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High-Pressure Vapor−Liquid Equilibrium Data for Systems Involving Carbon Dioxide + Organic Solvent + β-Carotene

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Department of Food Engineering, URI - Campus de Erechim, Av. Sete de Setembro, 1621, Erechim, RS, 99700-000, Brazil, and Instituto de Pesquisa e Tecnologia-ITP, Programa de Mestrado em Engenharia de Processos PEP/UNIT, Campus Farolândia, Av. Murilo Dantas, 300, Aracaju, SE, 49032-490, Brazil
Cite this: J. Chem. Eng. Data 2007, 52, 4, 1437–1441
Publication Date (Web):June 6, 2007
https://doi.org/10.1021/je700125v
Copyright © 2007 American Chemical Society
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    Abstract

    This work reports experimental phase equilibrium (transition points) data for the systems CO2 + ethyl acetate, CO2 + ethyl acetate + β-carotene, and CO2 + ethanol + β-carotene at different concentrations of β-carotene in the organic (liquid) solvents. For this purpose, the static synthetic method, using a variable-volume view cell, was employed for obtaining the experimental data in the temperature range from (303 to 343) K and pressures up to 12 MPa. Vapor−liquid phase transitions were observed as bubble and dew points for all overall compositions investigated. In a general sense, it was experimentally observed that the addition of β-carotene leads to negligible changes in pressure transition values compared to CO2 + solvent systems. The Peng−Robinson equation of state, with the classical van der Waals quadratic mixing rule, was employed for the thermodynamic modeling of the systems investigated with a satisfactory agreement between experiment and theory. It was also observed that the interaction parameters of β-carotene/organic solvent and β-carotene/CO2 need not be considered for efficient prediction of phase behavior of the ternary systems.

    †

     Department of Food Engineering, URI - Campus de Erechim.

    *

     Corresponding author. Tel.:  +55-79-32182115. Fax:  +55-79-32182190. E-mail address:  [email protected].

    ‡

     Instituto de Pesquisa e Tecnologia-ITP.

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