Molar Heat Capacities, Thermodynamic Properties, and Thermal Stability of trans-4-(Aminomethyl)cyclohexanecarboxylic Acid
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College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China, Department of Chemistry and Chemical Engineering, Hunan University of Arts and Science, Changde 415000, China, Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China, and Dongting Pharmaceutical Company, Ltd., Changde 415000, China
Abstract
The low-temperature heat capacities of trans-4-(aminomethyl)cyclohexanecarboxylic acid were measured with an adiabatic calorimeter over the temperature range from (82 to 378) K. The heat capacity curve was smooth and continuous, which indicated that the compound was stable over the whole temperature range. Thermal decompositions of the compound were studied by thermogravimetry (TG) and the possible mechanism of the thermal decomposition was deduced. The energy of combustion of the compound was determined, and the standard enthalpy of combustion, ΔcHϑ, and standard enthalpy of formation, ΔfHϑ, were calculated.
†
Hunan Normal University.
‡
Hunan University of Arts and Science.
§
Dalian Institute of Chemical Physics, Chinese Academy of Sciences.
*
Corresponding author. Fax: 86-411-4694447. Telephone: 86-411-84379199. E-mail: [email protected].
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Dongting Pharmaceutical Co., Ltd.
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