ACS Publications. Most Trusted. Most Cited. Most Read
Densities, Viscosities, Refractive Indices, and Heat Capacities of Poly(propylene glycols) or Poly(ethylene glycol)−Poly(propylene glycol)−Poly(ethylene glycol)-block-Copolymers + 2-Methyltetrahydrofuran at (298.15 and 313.15) K and at Atmospheric Pressure

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Chem. Eng. Data 2008, 53, 6, 1302-1308
    Article

    Densities, Viscosities, Refractive Indices, and Heat Capacities of Poly(propylene glycols) or Poly(ethylene glycol)−Poly(propylene glycol)−Poly(ethylene glycol)-block-Copolymers + 2-Methyltetrahydrofuran at (298.15 and 313.15) K and at Atmospheric Pressure
    Click to copy article linkArticle link copied!

    View Author Information
    Istituto per la Sintesi Organica e la Fotoreattività (ISOF-CNR), via Gobetti 101, I-40129 Bologna, Italy, Dipartimento di Chimica “G. Ciamician”, Università degli Studi, via Selmi 2, I-40126 Bologna, Italy, and Istituto di Chimica e Tecnologia dei Polimeri (ICTP-CNR), viale Andrea Doria 6, I-95125 Catania, Italy
    * Corresponding author. E-mail: [email protected]. Tel.: +39-051-2094326 . Fax: +39-051-2094325.
    †ISOF-CNR.
    ‡Università degli Studi.
    §ICTP-CNR.
    Other Access Options

    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2008, 53, 6, 1302–1308
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je800005q
    Published May 2, 2008
    Copyright © 2008 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!

    Densities, ρ, dynamic viscosities, η, refractive indices, nD, and heat capacities, Cp, for the binary mixtures containing two poly(propylene glycols) (Mn = 1335 and Mn = 2004) and two block-copolymers [poly(ethylene)−poly(propylene)−poly(ethylene)] (Mn = 1220 and Mn = 2280) + 2-methyltetrahydrofuran were determined at (298.15 and 313.15) K and at atmospheric pressure using an Anton Paar density meter, a Schott-Geräte AVS viscometer, an Abbe refractometer, and a Perkin-Elmer differential scanning calorimeter. Volume variations, ΔV, and deviations of the dynamic viscosities, Δη, were obtained at these temperatures and are negative for all mixtures. Experimental data were fitted to the Redlich−Kister equation, and the adjustable parameters and the standard deviations between experimental and calculated values were estimated. Conclusions were qualitatively discussed in terms of molecular interactions.

    Copyright © 2008 American Chemical Society

    Subjects

    what are subjects

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Cited By

    Click to copy section linkSection link copied!

    This article is cited by 13 publications.

    1. Feng Zhou, Lei Zhong, Changxu Chen, Ye Li, and Chunjian Xu . Isobaric Vapor–Liquid Equilibrium for Binary and Ternary Systems of Isoamyl Alcohol + Isoamyl Acetate + Dimethyl Sulfoxide at 101.33 kPa. Journal of Chemical & Engineering Data 2017, 62 (2) , 691-697. https://doi.org/10.1021/acs.jced.6b00733
    2. Diké-Michel Alozie, Philippe Courtes, Benjamin Ha, and Denis Prat . Determination of Accurate Specific Heat Capacities of Liquids in a Reaction Calorimeter, by Statistical Design. Organic Process Research & Development 2011, 15 (6) , 1412-1419. https://doi.org/10.1021/op200093b
    3. Fabio Comelli, Adriana Bigi, Daniele Vitalini and Katia Rubini . Densities, Viscosities, Refractive Indices, and Heat Capacities of Poly(ethylene glycol-ran-propylene glycol) + Esters of Carbonic Acid at (293.15 and 313.15) K and at Atmospheric Pressure. Journal of Chemical & Engineering Data 2010, 55 (1) , 205-210. https://doi.org/10.1021/je900307z
    4. A. Rita Lopes, Hairong Wang, Jialin Dong, Joonkyoung Han, Evan S. Hatakeyama, Thomas P. Hoelen, Gregory V. Lowry. Impact of polymer molecular weight on the efficiency of temperature swing solvent extraction for desalination of concentrated brines. Desalination 2022, 543 , 116104. https://doi.org/10.1016/j.desal.2022.116104
    5. Mikael Männistö, Juha-Pekka Pokki, Ville Alopaeus. Quaternary and ternary LLE measurements for solvent (2-methyltetrahydrofuran and cyclopentyl methyl ether) + furfural + acetic acid + water between 298 and 343 K. The Journal of Chemical Thermodynamics 2018, 119 , 61-75. https://doi.org/10.1016/j.jct.2017.12.015
    6. Mikael Männistö, Juha-Pekka Pokki, Ludivine Fournis, Ville Alopaeus. Ternary and binary LLE measurements for solvent (2-methyltetrahydrofuran and cyclopentyl methyl ether) + furfural + water between 298 and 343 K. The Journal of Chemical Thermodynamics 2017, 110 , 127-136. https://doi.org/10.1016/j.jct.2017.02.016
    7. Christian Wohlfarth. Viscosity of 2-methyltetrahydrofuran. 2017, 168-168. https://doi.org/10.1007/978-3-662-49218-5_147
    8. Christian Wohlfarth. Refractive index of 2-methyltetrahydrofuran. 2017, 193-193. https://doi.org/10.1007/978-3-662-49236-9_180
    9. I.M. Alwaan, A. Hassan. Effect of N, N-M-Phenylenebismaleimide on Thermodynamics Properties of Epoxidised Natural Rubber by Using Differential Scanning Calorimeter. Progress in Rubber, Plastics and Recycling Technology 2014, 30 (3) , 169-184. https://doi.org/10.1177/147776061403000304
    10. Maurizio S. Montaudo, Salvatore Battiato. Polymers. 2012, 1079-1105. https://doi.org/10.1002/9781118180730.ch45
    11. Ch. Wohlfarth. pVT data of poly(ethylene glycol-b-propylene glycol-b-ethylene glycol) in 2-methyltetrahydrofuran. 2010, 124-124. https://doi.org/10.1007/978-3-642-02890-8_82
    12. Ch. Wohlfarth. pVT data of poly(propylene glycol) in 2-methyltetrahydrofuran. 2010, 271-273. https://doi.org/10.1007/978-3-642-02890-8_122
    13. Romolo Francesconi, Adriana Bigi, Daniele Vitalini, Katia Rubini, Fabio Comelli. Densities, Viscosities, Refractive Indices, and Heat Capacities of Four Poly(ethylene glycol)−Poly(propylene glycol)−Poly(ethylene glycol)- block- Copolymers + Dimethyl Sulfoxide at (298.15 and 313.15) K and at Atmospheric Pressure. Journal of Chemical & Engineering Data 2009, 54 (3) , 956-961. https://doi.org/10.1021/je800731t
    Download PDF
    Go to Journal of Chemical & Engineering Data
    Get e-Alerts
    Get e-Alerts

    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2008, 53, 6, 1302–1308
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je800005q
    Published May 2, 2008
    Copyright © 2008 American Chemical Society
    Request reuse permissions

    Article Views

    404

    Altmetric

    -

    Citations

    13
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.