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Solubilities of 2,4,8,10-Tetraoxa-3,9-diphosphaspiro[5.5]undecane-3,9-dimethanol, α,α,α‘,α‘-tetramethyl-3,9-dioxide in Selected Solvents

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School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, People's Republic of China
Cite this: J. Chem. Eng. Data 2007, 52, 4, 1340–1342
Publication Date (Web):May 31, 2007
https://doi.org/10.1021/je700050r
Copyright © 2007 American Chemical Society

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    Abstract

    A phosphorus-containing flame retardant 2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane-3,9-dimethanol, α,α,α‘,α‘-tetramethyl-3,9-dioxide (DPDM) was synthesized. The structure and the thermal stability of the compound were characterized by infrared spectroscopy (IR), nuclear magnetic resonance (1H NMR), mass spectroscopy (MS), elemental analysis, and thermogravimetric analysis. Using a static analytical method, the solubilities of DPDM in acetic acid + acetone binary mixtures, water, methanol, and ethanol were determined in the temperature range from (293.14 to 338.14) K. The solubility data were correlated with an empirical equation.

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     Corresponding author. Fax:  +86-10-68911040. E-mail:  [email protected].

    Cited By

    This article is cited by 5 publications.

    1. Xiao Ma, Qianqiong Zhao, Qianwen Liu, Yalin Xing, Ruilan Fan, and Rongkai Tian . Synthesis and Solubility of 5,5-Dimethyl-2-(phenyl(phenylamino)methyl)-1,3,2-dioxaphosphinane 2-oxide in Selected Solvents between 278.15 K and 347.15 K. Journal of Chemical & Engineering Data 2017, 62 (12) , 4196-4204. https://doi.org/10.1021/acs.jced.7b00585
    2. Lai Guo, Rui-lan Fan, Guan-qun Yun, and Cong-yan Chen . Solubilities of 1,3,2-Dioxaphosphorinane-2-methanol-α,α-5,5-tetramethyl 2-oxide in Selected Solvents at 273.15 K to 343.15 K. Journal of Chemical & Engineering Data 2013, 58 (8) , 2267-2271. https://doi.org/10.1021/je4003114
    3. Xiu-Zhi Guo, Li-Sheng Wang, Biao Wang and Na-Na Tian. Solubilities of 3,9-Dimethyl-3,9-dioxide-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane in Selected Solvents. Journal of Chemical & Engineering Data 2010, 55 (2) , 978-981. https://doi.org/10.1021/je9004189
    4. Zhan Xi Bian, Guan Qun Yun, Rui Lan Fan, Lai Guo, Shu Feng Chen. Synthesis and Solubilities of 2,6,7-Trioxa-1-Phospha Bicycle [2,2,2] Octane-4-Carboxylic Acid 1-Oxide in Selected Solvents. Advanced Materials Research 2013, 634-638 , 445-450. https://doi.org/10.4028/www.scientific.net/AMR.634-638.445
    5. Ru-Yi Jiang, Li-Sheng Wang. Solubilities of Hexaphenoxycyclotriphosphazene and Tri(2-cyanoethyl)phosphine in Selected Solvents: Measurement and Correlation. Journal of Solution Chemistry 2012, 41 (12) , 2107-2122. https://doi.org/10.1007/s10953-012-9930-4

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