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Densities and Excess Molar Volumes of N-Methylmorpholine + 1-Alkanol Systems at 298.15 K

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Industrial Chemistry Centre, Royal Scientific Society, P.O. Box 1438, Al-Jubaiha 11941, Amman, Jordan
* Corresponding author. E-mail: [email protected]; [email protected]
Cite this: J. Chem. Eng. Data 2008, 53, 1, 307–309
Publication Date (Web):December 19, 2007
https://doi.org/10.1021/je7005055
Copyright © 2008 American Chemical Society

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    Abstract

    Densities, ρ, of pure N-methylmorpholine (1) + ethanol (2), + 1-propanol (2), + 1-butanol (2), + 1-pentanol (2), + 1-hexanol (2), and + 1-octanol (2) and their binary mixtures were measured using a digital vibrating tube densimeter at 298.15 K. Excess molar volumes, VE, of the binary mixtures were calculated from density values. Excess molar volumes of binary mixtures of N-methylmorpholine (1) + ethanol (2) and + 1-propanol (2) show an S-shaped dependence on composition with positive values in the N-methylmorpholine-rich region and negative values at the opposite extreme. The excess molar volume is positive over the mole fraction range for N-methylmorpholine (1) + 1-butanol (2), + 1-pentanol (2), 1-hexanol (2), and + 1-octanol (2) systems. All experimental VE values were fitted to the Redlich–Kister equation.

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