was used to measure the diffusion coefficients of benzene, chlorobenzene, ethylbenzene, toluene, p-chlorotoluene, naphthalene, pyrene, and perylene at infinite dilution in mixtures of hexane + octane, hexane + decane, heptane + octane, heptane + decane, octane + decane, cyclohexane + hexane, cyclohexane + heptane, cyclohexane + octane, and cyclohexane + decane at 298.15 K. Experimental data were correlated satisfactorily by means of the Leffler−Cullinan equation using the measured values of solutes in the pure solvents and a group contribution method for estimating the viscosity of the solvent mixtures.

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     Corresponding author. E-mail:  [email protected]. Fax:  +33 4 91 82 91 52.

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    20. Jochen Winkelmann. Diffusion coefficient of ethylbenzene in octane at infinite dilution. 2018, 2644-2644. https://doi.org/10.1007/978-3-662-54089-3_2038
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    22. Jochen Winkelmann. Diffusion coefficient of naphthalene in cyclohexane at infinite dilution. 2018, 2794-2794. https://doi.org/10.1007/978-3-662-54089-3_2186
    23. Jochen Winkelmann. Diffusion coefficient of naphthalene in octane at infinite dilution. 2018, 2798-2798. https://doi.org/10.1007/978-3-662-54089-3_2190
    24. Jochen Winkelmann. Diffusion coefficient of naphthalene in decane at infinite dilution. 2018, 2799-2799. https://doi.org/10.1007/978-3-662-54089-3_2191
    25. Jochen Winkelmann. Diffusion coefficient of pyrene in cyclohexane at infinite dilution. 2018, 2993-2993. https://doi.org/10.1007/978-3-662-54089-3_2383
    26. Jochen Winkelmann. Diffusion coefficient of pyrene in octane at infinite dilution. 2018, 2997-2997. https://doi.org/10.1007/978-3-662-54089-3_2387
    27. Jochen Winkelmann. Diffusion coefficient of pyrene in decane at infinite dilution. 2018, 2998-2998. https://doi.org/10.1007/978-3-662-54089-3_2388
    28. Jochen Winkelmann. Diffusion coefficient of perylene in cyclohexane at infinite dilution. 2018, 3056-3056. https://doi.org/10.1007/978-3-662-54089-3_2445
    29. Jochen Winkelmann. Diffusion coefficient of perylene in octane at infinite dilution. 2018, 3060-3060. https://doi.org/10.1007/978-3-662-54089-3_2449
    30. Jochen Winkelmann. Diffusion coefficient of perylene in decane at infinite dilution. 2018, 3061-3061. https://doi.org/10.1007/978-3-662-54089-3_2450
    31. Jochen Winkelmann. Diffusion coefficient of chlorobenzene into cyclohexane and hexane at infinite dilution. 2018, 3389-3389. https://doi.org/10.1007/978-3-662-54089-3_2745
    32. Jochen Winkelmann. Diffusion coefficient of chlorobenzene into cyclohexane and heptane at infinite dilution. 2018, 3390-3390. https://doi.org/10.1007/978-3-662-54089-3_2746
    33. Jochen Winkelmann. Diffusion coefficient of chlorobenzene into cyclohexane and octane at infinite dilution. 2018, 3391-3391. https://doi.org/10.1007/978-3-662-54089-3_2747
    34. Jochen Winkelmann. Diffusion coefficient of chlorobenzene into cyclohexane and decane at infinite dilution. 2018, 3392-3392. https://doi.org/10.1007/978-3-662-54089-3_2748
    35. Jochen Winkelmann. Diffusion coefficient of chlorobenzene into hexane and octane at infinite dilution. 2018, 3394-3394. https://doi.org/10.1007/978-3-662-54089-3_2750
