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    Densities and Excess Enthalpies for Ionic Liquids + Ethanol or + Nitromethane
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    Departamento de Física Aplicada, Universidad de Vigo, Facultad de Ciencias, Campus As Lagoas, 32004, Ourense, Spain
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2008, 53, 6, 1298–1301
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    https://doi.org/10.1021/je700754k
    Published April 26, 2008
    Copyright © 2008 American Chemical Society
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    Abstract

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    Density in the temperature interval (293.15 to 323.15) K and excess enthalpy at 303.15 K are determined for 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM][BF4] + ethanol or + nitromethane and 1-butyl-3-methylimidazolium methylsulfate [BMIM][MeSO4] + ethanol or + nitromethane. Excess molar volumes are calculated at several temperatures from density data. Both excess properties are fitted to a Redlich−Kister-based equation, and results are discussed in terms of the chemical nature of the compounds that form the mixtures.

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    3. A. Podgoršek, J. Jacquemin, A. A. H. Pádua, and M. F. Costa Gomes . Mixing Enthalpy for Binary Mixtures Containing Ionic Liquids. Chemical Reviews 2016, 116 (10) , 6075-6106. https://doi.org/10.1021/acs.chemrev.5b00379
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    6. Zhibo Zhang, Qing Zhou, Xingmei Lu, Congzhen Qiao, and Suojiang Zhang . Densities and Viscosities of Binary Mixtures Containing 1,3-Dimethylimidazolium Dimethylphosphate and Alcohols. Journal of Chemical & Engineering Data 2014, 59 (8) , 2377-2388. https://doi.org/10.1021/je401124t
    7. Elise A. Cade, David R. Saeva, and Markus M. Hoffmann . Comparing Composition- and Temperature-Dependent Excess Molar Volumes of Binary Systems Involving Ionic Liquids. Journal of Chemical & Engineering Data 2014, 59 (6) , 1892-1914. https://doi.org/10.1021/je500053c
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    13. S. M. Hosseini, J. Moghadasi, M. M. Papari, and F. Fadaei Nobandegani . Modeling the Volumetric Properties of Ionic Liquids Using Modified Perturbed Hard-Sphere Equation of State: Application to Pure and Binary Mixtures. Industrial & Engineering Chemistry Research 2012, 51 (2) , 758-766. https://doi.org/10.1021/ie2012455
    14. Pankaj Attri, Pannuru Venkatesu, and T. Hofman . Temperature Dependence Measurements and Structural Characterization of Trimethyl Ammonium Ionic Liquids with a Highly Polar Solvent. The Journal of Physical Chemistry B 2011, 115 (33) , 10086-10097. https://doi.org/10.1021/jp2059084
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    38. Mikhail A. Varfolomeev, Artashes A. Khachatrian, Bulat S. Akhmadeev, Boris N. Solomonov. Thermodynamics of hydrogen bonding and van der Waals interactions of organic solutes in solutions of imidazolium based ionic liquids: “Structure-property” relationships. Thermochimica Acta 2016, 633 , 12-23. https://doi.org/10.1016/j.tca.2016.03.036
    39. M. M. Alavianmehr, M. Taghizadehfard, S. M. Hosseini. Development of a perturbed hard-sphere equation of state for pure and mixture of ionic liquids. Ionics 2016, 22 (5) , 649-660. https://doi.org/10.1007/s11581-015-1578-9
    40. Suojiang Zhang, Qing Zhou, Xingmei Lu, Yuting Song, Xinxin Wang. Properties of 1-butyl-3-methylimidazolium tetrafluoroborate mixtures. 2016, 398-484. https://doi.org/10.1007/978-94-017-7573-1_34
    41. Suojiang Zhang, Qing Zhou, Xingmei Lu, Yuting Song, Xinxin Wang. Properties of 1-butyl-3-methyl imidazolium methylsulfate mixtures. 2016, 563-586. https://doi.org/10.1007/978-94-017-7573-1_41
    42. Dharmendra Singh, Vickramjeet Singh, Ramesh L. Gardas. Volumetric and Acoustic Properties of a DBU (1,8-Diazobicyclo[5.4.0]undec-7-ene) Based Protic Ionic Liquid in Water at T = (293.15 to 328.15) K. Journal of Solution Chemistry 2015, 44 (3-4) , 634-651. https://doi.org/10.1007/s10953-015-0313-5
