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Vapor−Liquid Equilibria of Selected Components in Propylene Oxide Production

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Department of Chemical and Environmental Engineering, Faculty of Chemical and Food Technology, Slovak University of Technology, 812 37 Bratislava, Slovak Republic
* Corresponding author. E-mail: [email protected]
Cite this: J. Chem. Eng. Data 2008, 53, 7, 1579–1582
Publication Date (Web):June 19, 2008
https://doi.org/10.1021/je800122x
Copyright © 2008 American Chemical Society

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    Abstract

    Vapor−liquid equilibrium (VLE) of binary systems formed by 1,2-dichloropropane and propylene chlorohydrine or bis(2-chloroisopropyl) ether at a pressure of 10 kPa as well as the variation of the saturated vapor pressure of propylene chlorohydrine and bis(2-chloroisopropyl) ether with temperature were measured by a static method. Binary VLE data were fitted to the Redlich−Kister, Wilson, NRTL, and UNIQUAC models employing the maximum likelihood procedure. Binary parameters of individual excess molar Gibbs energy models were obtained assuming the ideal behavior of the vapor phase. A good agreement between the experimental and correlated data was found. A comparison of the fit goodness of the selected GE models is presented. The experimental data of the single component equilibrium measurements were correlated by the Antoine equation applying the least-squares method.

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    Cited By

    This article is cited by 6 publications.

    1. Bing Jia, Kun Xin, Xiaoxiao Bian, Chuanfu Zhu, Yingmin Yu, and Qingsong Li . Liquid–Liquid Equilibria for the Extraction of Chloropropanols from 1,2-Dichloropropane Using Water or 1,4-Butylene Glycol. Journal of Chemical & Engineering Data 2017, 62 (3) , 1130-1134. https://doi.org/10.1021/acs.jced.6b00976
    2. Kelly E. Fletcher, Frank E. Löffler, Hans-Hermann Richnow and Ivonne Nijenhuis . Stable Carbon Isotope Fractionation of 1,2-Dichloropropane during Dichloroelimination by Dehalococcoides Populations. Environmental Science & Technology 2009, 43 (18) , 6915-6919. https://doi.org/10.1021/es900365x
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    4. Qingyuan Guo, Kai Yang, Jianwei Yu, Chunmiao Wang, Xiaodong Wen, Liping Zhang, Min Yang, Ping Xia, Dong Zhang. Simultaneous removal of multiple odorants from source water suffering from septic and musty odors: Verification in a full-scale water treatment plant with ozonation. Water Research 2016, 100 , 1-6. https://doi.org/10.1016/j.watres.2016.05.017
    5. Qingyuan Guo, Jianwei Yu, Kai Yang, Xiaodong Wen, Haifeng Zhang, Zhiyong Yu, Hongyan Li, Dong Zhang, Min Yang. Identification of complex septic odorants in Huangpu River source water by combining the data from gas chromatography-olfactometry and comprehensive two-dimensional gas chromatography using retention indices. Science of The Total Environment 2016, 556 , 36-44. https://doi.org/10.1016/j.scitotenv.2016.03.003
    6. Li Xia, Xiaoyan Sun, you Li, Shuguang Xiang. Simulation and Optimization of Saponification Process in Propylene Oxide Plant. 2012, 125-129. https://doi.org/10.1016/B978-0-444-59507-2.50017-2

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