    36. Jochen Winkelmann. Diffusion coefficient of chlorobenzene into hexane and decane at infinite dilution. 2018, 3395-3395. https://doi.org/10.1007/978-3-662-54089-3_2751
    37. Jochen Winkelmann. Diffusion coefficient of chlorobenzene into heptane and octane at infinite dilution. 2018, 3396-3396. https://doi.org/10.1007/978-3-662-54089-3_2752
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    39. Jochen Winkelmann. Diffusion coefficient of chlorobenzene into octane and decane at infinite dilution. 2018, 3398-3398. https://doi.org/10.1007/978-3-662-54089-3_2754
    40. Jochen Winkelmann. Diffusion coefficient of benzene into cyclohexane and hexane at infinite dilution. 2018, 3409-3409. https://doi.org/10.1007/978-3-662-54089-3_2764
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    44. Jochen Winkelmann. Diffusion coefficient of benzene into hexane and octane at infinite dilution. 2018, 3416-3416. https://doi.org/10.1007/978-3-662-54089-3_2770
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    48. Jochen Winkelmann. Diffusion coefficient of benzene into octane and decane at infinite dilution. 2018, 3421-3421. https://doi.org/10.1007/978-3-662-54089-3_2775
    49. Jochen Winkelmann. Diffusion coefficient of 4-chloro-toluene into cyclohexane and hexane at infinite dilution. 2018, 3427-3427. https://doi.org/10.1007/978-3-662-54089-3_2781
    50. Jochen Winkelmann. Diffusion coefficient of 4-chloro-toluene into cyclohexane and heptane at infinite dilution. 2018, 3428-3428. https://doi.org/10.1007/978-3-662-54089-3_2782
    51. Jochen Winkelmann. Diffusion coefficient of 4-chloro-toluene into cyclohexane and octane at infinite dilution. 2018, 3429-3429. https://doi.org/10.1007/978-3-662-54089-3_2783
    52. Jochen Winkelmann. Diffusion coefficient of 4-chloro-toluene into cyclohexane and decane at infinite dilution. 2018, 3430-3430. https://doi.org/10.1007/978-3-662-54089-3_2784
    53. Jochen Winkelmann. Diffusion coefficient of 4-chloro-toluene into hexane and octane at infinite dilution. 2018, 3432-3432. https://doi.org/10.1007/978-3-662-54089-3_2786
    54. Jochen Winkelmann. Diffusion coefficient of 4-chloro-toluene into hexane and decane at infinite dilution. 2018, 3433-3433. https://doi.org/10.1007/978-3-662-54089-3_2787
    55. Jochen Winkelmann. Diffusion coefficient of 4-chloro-toluene into heptane and octane at infinite dilution. 2018, 3434-3434. https://doi.org/10.1007/978-3-662-54089-3_2788
    56. Jochen Winkelmann. Diffusion coefficient of 4-chloro-toluene into heptane and decane at infinite dilution. 2018, 3435-3435. https://doi.org/10.1007/978-3-662-54089-3_2789
    57. Jochen Winkelmann. Diffusion coefficient of 4-chloro-toluene into octane and decane at infinite dilution. 2018, 3436-3436. https://doi.org/10.1007/978-3-662-54089-3_2790
    58. Jochen Winkelmann. Diffusion coefficient of toluene into cyclohexane and hexane at infinite dilution. 2018, 3437-3437. https://doi.org/10.1007/978-3-662-54089-3_2791
    59. Jochen Winkelmann. Diffusion coefficient of toluene into cyclohexane and heptane at infinite dilution. 2018, 3438-3438. https://doi.org/10.1007/978-3-662-54089-3_2792
    60. Jochen Winkelmann. Diffusion coefficient of toluene into cyclohexane and octane at infinite dilution. 2018, 3439-3439. https://doi.org/10.1007/978-3-662-54089-3_2793
    61. Jochen Winkelmann. Diffusion coefficient of toluene into cyclohexane and decane at infinite dilution. 2018, 3440-3440. https://doi.org/10.1007/978-3-662-54089-3_2794
