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Densities and Excess Enthalpies for Ionic Liquids + Ethanol or + Nitromethane

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Departamento de Física Aplicada, Universidad de Vigo, Facultad de Ciencias, Campus As Lagoas, 32004, Ourense, Spain
* Corresponding author. Tel.: +34988387213 . Fax: +34988387227. E-mail: [email protected]
Cite this: J. Chem. Eng. Data 2008, 53, 6, 1298–1301
Publication Date (Web):April 26, 2008
https://doi.org/10.1021/je700754k
Copyright © 2008 American Chemical Society

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    Abstract

    Density in the temperature interval (293.15 to 323.15) K and excess enthalpy at 303.15 K are determined for 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM][BF4] + ethanol or + nitromethane and 1-butyl-3-methylimidazolium methylsulfate [BMIM][MeSO4] + ethanol or + nitromethane. Excess molar volumes are calculated at several temperatures from density data. Both excess properties are fitted to a Redlich−Kister-based equation, and results are discussed in terms of the chemical nature of the compounds that form the mixtures.

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