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    44. Zhigang Lei, Chengna Dai, Jiqin Zhu, Biaohua Chen. Extractive distillation with ionic liquids: A review. AIChE Journal 2014, 60 (9) , 3312-3329. https://doi.org/10.1002/aic.14537
    45. Torben Hector, Jürgen Gmehling. Present status of the modified UNIFAC model for the prediction of phase equilibria and excess enthalpies for systems with ionic liquids. Fluid Phase Equilibria 2014, 371 , 82-92. https://doi.org/10.1016/j.fluid.2014.03.006
    46. Sushma P. Ijardar, Naved I. Malek. Experimental and theoretical excess molar properties of imidazolium based ionic liquids with molecular organic solvents – I. 1-Hexyl-3-methylimidazlouim tetraflouroborate and 1-octyl-3-methylimidazlouim tetraflouroborate with cyclic ethers. The Journal of Chemical Thermodynamics 2014, 71 , 236-248. https://doi.org/10.1016/j.jct.2013.11.027
    47. Tiancheng Mu, Buxing Han. Structures and Thermodynamic Properties of Ionic Liquids. 2014, 107-139. https://doi.org/10.1007/978-3-642-38619-0_4
    48. Dobrochna Matkowska, Tadeusz Hofman. Volumetric Properties of the {x 1[C4mim][MeSO4] + (1 − x 1)MeOH} System at Temperatures from (283.15 to 333.15) K and Pressures from (0.1 to 35) MPa. Journal of Solution Chemistry 2013, 42 (5) , 979-990. https://doi.org/10.1007/s10953-013-0016-8
    49. S.M. Hosseini, M.M. Alavianmehr, D. Mohammad-Aghaie, F. Fadaei-Nobandegani, J. Moghadasi. Volumetric properties of ionic liquids from cubic equation of state: Application to pure and mixture. Journal of Industrial and Engineering Chemistry 2013, 19 (3) , 769-775. https://doi.org/10.1016/j.jiec.2012.10.013
    50. Varadhi Govinda, P. Madhusudhana Reddy, Pankaj Attri, P. Venkatesu, P. Venkateswarlu. Influence of anion on thermophysical properties of ionic liquids with polar solvent. The Journal of Chemical Thermodynamics 2013, 58 , 269-278. https://doi.org/10.1016/j.jct.2012.11.014
    51. Evgeniy V. Ivanov. Volumetric properties of dilute solutions of water in ethanol and water-d2 in ethanol-d1 between T=(278.15 and 318.15)K. The Journal of Chemical Thermodynamics 2012, 47 , 162-170. https://doi.org/10.1016/j.jct.2011.10.009
    52. Fuxin Yang, Xiaopo Wang, Zhigang Liu. Volumetric properties of binary and ternary mixtures of bis(2-hydroxyethyl)amine with water, methanol, ethanol from (278.15 to 353.15)K. Thermochimica Acta 2012, 533 , 1-9. https://doi.org/10.1016/j.tca.2012.01.007
    53. Jianguo Zhou, Rongjiao Zhu, Hongfei Xu, Yiling Tian. Densities, excess molar volume, isothermal compressibility, and isobaric expansivity of (dimethyl carbonate+n-hexane) systems at temperatures (293.15 to 313.15)K and pressures from 0.1MPa up to 40MPa. The Journal of Chemical Thermodynamics 2010, 42 (12) , 1429-1434. https://doi.org/10.1016/j.jct.2010.06.011
    54. Evgeniy V. Ivanov. Water as a solute in nitromethane: Effect of H2O–D2O isotope substitution on the solution volumetric properties between 278.15K and 318.15K. The Journal of Chemical Thermodynamics 2010, 42 (12) , 1458-1464. https://doi.org/10.1016/j.jct.2010.07.002
    55. Mérièm Anouti, Annie Vigeant, Johan Jacquemin, Catherine Brigouleix, Daniel Lemordant. Volumetric properties, viscosity and refractive index of the protic ionic liquid, pyrrolidinium octanoate, in molecular solvents. The Journal of Chemical Thermodynamics 2010, 42 (7) , 834-845. https://doi.org/10.1016/j.jct.2010.01.013
    56. Gonzalo García-Miaja, Jacobo Troncoso, Luis Romaní. Excess molar properties for binary systems of alkylimidazolium-based ionic liquids+nitromethane. Experimental results and ERAS-model calculations. The Journal of Chemical Thermodynamics 2009, 41 (3) , 334-341. https://doi.org/10.1016/j.jct.2008.09.002
    57. Gonzalo García-Miaja, Jacobo Troncoso, Luis Romaní. Excess properties for binary systems ionic liquid+ethanol: Experimental results and theoretical description using the ERAS model. Fluid Phase Equilibria 2008, 274 (1-2) , 59-67. https://doi.org/10.1016/j.fluid.2008.09.004
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    Cite this: J. Chem. Eng. Data 2008, 53, 6, 1298–1301
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je700754k
    Published April 26, 2008
    Copyright © 2008 American Chemical Society
    Request reuse permissions

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