    62. Jochen Winkelmann. Diffusion coefficient of toluene into hexane and octane at infinite dilution. 2018, 3442-3442. https://doi.org/10.1007/978-3-662-54089-3_2796
    63. Jochen Winkelmann. Diffusion coefficient of toluene into hexane and decane at infinite dilution. 2018, 3443-3443. https://doi.org/10.1007/978-3-662-54089-3_2797
    64. Jochen Winkelmann. Diffusion coefficient of toluene into heptane and octane at infinite dilution. 2018, 3444-3444. https://doi.org/10.1007/978-3-662-54089-3_2798
    65. Jochen Winkelmann. Diffusion coefficient of toluene into heptane and decane at infinite dilution. 2018, 3445-3445. https://doi.org/10.1007/978-3-662-54089-3_2799
    66. Jochen Winkelmann. Diffusion coefficient of toluene into octane and decane at infinite dilution. 2018, 3446-3446. https://doi.org/10.1007/978-3-662-54089-3_2800
    67. Jochen Winkelmann. Diffusion coefficient of ethylbenzene into cyclohexane and hexane at infinite dilution. 2018, 3447-3447. https://doi.org/10.1007/978-3-662-54089-3_2801
    68. Jochen Winkelmann. Diffusion coefficient of ethylbenzene into cyclohexane and heptane at infinite dilution. 2018, 3448-3448. https://doi.org/10.1007/978-3-662-54089-3_2802
    69. Jochen Winkelmann. Diffusion coefficient of ethylbenzene into cyclohexane and octane at infinite dilution. 2018, 3449-3449. https://doi.org/10.1007/978-3-662-54089-3_2803
    70. Jochen Winkelmann. Diffusion coefficient of ethylbenzene into cyclohexane and decane at infinite dilution. 2018, 3450-3450. https://doi.org/10.1007/978-3-662-54089-3_2804
    71. Jochen Winkelmann. Diffusion coefficient of ethylbenzene into hexane and octane at infinite dilution. 2018, 3452-3452. https://doi.org/10.1007/978-3-662-54089-3_2806
    72. Jochen Winkelmann. Diffusion coefficient of ethylbenzene into hexane and decane at infinite dilution. 2018, 3453-3453. https://doi.org/10.1007/978-3-662-54089-3_2807
    73. Jochen Winkelmann. Diffusion coefficient of ethylbenzene into heptane and octane at infinite dilution. 2018, 3454-3454. https://doi.org/10.1007/978-3-662-54089-3_2808
    74. Jochen Winkelmann. Diffusion coefficient of ethylbenzene into heptane and decane at infinite dilution. 2018, 3455-3455. https://doi.org/10.1007/978-3-662-54089-3_2809
    75. Jochen Winkelmann. Diffusion coefficient of ethylbenzene into octane and decane at infinite dilution. 2018, 3456-3456. https://doi.org/10.1007/978-3-662-54089-3_2810
    76. Jochen Winkelmann. Diffusion coefficient of naphthalene into cyclohexane and hexane at infinite dilution. 2018, 3458-3458. https://doi.org/10.1007/978-3-662-54089-3_2812
    77. Jochen Winkelmann. Diffusion coefficient of naphthalene into cyclohexane and heptane at infinite dilution. 2018, 3459-3459. https://doi.org/10.1007/978-3-662-54089-3_2813
    78. Jochen Winkelmann. Diffusion coefficient of naphthalene into cyclohexane and octane at infinite dilution. 2018, 3460-3460. https://doi.org/10.1007/978-3-662-54089-3_2814
    79. Jochen Winkelmann. Diffusion coefficient of naphthalene into cyclohexane and decane at infinite dilution. 2018, 3461-3461. https://doi.org/10.1007/978-3-662-54089-3_2815
    80. Jochen Winkelmann. Diffusion coefficient of naphthalene into hexane and octane at infinite dilution. 2018, 3463-3463. https://doi.org/10.1007/978-3-662-54089-3_2817
