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Activity Coefficients at Infinite Dilution of Polar Solutes in 1-Propyl-2,3-dimethylimidazolium Tetrafluoroborate Using Gas–Liquid Chromatography

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School of Chemical Engineering & the Environment, Beijing Institute of Technology, Beijing 100081, People’s Republic of China
* Corresponding author. E-mail: [email protected]
†Present address: Department of Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, People’s Republic of China. E-mail: [email protected].
Cite this: J. Chem. Eng. Data 2008, 53, 3, 871–873
Publication Date (Web):February 14, 2008
https://doi.org/10.1021/je700640r
Copyright © 2008 American Chemical Society

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    Abstract

    Activity coefficients at infinite dilution γi of 17 polar solutes (linear and branched C1 to C5 alcohols, acetonitrile, acetone, 1,4-dioxane, tetrahydrofuran, ethyl acetate, and chloromethanes) in the ionic liquid 1-propyl-2,3-dimethylimidazolium tetrafluoroborate ([PDMIM][BF4]) have been measured by the gas−liquid chromatographic method with the ionic liquid as the stationary phase. The measurements were carried out in the temperature range of (303.15 to 363.15) K. The partial molar excess enthalpies at infinite dilution HiE,∞ of the solutes in the ionic liquid were also derived from the temperature dependence of the γi values.

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