    81. Jochen Winkelmann. Diffusion coefficient of naphthalene into hexane and decane at infinite dilution. 2018, 3464-3464. https://doi.org/10.1007/978-3-662-54089-3_2818
    82. Jochen Winkelmann. Diffusion coefficient of naphthalene into heptane and octane at infinite dilution. 2018, 3465-3465. https://doi.org/10.1007/978-3-662-54089-3_2819
    83. Jochen Winkelmann. Diffusion coefficient of naphthalene into heptane and decane at infinite dilution. 2018, 3466-3466. https://doi.org/10.1007/978-3-662-54089-3_2820
    84. Jochen Winkelmann. Diffusion coefficient of naphthalene into octane and decane at infinite dilution. 2018, 3467-3467. https://doi.org/10.1007/978-3-662-54089-3_2821
    85. Jochen Winkelmann. Diffusion coefficient of pyrene into cyclohexane and hexane at infinite dilution. 2018, 3473-3473. https://doi.org/10.1007/978-3-662-54089-3_2826
    86. Jochen Winkelmann. Diffusion coefficient of pyrene into cyclohexane and heptane at infinite dilution. 2018, 3474-3474. https://doi.org/10.1007/978-3-662-54089-3_2827
    87. Jochen Winkelmann. Diffusion coefficient of pyrene into cyclohexane and octane at infinite dilution. 2018, 3475-3475. https://doi.org/10.1007/978-3-662-54089-3_2828
    88. Jochen Winkelmann. Diffusion coefficient of pyrene into cyclohexane and decane at infinite dilution. 2018, 3476-3476. https://doi.org/10.1007/978-3-662-54089-3_2829
    89. Jochen Winkelmann. Diffusion coefficient of pyrene into hexane and octane at infinite dilution. 2018, 3478-3478. https://doi.org/10.1007/978-3-662-54089-3_2831
    90. Jochen Winkelmann. Diffusion coefficient of pyrene into hexane and decane at infinite dilution. 2018, 3479-3479. https://doi.org/10.1007/978-3-662-54089-3_2832
    91. Jochen Winkelmann. Diffusion coefficient of pyrene into heptane and octane at infinite dilution. 2018, 3480-3480. https://doi.org/10.1007/978-3-662-54089-3_2833
    92. Jochen Winkelmann. Diffusion coefficient of pyrene into heptane and decane at infinite dilution. 2018, 3481-3481. https://doi.org/10.1007/978-3-662-54089-3_2834
    93. Jochen Winkelmann. Diffusion coefficient of pyrene into octane and decane at infinite dilution. 2018, 3482-3482. https://doi.org/10.1007/978-3-662-54089-3_2835
    94. Jochen Winkelmann. Diffusion coefficient of perylene into cyclohexane and hexane at infinite dilution. 2018, 3484-3484. https://doi.org/10.1007/978-3-662-54089-3_2837
    95. Jochen Winkelmann. Diffusion coefficient of perylene into cyclohexane and heptane at infinite dilution. 2018, 3485-3485. https://doi.org/10.1007/978-3-662-54089-3_2838
    96. Jochen Winkelmann. Diffusion coefficient of perylene into cyclohexane and octane at infinite dilution. 2018, 3486-3486. https://doi.org/10.1007/978-3-662-54089-3_2839
    97. Jochen Winkelmann. Diffusion coefficient of perylene into cyclohexane and decane at infinite dilution. 2018, 3487-3487. https://doi.org/10.1007/978-3-662-54089-3_2840
    98. Jochen Winkelmann. Diffusion coefficient of perylene into hexane and octane at infinite dilution. 2018, 3489-3489. https://doi.org/10.1007/978-3-662-54089-3_2842
    99. Jochen Winkelmann. Diffusion coefficient of perylene into hexane and decane at infinite dilution. 2018, 3490-3490. https://doi.org/10.1007/978-3-662-54089-3_2843
    100. Jochen Winkelmann. Diffusion coefficient of perylene into heptane and octane at infinite dilution. 2018, 3491-3491. https://doi.org/10.1007/978-3-662-54089-3_2844
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